After recrystallizing an impure sample with isopropanol, you isolate your product by filtration. What solvent do you use to wash your crystals? Room temperature distilled water Room temperature isopropanol Ice cold distilled water Ice cold isopropanol

Answers

Answer 1

Answer:

The correct answer is ice cold isopropanol.

Explanation:

Any compound in the initial stage is first dissolved in any suitable solvent and is heated for a certain duration for the process of recrystallization. Afterward, the compound is kept at room temperature so that it gets cooled gradually. In the process, the impurities remain dissolved in the solvent and the pure compound gets separated in the form of a precipitate.  

Post all this, the filtration of the pure compound is done and is then washed with the cold solvent, which was initially used to dissolve the compound. Therefore, the appropriate solvent to use in the process is ice-cold isopropanol.  


Related Questions

Amylase is the enzyme that controls the breakdown of starch to glucose. Describe how the student could investigate the effect of pH on the breakdown of starch by amylase.

Answers

Answer:

Explanation:

You will investigate the breakdown of starch by amylase at different pHs.

The different pHs under investigation will be produced using buffer solutions. Buffer solutions produce a particular pH, and will maintain it if other substances are added.

The amylase will break down the starch.

A series of test tubes containing a mixture of starch and amylase is set up at different pHs.

A sample is removed from the test tubes every 10 seconds to test for the presence of starch. Iodine solution will turn a blue/black colour when starch is present, so when all the starch is broken down, a blue-black colour is no longer produced. The iodine solution will remain orange-brown.

A control experiment must be set up - without the amylase - to make sure that the starch would not break down anyway, in the absence of an enzyme. The result of the control experiment must be negative - the colour must remain blue-black - for results with the enzyme to be valid.

When the starch solution is added:

Start timing immediately.Remove a sample immediately and test it with iodine solution.Sample the starch-amylase mixture continuously, for example every 10 seconds.

For each pH investigated, record the time taken for the disappearance of starch, ie when the iodine solution in the spotting tile remains orange-brown.

The time taken for the disappearance of starch is not the rate of reaction.

It will give us an indication of the rate, but is the inverse of the rate - the shorter the time taken, the greater the rate of the reaction.

We can calculate the rate of the reaction by calculating  \frac{1}{t}, obtaining a measure of the rate of reaction by dividing one by the time taken for the reaction to occur.

A similar experiment can be carried out to investigate the effect of temperature on amylase activity.

Set up a series of test tubes in the same way and maintain these at different temperatures using a water bath - either electrical or a heated beaker of water.

Depending on the chemical reaction under investigation, you might monitor the reaction in a different way. If investigating the effect of temperature on the breakdown of lipid by lipase, you could monitor pH change - lipids are broken down into fatty acids and glycerol. As the reaction begins, the release of fatty acids will mean that the pH will decrease.

good luck :)

At high temperatures one mole of hydrogen gas reacts with one mole of bromine gas to form hydrogen bromide. At a given temperature the equilibrium constant is 57.6. If at the same temperature, a mixture of 4.67 × 10^-3M bromine gas, 2.14 × 10^−3 hydrogen gas, and 2.40 × 10^−2M hydrogen bromide gas is made, then:

a. the system is at equilibrium.
b. the system is far from equilibrium and will shift to form more hydrogen gas.
c. the system is far from equilibrium and will shift to form more hydrogen bromide gas.
d. nothing can be deduced since we do not know whether the reaction is endothermic or exothermic.
e. nothing can be deduced since we do not know whether the equilibrium constant is Kc or Kp.

Answers

Answer:

a. the system is at equilibrium.

Explanation:

Hello,

In this case, the undergoing chemical reaction is:

[tex]H_2+Br_2\rightleftharpoons 2HBr[/tex]

Thus, the law of mass action is given by:

[tex]Keq=\frac{[HBr]^2}{[H_2][Br_2]} =57.6[/tex]

Nonetheless, for the given point of 4.67 × 10^-3M bromine gas, 2.14 × 10^−3 hydrogen gas, and 2.40 × 10^−2M hydrogen bromide gas we should compute the reaction quotient in order to know whether the direction of the reaction is to left or to right, thus:

[tex]Q=\frac{[HBr]^2}{[H_2][Br_2]} =\frac{(2.40x10^{-2})^2}{(4.67x10^{-3})(2.14x10^{-3})} \\\\Q=57.6[/tex]

Therefore, since Keq=Q, we say that the system is at equilibrium, for that reason, the answer is a.

Best regards.

A student dissolved 5.00 g of Co(NO3)2 in enough water to make 100. mL of stock solution. He took 4.00 mL of the stock solution and then diluted it with water to give 275. mL of a final solution. How many grams of NO3- ion are there in the final solution?

Answers

Answer:

0.136g

Explanation:

A student dissolved 5.00 g of Co(NO3)2 in enough water to make 100. mL of stock solution. He took 4.00 mL of the stock solution and then diluted it with water to give 275. mL of a final solution. How many grams of NO3- ion are there in the final solution?

[tex]Co(NO_3)_2(aq)\rightarrow Co^{2+}(aq)+2NO_3^{-}(aq)[/tex]

Initial mole of Co(NO3)2  [tex]=\frac{mass}{molar mass}[/tex]

[tex]=\frac{5.00}{182.94} \\\\=0.02733mol[/tex]

Mole of Co(NO3)2 in final solution

[tex]=\frac{4.00}{100}\times 0.02733\\\\=0.04\times 0.02733\\\\= 0.001093mol[/tex]

Mole of  NO3- in final solution = 2 x Mole of Co(NO3)2

[tex]=2\times 0.001093\\\\=0.002186mol[/tex]

Mass of  NO3- in final solution is mole x Molar mass of NO3

[tex]=0.002186\times62.01\\\\=0.136g[/tex]

The final solution contains 0.24 g of nitrate ion.

Number of moles of  Co(NO3)2 =  5.00 g/183 g/mol = 0.027 moles

Number of moles = concentration × volume

concentration = Number of moles /volume

Volume of solution = 100 mL or 0.1 L

concentration =  0.027 moles/0.1 L = 0.27 M

Using the dilution formula;

C1V1 = C2V2

C1 =  0.27 M

V1 = 4.00 mL

C2 = ?

V2 =  275. mL

C2 = C1V1/V2

C2 = 0.27 × 4.00/ 275

C2 = 0.0039 M

Number of moles of NO3- ion in Co(NO3)2 = 0.0039 M × 62 g/mol = 0.24 g

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a) A molecule of DNA contains 140 A bases, how many T bases will it contain?​ Plz help ❤️

Answers

Answer:

140 T or thymine base

Explanation:

Adenine pairs with Thymine in DNA thus the number of adenine will always equal number of thymine (unless some sort of mutation), therefore in this problem you have 140 A so you have 140 T as well. Remember: Adenine (A) and Thymine(T) is equal, & Cytosine (C) and Guanine (G) is equal

A stock solution will be prepared by mixing the following chemicals together:

3.0 mL of 0.00200 M KSCN
10.0 mL of 0.200 M Fe(NO3)3
17.0 mL of 0.5 M HNO3

Determine the molar concentration of Fe(NO3)3 in the stock solution.

Answers

Answer:

0.067M Fe(NO3)3

Explanation:

A stock solution is a concentrated solution that is diluted to prepare the solutions that you will use.

The volume of the stock solution is 3.0mL + 10.0mL + 17.0mL= 30.0mL.

The ratio between volume of the aliquot (10.0mL) and total volume (30.0mL) is called dilution factor, that is: 30.0mL / 10.0mL = 3

That means the Fe(NO3)3 is diluted 3 times. That means the molar concentration of the stock solution is:

0.200M / 3 =

0.067M Fe(NO3)3

A laser is used in eye surgery to weld a detached retina back into place. The wavelength of the laser beam is 503 nm, while the power is 1.4 W. During surgery, the laser beam is turned on for 0.070 s. During this time, how many photons are emitted by the laser?

Answers

Answer:

Number of proton emmitted by laser=[tex]2.48*10^17proton[/tex]

Explanation:

Energy is the ability to cause change; power is directly proportional to energy and its the rate energy is utilized.

Power=energy/time.

First we need to calculate the total energy used which is equal to the total power utilized.

E(total)= P( total) = 1.4W × 0.070 s =[tex]0.098J[/tex]

CHECK THE ATTACHMENT FOR THE REMAINING DETAILED CALCULATION

Suppose an industrial quality-control chemist analyzes a sample from a copper processing plant in the following way. He adds powdered iron to a copper(II) sulfate sample from the plant until no more copper will precipitate. He then washes, dries, and weighs the precipitate, and finds that it has a mass of . Calculate the original concentration of copper(II) sulfate in the sample. Round your answer to significant digits.

Answers

Answer:

Concentration of Copper (II) Sulfate in the original sample in mol/L = 0.0035 M

Concentration of Copper (II) Sulfate in the original sample in g/L = 0.56 g/L

Explanation:

Complete Question

Fe(s) + CuSO₄(aq) → Cu(s) + FeSO₄(aq)

Suppose an industrial quality-control chemist analyzes a sample from a copper processing plant in the following way. He adds powdered iron to a 400.mL copper (II) sulfate sample from the plant until no more copper will precipitate. He then washes, dries, and weighs the precipitate, and finds that it has a mass of 89.mg. Calculate the original concentration of copper(II) sulfate in the sample. Round your answer to 2 significant figures.

Solution

Noting that the precipitate is Copper as it is the only solid by-product of this reaction.

89 mg of Copper is produced from this reaction.

We convert this into number of moles for further stoichiometric calculations

Mass of Copper = 89 mg = 0.089 g

Molar mass of Copper = 63.546 amu

Number of moles of Copper produced from the reaction = (0.089/63.546) = 0.0014005602 = 0.001401 mole

From the stoichiometric balance of the reaction,

1 mole of Copper is produced from 1 mole of Copper (II) Sulfate

0.001401 mole of Copper will be produced similarly from 0.001401 mole of Copper (II) Sulfate.

Number of moles of Copper (II) Sulfate in the original sample = 0.001401 mole

Concentration of Copper (II) Sulfate in the original sample in mol/L = (Number of moles) ÷ (Volume in L)

Number of moles = 0.001401 mole

Volume in L = (400/1000) = 0.4 L

Concentration of Copper (II) Sulfate in the original sample in mol/L = (0.001401/0.4) = 0.0035025 mol/L = 0.0035 mol/L to 2 s.f.

Concentration in g/L = (Concentration in mol/L) × (Molar Mass)

Concentration in mol/L = 0.0035025 M

Molar mass of Copper (II) Sulfate = 159.609 g/mol

Concentration of Copper (II) Sulfate in the original sample in g/L = 0.0035025 × 159.609 = 0.559 g/L = 0.56 g/L to 2 s.f

Hope this Helps!!!!

The concentration of the original copper solution is 0.035 M.

The equation of the reaction is;

Fe(s) + CuSO4(aq) -------> FeSO4(aq) + Cu(s)

Number of moles of copper obtained = 89 × 10^-3g/63.5 = 0.0014 moles

Since the reaction is 1:1, the number of moles of copper sulfate that reacted is c.

From the question, we are told that the volume of solution is 400.mL or 0.04L.

Hence, the concentration of the solution is; number of moles /volume

=  0.0014 moles/0.04L = 0.035 M

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Missing parts;

Suppose an industrial quality-control chemist analyzes a sample from a copper processing plant in the following way. He adds powdered iron to a 400.mL copper (II) sulfate sample from the plant until no more copper will precipitate. He then washes, dries, and weighs the precipitate, and finds that it has a mass of 89.mg. Calculate the original concentration of copper(II) sulfate in the sample. Round your answer to 2 significant figures.

Volume of water is 35 cm3 and mass of water is 60 gram, what is the density of the water.​

Answers

Answer:

p = 1.714 g/cm3

Explanation:

Density Equation

p=mV

Where:

p = density

m = mass  = 60g

V = volume = 35cm3

p = 60g x 35cm3

p = 1.714 g/cm3

p=1.714g/cm³

Explanation:

v=35cm³

m=60g

P=mass/volume (density formula)

=60/35

=1.714g/cm³

What is the temperature at which the substance can be both in the solid and the liquid phase?

Answers

Answer: Gas–liquid–solid triple point

The single combination of pressure and temperature at which liquid water, solid ice, and water vapor can coexist in a stable equilibrium occurs at approximately 273.1575 K (0.0075 °C; 32.0135 °F) and a partial vapor pressure of 611.657 pascals (6.11657 mbar; 0.00603659 atm).

Explanation:

It represents the equilibrium between the liquid and gas phases. The point on this curve where the vapor pressure is 1 atm is the normal boiling point of the substance. The vapor-pressure curve ends at the critical point (B), which is at the critical temperature and critical pressure of the substance.

g a solution is made by mixing 500.0 mL of 0.037980.03798 M Na2sO4 Na2sO4 with 500.0 mL of 0.034280.03428 M NaOH NaOH . Complete the mass balance expressions for the sodium and arsenate species in the final solution.

Answers

Answer:

The concentration of the sodium and arsenate ions at the end of the reaction in the final solution

[Na⁺] = 0.05512 M

[HAsO₄²⁻] = 0.00185 M

[AsO₄³⁻] = 0.01714 M

Explanation:

Complete Question

A solution is made by 500.0 mL of 0.03798 M Na₂HAsO₄ with 500.0 mL of 0.03428 M NaOH. Complete the mass balance expressions for the sodium and arsenate species in the final solution.

Na₂HAsO₄ + NaOH → Na₃AsO₄ + H₂O

From the information provided in this question, we can calculate the number of moles of each reactant at the start of the reaction and we then determine which reagent is in excess and which one is the limiting reagent (in short supply and determines the amount of products to be formed)

Concentration in mol/L = (Number of moles) ÷ (Volume in L)

Number of moles = (Concentration in mol/L) × (Number of moles)

For Na₂HAsO₄

Concentration in mol/L = 0.03798 M

Volume in L = (500/1000) = 0.50 L

Number of moles = 0.03798 × 0.5 = 0.01899 mole

For NaOH

Concentration in mol/L = 0.03428 M

Volume in L = (500/1000) = 0.50 L

Number of moles = 0.03428 × 0.5 = 0.01714 mole

Since the NaOH is in short supply, it is evident that it is the limiting reagent and Na₂HAsO₄ is in excess.

Na₂HAsO₄ + NaOH → Na₃AsO₄ + H₂O

0.01899        0.01714        0           0 (At time t=0)

(0.01899 - 0.1714) | 0 → 0.01714    0.01714 (end)

0.00185  | 0 → 0.01714    0.01714 (end)  

Hence, at the end of the reaction, the following compounds have the following number of moles

Na₂HAsO₄ = 0.00185 mole

This means Na⁺ has (2×0.00185) = 0.0037 mole at the end of the reaction and (HAsO₄)²⁻ has 0.00185 mole at the end of the reaction

NaOH = 0 mole

Na₃AsO₄ = 0.01714 moles

This means Na⁺ has (3×0.01714) = 0.05142 mole at the end of the reaction and (AsO₄)³⁻ has 0.01714 mole at the end of the reaction

H₂O = 0.01714 moles

So, at the end of the reaction

Na⁺ has 0.0037 + 0.05142 = 0.05512 mole

(HAsO₄)²⁻ has 0.00185 mole

(AsO₄)³⁻ has 0.01714 mole.

And since the Total volume of the reaction setup is now 500 mL + 500 mL = 1000 mL = 1 L

Hence, the concentration of the sodium and arsenate ions at the end of the reaction is

[Na⁺] = 0.05512 M

[HAsO₄²⁻] = 0.00185 M

[AsO₄³⁻] = 0.01714 M

Hope this Helps!!!

Answer:

[tex]\rm [Na^{+}]= \text{0.055 12 mol/L}[/tex]

[tex]\rm [HAsO_{4}^{2-}] + [AsO_{4}^{3-}] + [H_{2}AsO_{4}^{-}] + [H_{3}AsO_{4}] = \text{0.018 99 mol/L}[/tex]

Explanation:

The overall equation for the reaction is  

Na₂HAsO₄ + NaOH ⟶ Na₃AsO₄ + H₂O

1. Mass balance for Na

All the Na⁺ comes from the Na₂HAsO₄ and the NaOH.

The mass balance equation for Na is  

[tex]\rm c_{Na^{+}} = 2[Na^{+}]_{Na_{2}HAsO_{4}} + [Na^{+}]_{NaOH}[/tex]

At the moment of mixing and before the reaction started, the total volume had doubled, so the concentrations of each component were halved.

[Na₂HAsO₄] = ½ × 0.037 98 =0.018 99 mol·L⁻¹

[NaOH]         = ½ × 0.034 28 = 0.017 14 mol·L⁻¹

[tex]\rm c_{Na^{+}} = 2\times 0.01899 + 0.01714 = 0.03798 + 0.01714\\c_{Na^{+}}= \textbf{0.055 12 mol/L}[/tex]

2. Mass balance for arsenate species

All the arsenate species come from the Na₂HAsO₄.

The reactions involved are

HAsO₄²⁻+ OH⁻ ⇌ AsO₄³⁻ + H₂O

HAsO₄²⁻ + H₂O ⇌ H₂AsO₄⁻ + OH⁻

H₂AsO₄⁻ + H₂O ⇌ H₃AsO₄ + OH⁻

The mass balance equation for arsenate species is

[tex]\rm c_{\text{arsenate}} = [HAsO_{4}^{2-}] + [AsO_{4}^{3-}] + [H_{2}AsO_{4}^{-}] + [H_{3}AsO_{4}][/tex]

At the moment of mixing, the concentration of Na₂HAsO₄ had halved.

[Na₂HAsO₄] = ½ × 0.039 78 = 0.018 99 mol·L⁻¹

[tex]\rm [HAsO_{4}^{2-}] + [AsO_{4}^{3-}] + [H_{2}AsO_{4}^{-}] + [H_{3}AsO_{4}] = \textbf{0.018 99 mol/L}[/tex]

g Identify the type of reaction [(combination (c), decomposition (d), combustion (co), single replacement (sr), double replacement (dr) , or neutralization (n)] and write a balanced equation. If there is no reaction, write NR. Aqueous ammonium phosphate reacts with aqueous calcium sulfide.

Answers

Answer: [tex]2(NH_4)_3PO_4(aq)+3CaS(aq)\rightarrow Ca_3(PO_4)_2(aq)+3(NH_4)_2S(s)[/tex] is a double displacement reaction (dr).

Explanation:

A double displacement reaction (dr) is one in which exchange of ions take place. The salts which are soluble in water are designated by symbol (aq) and those which are insoluble in water and remain in solid form are represented by (s) after their chemical formulas.

[tex]2(NH_4)_3PO_4(aq)+3CaS(aq)\rightarrow Ca_3(PO_4)_2(aq)+3(NH_4)_2S(s)[/tex]

Combination reaction (C) is defined as the reaction where substances combine in their elemental state to form a single compound.

Single displacement reaction (sr) is defined as the reaction where more reactive element displaces a less reactive element from its chemical reaction.

Decomposition reaction (d) is defined as the reaction where a single substance breaks down into two or more simpler substances.

Combustion (Co) is a type of chemical reaction in which hydrocarbons burn in the presence of oxygen to form carbon dioxide and water along with heat.

Magnesium and nitrogen react in a combination reaction to produce magnesium nitride:

3 Mg + N2 → Mg3N2

In a particular experiment, a 8.33-g sample of N2 reacts completely. The mass of Mg consumed is ________ g.

Answers

Answer:

21.7 g

Explanation:

Step 1: Write the balanced equation

3 Mg + N₂ → Mg₃N₂

Step 2: Calculate the moles corresponding to 8.33 g of nitrogen

The molar mass of N₂ is 28.01 g/mol.

[tex]8.33 g \times \frac{1mol}{28.01g} =0.297mol[/tex]

Step 3: Calculate the moles of magnesium that reacts with 0.297 moles of nitrogen

The molar ratio of Mg to N₂ is 3:1. The reacting moles of Mg are 3/1 × 0.297 mol = 0.891 mol

Step 4: Calculate the mass corresponding to 0.891 moles of magnesium

The molar mass of Mg is 24.31 g/mol.

[tex]0.891 mol \times \frac{24.31g}{mol} = 21.7 g[/tex]

Answer:

[tex]m_{Mg}=21.7 g Mg[/tex]

Explanation:

Hello,

In this case, considering the given reaction, we are able to compute the mass of magnesium that is consumed by considering its molar mass (24.31 g/mol), the molar mass of diatomic nitrogen (28.02 g/mol), the initial mass of nitrogen (8.33 g) and the 3:1 molar ratio of magnesium to nitrogen in the reaction.

Hence we compute it by applying the shown below stoichiometric procedure:

[tex]m_{Mg}=8.33 gN_2*\frac{1molN_2}{28.02gN_2} *\frac{3molMg}{1molN_2} *\frac{24.31gMg}{1molMg} \\\\m_{Mg}=21.7 g Mg[/tex]

Regards.

Gravity on Earth is 9.8 m/s2, and gravity on the Moon is 1.6 m/s2.

so if the mass of an object on earth is 40 kilograms what is the mass on the moon.
and how much does it way

Answers

Answer:

Mass is the same but it weights 64 Newtons

Explanation:

First of Mass is the same in any sort of gravity. Now let's calculate weight

W = MG

where W = Weight

M = Mass

G = Gravity

W = (40kg)(1.6)

W = 64

Sorry for the spelling mistakes, hope this helps

Answer:6.61kilo

Explanation: fdfv

how many molecules (not moles) of NH3 are produced from 5.25x10^-4 g of H2?

due in a few, please help. will mark as brainliest

Answers

Answer:

not 100% but i think its 1.57x10^20

Explanation:

5.25x10^-4g / 2.016g

2.60x10^-4 x 6.022x10^23= 1.56x10^20 molecules

How many moles of CO2 are produced when 84 0 mol O2 completely react?


Answers

Answer:

Explanation:boom

what is the sign of Mercury​

Answers

Answer:

The answer is Hg.

Explanation:

Symbol for Mercury is Hg.

The sign of Mercury is HG

The functional groups in an organic compound can frequently be deduced from its infrared absorption spectrum. A compound containing C, H, and O exhibits intense absorption at 1720 cm-1. No additional information is available. List possible classes for which there is positive evidence.
Relative absorption intensity: (s)=strong, (m)=medium, (w)=weak.

What functional class(es) does the compound belong to?
List only classes for which evidence is given here. Attach no significance to evidence not cited explicitly.
Do not over-interpret exact absorption band positions. None of your inferences should depend on small differences like 10 to 20 cm-1.

a. alkane (List only if no other functional class applies.)
b. alkene h. amine
c. terminal alkyne i. aldehyde or ketone
d. internal alkyne j. carboxylic acid
e. arene k. ester
f. alcohol l. nitrile
g. ether

Answers

Answer:

The class of this compound is aldehyde or ketone (i).

Explanation:

Absorption peak at 1720 cm-1 shows the presence of a carbonyl group, possibly an aldehyde or ketone with C=O bond.

Further information on molecular formula would be required for structural elucidation.

what is a mitochondrion

Answers

Explanation:

Mitochondria (sing. mitochondria) are organelles, or parts of the eukaryote cell. They are in the cytoplasm, not the nucleus. They make the most cell supply of adenosine triphosphate (ATP), a molecule that cells use as an energy source. ... This means that mitochondria are known as '' the powerhouse of the cell'' or ''cell strength".

Good Luck, and have a great day..

an organelle found in large numbers in most cells, in which the biochemical processes of respiration and energy production occur. It has a double membrane, the inner layer being folded inward to form layers (cristae

A scientist mixed 25.00 mL of 2.00 M KOH with 25.00 mL of 2.00 M HBr. The temperature of the mixed solution rose from 22.7 oC to 31.9 oC. Calculate the enthalpy change for the reaction in kJ/mol HBr, assuming that the calorimeter loses negligible heat, that the volumes are additive, and that the solution density is 1.00 g/mL, and that its specific heat is 4.184 J/g.oC.

Answers

Answer:

38.493 KJ/mol

Explanation:

Equation of reaction; HBr + KOH ---> KBr + H2O

Heat evolved = mass * specific heat capacity * temperature rise

Mass of solution = density * volume

Mass = 1.00 g/ml*50 ml = 50g

Temperature rise = 31.9 - 22.7 = 9.2 °C

Heat evolved = 50 * 4.184 * 9.2 = 1924.64 J

From the equation of reaction, 1 mole of HBr reacts with 1mole of KOH to produce 1 mole of H20

Number of moles of HBr involved in the reaction = molar concentration * volume (L)

Molar concentration = 2.0 M, volume = 25 ml = 0.025 L

Number of moles = 2.0 M * 0.025 L= 0.05 moles

Therefore, 0.05 moles of HBr reacts with 0.05 moles of KOH to produce 0.05 moles of H20

Enthalpy change per mole of HBr = 1924.64 J/0.05 moles = 38492.8 J/mol = 38.493 KJ/mol

When vinylcyclohexane is treated with in dichloromethane, the major product is (2-bromo ethylidene)cyclohexane . Account for the formation of this product by drawing the structure of the most stable radical intermediate. Include all valence lone pairs in your answer. Include all valence radical electrons in your answer.

Answers

Answer:

Explanation:

Vinylcyclohexane is an example of a cyclic hydrocarbon where the vinyl group (-CH=CH₂ ) attaches itself to an end of a cyclohexane in ring form thereby giving rise to a vinylcyclohexane. The vinyl group are ethylene with a reduction in one hydrogen atom given them the name vinyl.

SOo, when vinylcyclohexane is treated with  NBS ( i.e N-Bromosuccinimide a chemical reagent used in organic reactions) ; the bromine in the NBS reacts with the cyclohexane thereby giving rise to a allyl radical first. The allyl radical is resonance stabilized radical  with an unpaired electron on the allylic carbon . As a result of stabilization ; a more stable substituted cycloalkene is formed as an intermediate .

This   stable substituted cycloalkene intermediate then finally react with a bromine ion to give a major product known as ; (2-bromo ethylidene)cyclohexane.

The diagram emphasizing more on the above explanation can be seen in the attached image below

A chemist titrates of a butanoic acid solution with solution at . Calculate the pH at equivalence. The of butanoic acid is__________ .Round your answer to decimal places.
Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of solution added.

Answers

Answer:

pH = 8.75

Explanation:

100.0mL of a 0.8108M of a butanoic acid (HC₃H₇CO₂, pKa 4.82) solution is titrated with 0.0520M KOH.

The reaction is:

HC₃H₇CO₂ + KOH → H₂O + KC₃H₇CO

Moles of butanoic acid are:

0.1000L × (0.8108mol / L) = 0.08108 moles of butanoic

For a complete reaction, volume of KOH must be added is the volume in which 0.08108 moles of KOH are added, that is:

0.08108 mol × (L / 0.0520mol) = 1.56L of KOH.

Total volume in equilibrium is 1.56L + 0.10L = 1.66L

That means concentration of butanoic acid is:

0.08108 mol / 1.66L = 0.04884M HC₃H₇CO₂

At equivalence point, there is just C₃H₇CO⁻ in solution

Kb of butanoic acid is:

C₃H₇CO⁻ + H₂O ⇄ HC₃H₇CO₂ + OH⁻

Kb = Kw / Ka

Ka = 10^-pKa

Ka = 1.51x10⁻⁵

Kb = 1x10⁻¹⁴ / 1.51x10⁻⁵ = 6.61x10⁻¹⁰

The equilibrium of Kb is:

Kb = 6.61x10⁻¹⁰ =  [HC₃H₇CO₂] [OH⁻] / [C₃H₇CO⁻]

As at equivalence point there is just C₃H₇CO⁻, the equilibrium concentrations are:

[C₃H₇CO⁻] = 0.04884M - X

[HC₃H₇CO₂] = X

[OH⁻] = X

Replacing in Kb:

6.61x10⁻¹⁰ =  X² / [0.04884M - X]

0 =  X² + 6.61x10⁻¹⁰X - 3.23x10⁻¹¹

Solving for X:

X = -5.68x10⁻⁶ → False solution. There is no negative concentrations

X = 5.683x10⁻⁶ → Right solution.

As [OH⁻] = X, [OH⁻] = 5.683x10⁻⁶.

pOH = - log [OH⁻]

pOH = 5.245

pH = 14 - pOH

pH = 8.75

What is Keq for the reaction 2HCl(9) = H2(g) + Cl2(g)?

Answers

Answer:

Keq= [(Cl2) (H2)] / (HCl)^2

Explanation:

Equilibrium Constant, Keq, is written as products/reactants.

So it's going to be Keq= [(Cl2) (H2)] / (HCl)^2

For the iodine trichloride molecule: a. Determine the number of valence electrons for each atom in the molecule b. Draw the Lewis Dot structure c. Describe why the molecule is drawn this way (i.e. any extra rules/steps needed?) d. Show the polarity of each bond and for the molecule by drawing in the dipole +à

Answers

Answer:

Explanation:

a. Determine the number of valence electrons for each atom in the molecule

In this case we both atoms are halogens. Therefore we will have 7 electrons for each atom.

b. Draw the Lewis Dot structure

In this case, the formula is [tex]ICl_3[/tex], so the central atom would be "I" and the "Cl" atoms would be placed around "I". See figure 1

c. Describe why the molecule is drawn this way (i.e. any extra rules/steps needed?)

In this specific case, the "I" atom don't follow the octet rule. We will have an expanded octet for iodine (more than 8 electrons).

d. Show the polarity of each bond and for the molecule by drawing in the dipole +d

The negative dipole would be placed in the atom with higher electronegativity, in this case "Cl". The positive dipole would be placed in the atom with low electronegativity, in this case "I".

I hope it helps!

Which of these tasks would a geologist be most likely to perform?
A. Determining the species of a recently collected specimen
O B. Hypothesizing how pieces of ancient pottery were used
O C. Creating a new kind of material using polymers
O D. Determining the best method to extract underground natural gas
SUBMIT

Answers

Answer:

Explanation:

O B. Hypothesizing how pieces of ancient pottery were used

Using the following balanced chemical equation 8 H2 + S8à 8 H2S. Determine the mass of the product (molar mass = 34.08g/mol) if you start with 1.35 g of hydrogen and 6.86 g of S8 (Molar mass = 256.5 g/mole).

Answers

Answer: 7.29 g of [tex]H_2S[/tex] will be produced from the given masses of both reactants.

Explanation:

To calculate the moles :

[tex]\text{Moles of solute}=\frac{\text{given mass}}{\text{Molar Mass}}[/tex]    

[tex]{\text{Moles of} H_2}=\frac{1.35g}{2.01g/mol}=0.672moles[/tex]

[tex]\text{Moles of} S_8=\frac{6.86g}{256.5g/mol}=0.0267moles[/tex]

[tex]8H_2+S_8\rightarrow 8H_2S[/tex]

According to stoichiometry :

1 mole of [tex]S_8[/tex] require = 8 moles of [tex]H_2[/tex]

Thus 0.0267 moles of [tex]S_8[/tex] will require=[tex]\frac{8}{1}\times 0.0267=0.214moles[/tex]  of [tex]H_2[/tex]

Thus [tex]S_8[/tex] is the limiting reagent as it limits the formation of product and [tex]H_2[/tex] is the excess reagent.

As 1 mole of [tex]S_8[/tex] give = 8 moles of [tex]H_2S[/tex]

Thus 0.0267 moles of [tex]S_8[/tex] give =[tex]\frac{8}{1}\times 0.0267=0.214moles[/tex]  of [tex]H_2S[/tex]

Mass of [tex]H_2S=moles\times {\text {Molar mass}}=0.214moles\times 34.08g/mol=7.29g[/tex]

Thus 7.29 g of [tex]H_2S[/tex] will be produced from the given masses of both reactants.

Which of the following is an example of a mechanical wave?
O A. A light ray
B. A seismic wave
C. A radio wave
D. An X-ray

Answers

Answer:

A seismic wave

Explanation:

It requires a medium for its propagation.

When an unsymmetrical alkene such as propene is treated with N-bromosuccinimide in aqueous dimethyl sulfoxide, the major product has the bromine atom bonded to the less highly substituted carbon atom. Is this Markovnikov or non-Markovnikov orientation

Answers

All done for you no worries

When an unsymmetrical alkene such as propene is treated with N-bromosuccinimide in aqueous dimethyl sulfoxide, the major product has the bromine atom bonded to the less highly substituted carbon atom. This reaction describes a non-Markovnikov orientation.

In the reaction between an unsymmetrical alkene (such as propene) and N-bromosuccinimide (NBS) in the presence of aqueous dimethyl sulfoxide (DMSO), the major product is formed with the bromine atom bonded to the less highly substituted carbon atom of the alkene.

In Markovnikov's addition, the major product is formed by adding the electrophile (in this case, the bromine atom) to the carbon atom with more hydrogen atoms bonded to it. However, the given reaction exhibits non-Markovnikov selectivity, as the bromine atom adds to the less substituted carbon atom.

This non-Markovnikov selectivity can be attributed to the presence of DMSO, which acts as a polar solvent and helps generate a bromine radical (Br•). The radical intermediate can then undergo reaction with the alkene, leading to the observed regioselectivity where the bromine atom adds to the less substituted carbon. This process is known as a radical addition reaction.

Hence, the reaction demonstrates a non-Markovnikov orientation due to the addition of the bromine atom to the less highly substituted carbon atom of the propene molecule.

Learn more about the Markovnikov rule here:

https://brainly.com/question/33423745

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The compound ClF contains Group of answer choices polar covalent bonds with partial negative charges on the Cl atoms. ionic bonds. nonpolar covalent bonds. polar covalent bonds with partial negative charges on the F atoms.

Answers

Answer:

polar covalent bonds with partial negative charges on the F atoms.

Explanation:

A covalent bond could be polar or nonpolar depending on the relative electro negativity difference between the two bonding atoms. In this case, the bonding atoms are chlorine and fluorine.

In the Pauling's scale, fluorine has an electro negativity value of 3.98 while chlorine has an electro negativity value of 3.16. The difference in electro negativity between the two atoms is about 0.82. This magnitude of electro negativity difference between the two bonding atoms correspond to the existence of a polar covalent bond in the molecule.

The direction of the dipole depends on the relative electro negativity values of the two bonding atoms. Since fluorine is more electronegative than chlorine, the fluorine atom will be partially negative and the chlorine atom will be partially positive accordingly.

The compound ClF (chlorine monofluoride) contains polar covalent bonds with partial negative charges on the F atoms. Therefore, option D is correct.

In ClF, chlorine (Cl) is more electronegative than fluorine. As a result, the shared electrons in the Cl-F bond are pulled closer to the chlorine atom, creating a partial negative charge on the fluorine atoms and a partial positive charge on the chlorine atom.

This polarity in the Cl-F bond gives the molecule an overall polarity, making it a polar molecule. Thank you for pointing out the error, and I apologize for any confusion caused.

Thus, option D is correct.

To learn more about the polar covalent bonds, follow the link:

https://brainly.com/question/28295508

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Consider the following specific heats of metals. Metal Specific Heat Aluminum 0.897 J/(g°C) Magnesium 1.02 J/(g°C) Lithium 3.58 J/(g°C) Silver 0.237 J/(g°C) Gold 0.129 J/(g°C) If the same amount of heat is added to 25.0 g of each of the metals, which are all at the same initial temperature, which metal will have the lowest temperature?

Answers

Answer:

Lithium

Explanation:

The specific geat capacity of a substance is the energy required to raise 1 unit of that substance by one degree.

Heat energy (Q) = mc∇t

Q = heat energy

M = mass of the substance

c = specific heat capacity

∇t = change in temperature of the substance

Generally, increase in the specific heat capacity will lead to a lower final temperature likewise decrease in the specific heat capacity will lead to increase the final temperature of the substance.

From the data above, we can take just two specific heat capacity and test this theory.

Assuming we have a

Mass = 25g

Heat energy applied (Q) = 1 J

Initial temperature (T1) = 10°C

Final temperature (T2) = ?

Q = mc∇t

Q = mc (T2 - T1)

For Lithium, specific heat capacity = 3.58J/g°C

1 = 25 × 3.58 (T2 - 10)

Solve for T2

1 = 89.5 (T2 - 10)

1 = 89.5T2 - 895

89.5T2 = 896

T2 = 896 / 89.5

T2 = 10.011°C

For Magnesium (Mg) specific heat capacity = 1.02J/g°C

Q = mc∇t

1 = 25 × 1.02 × (T2 - 10)

1 = 25.5 (T2 - 10)

1 = 25.5T2 - 255

Solve for T2

25.5T2 = 256

T2 = 10.039°C

Notice the trend that decrease in the specific heat capacity leads to increase in the final temperature.

Try and continue for the elements and see how it works.

which statements describe how chemical formulas, such as H2O, represent compounds?

Answers

Answer:

2 Hydrogen One oxygen

Explanation:

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