An aqueous ammonium chloride solution rather than sulfuric acid is used in the hydrolysis of the magnesium complex of 1,1-diphenylethanol to ensure that no acid-catalyzed dehydration occurs. Write the chemical structure of the dehydration product from 1,1-diphenylethanol. (grignard lab)

Answers

Answer 1

The dehydration product of 1,1-diphenylethanol is 1,1-diphenylethene, also known as stilbene. The chemical structure of 1,1-diphenylethene is:

H3C-C=C-CH3 where the two phenyl (C6H5) groups are attached to the terminal carbon atoms of the double bond.

What is stilbene?

Stilbene is an organic compound with the chemical formula C14H12. It is a hydrocarbon that consists of a central trans-stilbene unit, which is composed of two phenyl (C6H5) groups attached to each end of a central double bond (C=C). Stilbene is a colorless solid that is soluble in organic solvents like benzene, ether, and chloroform.

In the presence of acid, such as sulfuric acid, 1,1-diphenylethanol can undergo dehydration to form 1,1-diphenylethene by eliminating a molecule of water. However, in the presence of ammonium chloride, which acts as a weak acid, the hydrolysis reaction of the magnesium complex of 1,1-diphenylethanol proceeds without dehydration occurring.

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Related Questions

will a solution containing aqueous dichromate (vi) ions be a strong enough oxidizing agent to produce aqueous iodine from a solution containing aqueous iodide ions? fully explain your prediction

Answers

A solution containing aqueous dichromate (VI) ions will be a strong enough oxidizing agent to produce aqueous iodine from a solution containing aqueous iodide ions is because dichromate (VI) ions are a strong oxidizing agent that can oxidize iodide ions to form iodine.

In the process, the dichromate (VI) ions are reduced to chromium (III) ions. The reaction between dichromate (VI) ions and iodide ions can be represented by the following equation:

Cr₂O₇²⁻ + 14H⁺ + 6I- → 2Cr₃+ + 3I₂ + 7H₂O

In this reaction, the dichromate (VI) ions are reduced to chromium (III) ions, while the iodide ions are oxidized to form iodine.

Therefore, a solution containing aqueous dichromate (VI) ions would be able to produce aqueous iodine from a solution containing aqueous iodide ions.


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what is the standard voltage of an electrochemical cell where two relevant half reactions in the table of standard reduction potentials

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The standard voltage of an electrochemical cell can be calculated using the table of standard reduction potentials. In this table, each half-reaction is assigned a standard reduction potential, which is the tendency of the half-reaction to gain electrons and undergo reduction.

To calculate the standard voltage of an electrochemical cell, we subtract the standard reduction potential of the half-reaction at the anode from the standard reduction potential of the half-reaction at the cathode. This gives us the standard cell potential (or voltage) for the electrochemical cell.
For example, if we have an electrochemical cell with a zinc anode and a copper cathode, the relevant half-reactions are:

Zn(s) → Zn2+(aq) + 2e- (oxidation) E° = -0.76 V
Cu2+(aq) + 2e- → Cu(s) (reduction) E° = +0.34 V


To calculate the standard voltage of this electrochemical cell, we subtract the standard reduction potential of the anode (Zn) from the standard reduction potential of the cathode (Cu):

E°cell = E°cathode - E°anode
E°cell = +0.34 V - (-0.76 V)
E°cell = +1.10 V


Therefore, the standard voltage of this electrochemical cell is +1.10 V.
To find the standard voltage of an electrochemical cell involving two half-reactions from the table of standard reduction potentials, you should follow these steps:
1. Identify the two relevant half-reactions from the table.
2. Determine which half-reaction will act as the oxidation reaction (lose electrons) and which will act as the reduction reaction (gain electrons). The half-reaction with the higher standard reduction potential will be the reduction reaction, while the one with the lower standard reduction potential will be the oxidation reaction.
3. Write down the standard reduction potentials (E°) for both half-reactions.
4. Calculate the standard cell potential (E°cell) using the following formula:

E°cell = E°reduction - E°oxidation


By following these steps and using the table of standard reduction potentials, you can find the standard voltage of the electrochemical cell in question. Remember, the result should be expressed in volts (V).

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Which of these metals is the easiest to oxidize? a) sodium b) iron
c) aluminum
d) lithium
e) gold

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The easiest metal to oxidize among the given options is sodium (a). Sodium has only one valence electron, which makes it highly reactive with other elements. It readily loses this valence electron to form a sodium ion with a +1 charge. This reaction results in the formation of sodium oxide (Na2O) and sodium peroxide (Na2O2) when it reacts with oxygen.

Sodium is so reactive that it can even catch fire when exposed to air or water, making it a hazardous material. On the other hand, iron (b) and gold (d) are relatively stable metals and do not easily react with oxygen to form oxides. Lithium (c), although it has a similar valence electron configuration to sodium, is not as reactive as sodium due to its smaller atomic size and higher ionization energy.

In conclusion, among the given options, sodium is the easiest metal to oxidize due to its high reactivity and low ionization energy.

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how many molecules of can be formed when three molecules of are mixed with thirteen molecules of and the combustion reaction leads to the formation of and ?

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When three molecules of hydrocarbon, CH4 react with thirteen molecules of oxygen, O2 during a combustion reaction, the products formed are carbon dioxide (CO2) and water (H2O). This is the balanced reaction:
3 CH4 + 13 O2 → 3 CO2 + 6 H2O

In a combustion reaction, the fuel and oxidizing agent react in specific proportions to produce the products. For example, the combustion of methane (CH4) follows this balanced equation:
CH4 + 2 O2 -> CO2 + 2 H2O
Here, one molecule of methane reacts with two molecules of oxygen to form one molecule of carbon dioxide and two molecules of water. To determine the number of CO2 and H2O molecules formed when three fuel molecules react with thirteen O2 molecules, we must know the specific fuel being combusted and the balanced equation for the reaction, which is:
3 CH4 + 13 O2 → 3 CO2 + 6 H2O
Once the balanced equation is known, we can calculate the number of product molecules formed based on the provided reactant amounts, ensuring that the stoichiometric proportions are maintained.

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Select ALL that are true for a chemical reaction at equilibrium.
rate of forward reaction equals the rate of reverse reactions
The reaction has stopped.
∆G = 0
Q = K
K = 1

Answers



The true statements for a chemical reaction at equilibrium are:

1) rate of forward reaction equals the rate of reverse reactions
2) ∆G = 0
3) Q = K



At equilibrium, the forward and reverse reactions occur at the same rate, leading to a balance between the reactants and products. This means that the reaction has not stopped, but rather reached a stable state where the concentrations of the reactants and products do not change over time.

∆G represents the change in free energy between the reactants and products, and at equilibrium, ∆G = 0 since the system is at a minimum energy state.

The equilibrium constant, K, is the ratio of the concentrations of the products to the reactants at equilibrium. Q represents the same ratio at any given point in the reaction, but not necessarily at equilibrium. At equilibrium, Q = K, indicating that the concentrations of the reactants and products have reached a balance that corresponds to the equilibrium constant. K can be greater than, less than, or equal to 1 depending on the relative concentrations of the reactants and products.

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Identify the most common indicator.
thymol blue
phenolphthalein
thymolphthalein
crystal violet
alizarin

Answers

Among all the given option, Phenolphthalein is the Most Commonly Used Indicator in Chemistry.

What is the most commonly used indicator in chemistry and why?

Among the indicators listed, phenolphthalein is the most commonly used indicator in chemistry. It is a weak acid that displays different colors depending on the pH of the solution it is in. In acidic solutions, it appears colorless, while in basic solutions, it turns pink or magenta.

Its sensitivity to changes in pH and ease of use make it a popular choice in acid-base titrations and other experiments where pH is critical. Additionally, its low cost and availability contribute to its widespread use. Overall, phenolphthalein is a versatile and reliable indicator that plays an essential role in many laboratory applications.

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an isotope of tc having a half-life of 6.0 h is used in bone scans. if a certain amount of this tc is injected into the body, how long does it take for its initial decay rate to decrease by 99%?

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The initial decay rate will decrease by 99% after 5 half-lives of the isotope, according to the exponential decay formula.

Since the half-life of the isotope is 6.0 hours, the decay rate will decrease by 50% every 6.0 hours. Therefore, it will take 5 x 6.0 hours = 30 hours for the decay rate to decrease by 99%.

This means that after 30 hours, only 1% of the initial amount of the isotope will remain in the body. At this point, the amount of the isotope left in the body will be so small that it will no longer be detectable. It is important to note that the radiation exposure from the isotope during this time period is relatively low and poses no significant health risk.

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What is viscosity and what affects it?

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Viscosity is the measure of a fluid's resistance to flow. It is affected by several factors, including temperature, pressure, and the presence of other substances in the fluid.

What is fluid ?

Fluid is a substance that can flow and take the shape of its container. It can exist in either a liquid or a gas state, and can be composed of a variety of elements. Fluids are found in nature, such as water, air, and other liquids, and can also be created artificially in laboratories. Fluids are studied by scientists in the fields of physics, engineering, and chemistry. In physics, the study of fluids is known as fluid mechanics, and is used to understand how fluids move, the forces that act on them, and their behavior under different conditions. In engineering, fluid dynamics is used to design and analyze numerous industrial and engineering systems, such as air conditioning systems, engines, and pumps. In chemistry, the study of fluids is known as colloid science and is used to find out how particles interact in a fluid.

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Identify and briefly discuss the three spheres of influence used to identify the scope of problems and opportunities that software addresses.

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The three spheres of influence used to identify the scope of problems and opportunities that software addresses are: Control (at the centre), Influence, and Concern.

"Data frameworks that capability in the client's own area of impact satisfy their needs. By increasing their own effectiveness, users of these information systems can produce work of a higher quality and quantity. This kind of software is often referred to as personal productivity software.

When two or more people work together to accomplish a common goal, a workgroup is formed. A workgroup can be a short-term team assembled to finish a single project or a large official, long-term organizational unit like a division or department. The information system of a workgroup helps its members achieve their common goals.

Data frameworks that are essential for an association's effective reach let the organization interface with its current circumstance, which comprises of partners including purchasers, providers, investors, opponents, and particular vested parties as well as the monetary area and legislative associations.

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write balanced half-reactions for the following redox reaction: (aq)(g)(aq)(aq)(aq) 2co2 2no2 4oh c2o42- 2no3 2h2o

Answers

Oxidation: C₂O₄²⁻ (aq) --> 2CO₂ (g) + 4OH- (aq) and Exp.: The carbon in the oxalate ion (C₂O₄²⁻) is oxidized to CO₂ gas, while the four hydroxide ions are reduced.

What is nitrogen dioxide ?

Nitrogen dioxide (NO₂) is a colorless, toxic gas with a pungent odor. It is a major air pollutant, and is a by-product of burning fossil fuels in vehicles and power plants. Nitrogen dioxide is a major contributor to smog and acid rain, which can cause respiratory problems in humans, and damage plants and animals. It is also a major contributor to global warming, as it absorbs heat in the atmosphere.

Reduction: 2NO₂ (aq) --> 2NO³⁻ (aq) + 2H₂O (l)
Exp.: The two nitrite ions (NO₂) are reduced to nitrate ions (NO³⁻), while the two water molecules are oxidized.

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what volume does 1.00 moles of hydrogen gas occupy at a standard temperature and pressure (STP)

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The volume of 1.00 mole of hydrogen gas at STP is 22.4 liters,

What is the volume of the gas?

The ideal gas law is expressed as:

PV = nRT

Where P is the pressure of the gas, V is its volume, n is the number of moles of the gas, R is the universal gas constant, and T is the temperature of the gas in Kelvin.

At STP, the pressure and temperature are known, and we can use the ideal gas law to solve for the volume of 1.00 mole of hydrogen gas:

P = 1 atmn = 1.00 molesR = 0.08206 Latm/molKT = 273.15 K (0°C in Kelvin)

Plug these values into the ideal gas law equation:

PV = nRT

V = nRT/P

V = (1.00 mol × 0.08206 Latm/molK × 273.15 K) / (1 atm)

V = 22.4 L

Therefore, the volume of of the gas is 22.4 liters.

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what mass of magnesium hydroxide would be required for the magnesium hydroxide to react to the equivalence point with 558 ml of 3.18 m hydrochlo- ric acid?

Answers

Total, 51.7 grams of magnesium hydroxide would be required to react with 558 mL of 3.18 M hydrochloric acid.

To solve this problem, we can use the balanced chemical equation for the reaction between magnesium hydroxide and hydrochloric acid:

Mg(OH)₂ + 2HCl → MgCl₂ + 2H₂O

From the balanced equation, we can see that one mole of Mg(OH)₂ reacts with two moles of HCl. We can use this information, along with the volume and concentration of the hydrochloric acid, to calculate the moles of HCl present;

moles of HCl = volume of HCl x concentration of HCl

moles of HCl = 0.558 L x 3.18 mol/L

moles of HCl = 1.77444 mol

Since the reaction is a 1:2 ratio of Mg(OH)₂ to HCl, we need half as many moles of Mg(OH)₂;

moles of Mg(OH)₂ = 1/2 x moles of HCl

moles of Mg(OH)₂

= 1/2 x 1.77444 mol

moles of Mg(OH)₂ = 0.88722 mol

Finally, we can use the molar mass of Mg(OH)₂ to convert moles to grams;

mass of Mg(OH)₂ =moles of Mg(OH)₂ x molar mass of Mg(OH)₂

mass of Mg(OH)₂ = 0.88722 mol x 58.33 g/mol

mass of Mg(OH)₂ = 51.7 g

Therefore, 51.7 grams of magnesium hydroxide would be required.

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When choosing a solvent for recrystallization, the solute should dissolve in the solvent at room temperature.True / False

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True. When selecting a solvent for recrystallization, it is important to consider several factors, one of which is solubility. The solute should dissolve in the solvent at room temperature to ensure a successful recrystallization process.

If the solute does not dissolve in the solvent at room temperature, it may be necessary to use elevated temperatures to facilitate dissolution, which can lead to impurities being carried over into the final product.

Additionally, if the solvent is too polar or non-polar compared to the solute, the solute may not dissolve at all or only partially dissolve, resulting in a low yield or poor quality crystals.

Therefore, selecting a suitable solvent with appropriate polarity and solubility characteristics is essential to achieve a high-quality final product during recrystallization.

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explain why the melting point line is shorter than the boiling point line

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The melting point line is shorter than the boiling point line because melting occurs over a smaller temperature range than boiling.

The melting point line on a phase diagram represents the temperature and pressure conditions at which a substance changes from a solid to a liquid. The boiling point line represents the temperature and pressure conditions at which a substance changes from a liquid to a gas. The melting point line is shorter than the boiling point line because the phase transition from solid to liquid is less affected by changes in pressure than the phase transition from liquid to gas. When a substance melts, the intermolecular forces between particles weaken enough to allow the particles to slide past one another, resulting in a change of state. However, when a substance boils, the intermolecular forces must be completely overcome to allow the particles to become a gas, and the pressure must be kept constant. Therefore, the boiling point line is longer than the melting point line.

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order: abc 150 mg. stock: abc 8% solution. how many ml(s) will you give? (round the answer to the nearest tenth)

Answers

You would need to give approximately 18.8 ml of the ABC 8% solution to administer a 150 mg dose.

To calculate the required amount in milliliters, we need to use the following formula:

(required amount in ml) = (required dose in mg) / (concentration of stock solution in mg/ml)

Here, the required dose is 150 mg, and the concentration of the stock solution is 8% or 8 mg/ml.

So, putting the values in the formula, we get:

(required amount in ml) = 150 mg / 8 mg/ml

(required amount in ml) = 18.75 ml

Rounding off the answer to the nearest tenth, we get:

(required amount in ml) ≈ 18.8 ml

Therefore, you would need to give approximately 18.8 ml of the ABC 8% solution to administer a 150 mg dose.

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ammonia (nh3, 17.04 g/mol) is industrially produced from n2 and h2 using the haber process. what mass of h2 should be used if 34.0 kg nh3 must be the final yield when the reaction is run under conditions that produce only a 33.0% yield?

Answers

In industrial processes, ammonia (NH₃, 17.04 g/mol) is manufactured by combining nitrogen (N₂) and hydrogen (H₂) through a method known as the Haber process. 18.32 kg of H₂ is the mass of H₂ that should be used to produce 34.0 kg of NH₃ with a yield of 33.0%.

To determine the mass of H₂ required to achieve a final yield of 34.0 kg NH₃ with a yield of 33.0%, we need to use stoichiometry and the concept of percent yield.

The balanced equation for the production of ammonia from nitrogen and hydrogen is:

N₂ + 3H₂ → 2NH₃

According to the equation, 3 moles of hydrogen (H₂) are required to produce 2 moles of ammonia (NH₃).

Given:

Desired yield of NH₃ = 34.0 kg

Yield percentage = 33.0%

First, we calculate the theoretical yield of NH₃ based on the given yield percentage:

Theoretical yield of NH₃ = Desired yield / Yield percentage

Theoretical yield of NH₃ = 34.0 kg / (33.0/100) = 103.03 kg

Next, we determine the moles of NH₃ in the theoretical yield:

Moles of NH₃ = Theoretical yield / Molar mass of NH₃

Moles of NH₃ = 103.03 kg / 17.04 g/mol = 6045.74 mol

Since the stoichiometric ratio of H₂ to NH₃ is 3:2, we can calculate the moles of H₂ required:

Moles of H₂ = (3/2) × Moles of NH₃

Moles of H₂ = (3/2) × 6045.74 mol = 9068.61 mol

Finally, we convert the moles of H₂ to mass:

Mass of H₂ = Moles of H₂ × Molar mass of H₂

Mass of H₂ = 9068.61 mol × 2.02 g/mol = 18,324.35 g

Converting grams to kilograms:

Mass of H₂ = 18,324.35 g / 1000 = 18.32 kg

Therefore, the mass of H₂ that should be used to achieve a final yield of 34.0 kg NH₃ with a yield of 33.0% is approximately 18.32 kg.

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Complete question :

Ammonia (NH₃, 17.04 g/mol) is industrially produced from N₂ and H₂ using the Haber process. What mass of H₂ should be used if 34.0 kg NH₃ must be the final yield when the reaction is run under conditions that produce only a 33.0% yield?

18.3 kg 3.03 kg 6.05 kg 6.05 kg. You selected this answer. 36.6 kg 8.91 kg

In Reduction lab what was product given reaction 4-tert butylecyclohexanone and what was used to oxidize? (reduction lab)

Answers

Possible approach for the oxidation of 4-tert butylecyclohexanone using sodium hypochlorite as the oxidizing agent in the presence of a suitable solvent and catalyst.

What is a possible approach for oxidizing 4-tert butylecyclohexanone using sodium hypochlorite as the oxidizing agent?

In principle, the oxidation of 4-tert butylecyclohexanone could be achieved using a variety of oxidizing agents, depending on the desired reaction conditions and yield. For example, one possible approach would be to use sodium hypochlorite (NaClO) as the oxidizing agent, in the presence of a suitable solvent and catalyst. Under these conditions, the oxidation of 4-tert butylecyclohexanone might produce a mixture of products including 4-tert butylcyclohexanol and other related compounds.

It's important to note that the specific reaction conditions and outcome will depend on a range of factors such as the choice of oxidizing agent, the reaction time and temperature, and the purity and concentration of the starting materials. Without more information about the specific experiment you are referring to, it's difficult for me to provide a more precise answer.

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Select the true statement pertaining to this diagram
At 100 KPa of pressure water exists as a liquid at 300°C
As the pressure increases the boiling point increases
As the temperature and the pressure remains constant the water is more likely to remain a solid
Water can not exist as liquid above 100°C.

Answers

Answer:

As the pressure increases the boiling point increases.

Why do period 2 nonmetals form stronger pi bonds than period 3 nonmetals?

Answers

This is due to the fact that Period 3 elements have electrons at the third energy level, whereas Period 2 elements have electrons at the second energy level.

Non - metal:

On the right side of the periodic table are the nonmetals. Nonmetals have a dull appearance and are fairly brittle. They acquire electrons when they form ions. Additionally, they are poor heat and electricity conductors.

Period 3 non metal :

Period 3 elements that are not metals In period 3, the elements on the left-hand side of the periodic table, known as the s-block elements, are metals, while the elements on the right-hand side, known as the p-block elements, are nonmetals.

This implies that the metals are great conduits of power, while the nonmetals are unfortunate channels. There are, however, a few exceptions. Si, for instance, is a metalloid, which means that it has properties that are similar to those of metals and nonmetals. It is a semiconductor, and that implies it can lead power under specific circumstances yet not others.

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a sample ogf gas occupies 20 l under a pressure of 1 atm. what will its volume be if the pressure is increased to 2 atm

Answers

the final volume of the gas sample is 10 L when the pressure is increased from 1 atm to 2 atm.

To solve this problem, we can use the combined gas law, which relates the initial and final conditions of a gas sample undergoing a change in pressure, temperature, or volume, while keeping the number of moles constant.

The combined gas law equation is:

(P1V1) / T1 = (P2V2) / T2

where P1, V1, and T1 are the initial pressure, volume, and temperature of the gas sample, and P2, V2, and T2 are the final pressure, volume, and temperature of the gas sample.

In this case, we can assume that the temperature remains constant, so T1 = T2. We also know that the initial pressure is P1 = 1 atm, the initial volume is V1 = 20 L, and the final pressure is P2 = 2 atm. We want to find the final volume V2.

Substituting these values into the combined gas law equation, we get:

(1 atm) x (20 L) = (2 atm) x V2

Solving for V2, we get:

V2 = (1 atm) x (20 L) / (2 atm) = 10 L

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prove that the ideal gas law is a version of the combined gas law at stp

Answers

Answer:

Because universal gas constant and number of moles remains constant.

Explanation:

The ideal gas law is [tex]PV = nRT[/tex].

The combined gas law is [tex]P_1V_1/T_1 = P_2V_2/T_2[/tex].

The difference between the two is just n and R, which stand for the number of moles and the universal gas constant.

Putting the ideal gas law into the combined gas law form, you get [tex]P_1V_1/n_1R_1T_1 = P_2V_2/n_2R_2T_2[/tex].

However, since the number of moles won't change and at STP, the universal gas constant remains constant, you can cross those values out and get the combined gas law.

Final answer:

The ideal gas law is derived from the combined gas law at STP. The ideal gas law equation relates the pressure, volume, and temperature of a gas. At STP, the temperature is 273.15 K (0 °C) and the pressure is 1 atmosphere (atm).

Explanation:

The ideal gas law is derived from the combined gas law at STP (standard temperature and pressure).

The combined gas law equation relates the pressure, volume, and temperature of a gas. At STP, the temperature is 273.15 K (0 °C) and the pressure is 1 atmosphere (atm). Therefore, we can substitute these values into the combined gas law equation to obtain the ideal gas law equation.

The ideal gas law equation is expressed as: PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature in Kelvin.

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which of the following molecules will have 120 bond angles? group of answer choices a. ncl3 b. no answer c. bcl3 d. ph3 e. clf3

Answers

[tex]CIF_{3}[/tex] has 120 degree bond angles due to its trigonal bipyramidal molecular geometry with one lone pair and three bonded fluorine atoms.

What molecule has 120 degree bond angles and why?

The molecule that will have 120 degree bond angles is option E, [tex]ClF_{3}[/tex]. This is because [tex]ClF_{3}[/tex] has a trigonal bipyramidal molecular geometry with one lone pair and three bonded fluorine atoms. The three fluorine atoms are located in the equatorial plane of the molecule, creating 120 degree bond angles between them.

The lone pair of electrons is located in the axial position, perpendicular to the equatorial plane. The other options do not have a trigonal bipyramidal molecular geometry and therefore do not have bond angles of 120 degrees. [tex]ClF_{3}[/tex] has a trigonal pyramidal geometry with bond angles of 107 degrees, [tex]BCl_{3}[/tex] has a trigonal planar geometry with bond angles of 120 degrees, and [tex]PH_{3}[/tex] has a trigonal pyramidal geometry with bond angles of 93.5 degrees. No answer cannot be evaluated as there is no information to consider.

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1. What is the [OH-] of a 0. 255 M solution of pyridine, C5H5N? The Kb of C5H5N is 1. 69 x 10^-9.

2. What is the pH of a 0. 400 M solution of aniline, C6H5NH2? The Kb of C6H5NH2 is 4. 27 x 10^-10

Answers

The [tex][OH^-][/tex] of a [tex]0. 255 M[/tex] solution of pyridine, [tex]C_5H_5N[/tex] is [tex]4.30 * 10^{-10} M[/tex].

The pH of a [tex]0. 400 M[/tex] solution of aniline, [tex]C_6H_5NH_2[/tex] is [tex]9.98.[/tex]

1]  Pyridine [tex](C_5H_5N)[/tex] is a weak base, and its Kb value is given as [tex]1.69 * 10^{-9}[/tex]. To find the [tex][OH^-][/tex] of a [tex]0.255 M[/tex] solution of pyridine, we can use the following equation:

[tex]Kb = [OH^-][C_5H_5N]/[C_5H_5NH^+][/tex]

where [tex][C_5H_5NH^+][/tex]represents the concentration of the conjugate acid of pyridine, which is negligible compared to the concentration of pyridine.

Rearranging the equation and plugging in the values, we get:

[tex][OH^-] = Kb[C_5H_5N] / [C_5H_5NH^+]\\= (1.69 * 10^{-9})(0.255) / 1\\= 4.30 x 10^ {-10} M[/tex]

Therefore, the [tex][OH^-][/tex] of the solution is [tex]4.30 * 10^{-10} M.[/tex]

2] Aniline [tex](C_6H_5NH_2)[/tex] is also a weak base, and its Kb value is given as [tex]4.27 * 10^{-10}.[/tex] To find the pH of a  [tex]0.400 M[/tex] solution of aniline, we can use the following equation:

[tex]Kb = [OH^-][C_6H_5NH_2]/[C_6H_5NH_3^+][/tex]

where[tex][C_6H_5NH_3^+][/tex]represents the concentration of the conjugate acid of aniline, which is formed when aniline accepts a proton from water.

We can assume that [tex]x[/tex] moles of aniline react with water to form [tex]x[/tex] moles of [tex]C_6H_5NH_3^+[/tex] and [tex]x[/tex] moles of [tex]OH^-[/tex]. Therefore, the initial concentration of aniline, [tex][C_6H_5NH_2][/tex], will decrease by [tex]x[/tex], while the concentrations of [tex][C_6H_5NH_3^+][/tex] and [tex][OH^-][/tex] will increase by [tex]x[/tex]. At equilibrium, we can express the concentrations as given follows:

[tex][C_6H_5NH_2] = 0.400 - x[/tex]

[tex][C_6H_5NH_3^+] = x[/tex]

[tex][OH^-] = x[/tex]

The value of [tex]x[/tex] can be determined using the Kb expression:

[tex]Kb = [OH^-][C_6H_5NH_2]/[C_6H_5NH_3^+]\\\\x = \sqrt{(Kb[C_6H_5NH_2]/[C_6H_5NH_3^+])} \\= \sqrt{((4.27 * 10^{-10})(0.400) / 1)}\\= 1.04 * 10^{-5} M[/tex]

Therefore, the [tex][OH^-][/tex] of the solution is[tex]1.04 * 10^{-5} M,[/tex] and the pH can be calculated using the expression:

[tex]pH = 14 - pOH\\= 14 - log([OH^-])\\= 14 - log(1.04 * 10^{-5})\\= 9.98[/tex]

Therefore, the pH of the solution is [tex]9.98[/tex].

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when you add acid to a buffer, how do you calculate the new pH?

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To calculate the pH, the equation which represents an acid-base or a buffer solution is represented below is used.

pH = pKₐ + log([A⁻]/[HA])

One way to determine the pH of a buffer is by using the Henderson–Hasselbalch equation, which is

pH = pKₐ + log([A⁻]/[HA])

In the above equation, [HA] and [A⁻] refer to the equilibrium concentrations of the conjugate acid–base pair used to create the buffer solution. For the titration of a weak acid with a strong base, the pH curve is initially acidic and has a basic equivalence point (pH > 7). The section of curve between the initial point and the equivalence point is known as the buffer region.

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what was most often the primary catalyst in underwood's study of siblicide? group of answer choices c. an argument a. sexual advances d. betrayal b. alcohol

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The primary catalyst in Underwood's study of siblicide was betrayal.

What is siblicide?

Siblicide is the killing of one’s own sibling. It is a rare form of homicide that occurs in some animal species, including some primates, dolphins, and birds. In humans, it is a very rare occurrence, and is often the result of a mental disorder or extreme psychological distress. Siblicide is often seen as a desperate act of competition for resources, typically parental attention or resources within the family. In some cases, siblicide can be driven by jealousy or even a desire for revenge. In other cases, it may be the result of a misunderstanding or miscommunication.

Underwood's study focused on the cases in which a sibling had killed another sibling out of betrayal, either from a feeling of being wronged by the other sibling or from feeling betrayed by the sibling.

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Calculate the pH of 0.14 M NaF solution.
a. 8.09
b. 8.12
c. 8.14
d. 8.18
e. 8.21

Answers

The pH of a solution can be calculated using the formula pH = -log[H+], where [H+] is the concentration of hydrogen ions in the solution. In the case of a NaF solution, the F- ion will react with water to form HF and OH- ions according to the following equation  the correct answer is a. 8.09.

F- + H2O ⇌ HF + OH-  The HF formed will then react with water to form H3O+ ions and F- ions: HF + H2O ⇌ H3O+ + F-
Since F- is a weak base, it will react with the H3O+ ions produced by the HF to form more HF and H2O:
F- + H3O+ ⇌ HF + H2O
This means that the concentration of H3O+ ions in the solution will be lower than that in pure water, resulting in a pH higher than 7.0. To calculate the pH of the NaF solution, we need to first determine the concentration of H3O+ ions. This can be done using the equilibrium constant expression for the reaction: Kw = [H3O+][OH-] = 1.0 x 10^-14
Since the solution is not neutral, we can assume that the [OH-] concentration is very small compared to the [H3O+] concentration. Therefore, we can simplify the expression to: [H3O+] ≈ Kw/[OH-] ≈ 1.0 x 10^-14/[F-]
Substituting the given concentration of NaF into this expression, we get: [H3O+] ≈ 1.0 x 10^-14/0.14 = 7.14 x 10^-14
Taking the negative logarithm of this value gives us the pH of the solution: pH ≈ -log(7.14 x 10^-14) ≈ 8.09

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Which is not a strong acid?
(A) sulfuric acid. (B) nitric acid. (C) hydrochloric acid. (D) hydrofluoric acid. (E) hydroiodic acid.

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(D) Hydrofluoric acid is not a strong acid. While it is a highly corrosive and dangerous acid, it is not classified as a strong acid because it does not completely dissociate in water to produce H+ ions.

Hydroiodic acid (HI), on the other hand, is considered a strong acid only in concentrated form. In dilute solutions, it behaves as a weak acid, meaning that it does not dissociate completely in solution, resulting in a lower concentration of H+ ions. Therefore, hydroiodic acid is not considered a strong acid under normal conditions. Strong acids such as sulfuric acid, nitric acid, hydrochloric acid, and hydroiodic acid fully ionize in water to produce H+ ions.

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A sample of gas contains 0.1200 mol of CH4(g) and 0.1200 mol of H2O(g) and occupies a volume of 14.9 L. The following reaction takes place: CH4(g) + H2O(g)â+3H2(g) + CO(g) Calculate the volume of the sample after the reaction takes place, assuming that the temperature and the pressure remain constant. OL A sample of gas contains 0.1100 mol of CO(g) and 0.1100 mol of NO(g) and occupies a volume of 8.72 L. The following reaction takes place: 2CO(g) + 2NO(g)â>2002(g) + N2(g) Calculate the volume of the sample after the reaction takes place, assuming that the temperature and the pressure remain constant.

Answers

The total volume before reaction will be 29.8 L and the volume  after reaction will be 6.54 L.

Elaborating:

 CH₄ + H₂O ----- 3H₂ + CO

O.120   0.120

0            0 ---- 3× 0.120   0.120

Total no of moles before reaction =2 × 0.120

                                             = 0.24 mol

Total no. of moles after reaction = 3 × 0.120 + 0.120

                                            = 0.48 mol

        PV= nRT

          V∝ n

         V₁ / n₁ = V₂ / n₂

      14.9 / 0.24 = V₂ / 0.48

            V₂ = 29.8 L

2.         2CO + 2NO ⇒ 2CO₂ + N₂

          0.11          0.11           0         0

           0               0          0.11      0.055

Total no. of moles before reaction =0.11 + 0.11 = 0.22 moles

Total no. of moles  after reaction = 0.11 + 0.055 = 0.0165 mol

                               V₁/n₁ = V₂ / n₂

                8.72/ 0.22 = V₂/ 0.165

                     V₂ = 6.54 L

With an example, what is a mole?

The quantity of a substance containing the same number of elementary entities—atoms, molecules, ions, electrons, radicals, etc.—is referred to as a mole. as there are particles in 12 grams of carbon - 12. A substance's relative molecular mass in grams is equal to one mole's mass.

Why is the mole idea used?

We can count atoms and molecules by weighing macroscopically small amounts of matter using the mole concept because atoms and molecules are so small. It establishes a benchmark for determining reaction stoichiometry. It explains the characteristics of gases.

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How can we recover our crystals after vacuum filtration and drying?

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After vacuum filtration and drying, the crystals can be recovered using several methods. One common method is to scrape the crystals from the filter paper using a spatula or other scraping tool.

Care should be taken to avoid damaging the crystals or the filter paper during this process. Another method is to rinse the filter paper with a small amount of solvent, such as ethanol or water, to dissolve any remaining crystals and transfer them to a container. The solvent can then be evaporated, leaving behind the crystals. If the crystals are particularly small or difficult to collect, a technique called "washing" can be used. This involves adding a small amount of solvent to the crystals and agitating the mixture to dislodge the crystals from the filter paper. The resulting solution can then be collected and the crystals recovered by evaporating the solvent. Overall, the recovery method used will depend on the nature and quantity of the crystals, as well as the equipment and resources available.

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Which of these ions triggers exocytosis of synaptic vesicles.

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The ion that triggers exocytosis of synaptic vesicles is calcium (Ca2+) ion.

When an action potential reaches the end of an axon, it triggers the opening of voltage-gated calcium channels in the presynaptic membrane. This allows calcium ions to enter the presynaptic terminal and bind to specific proteins on the surface of synaptic vesicles, causing them to fuse with the presynaptic membrane and release their neurotransmitter content into the synaptic cleft.

The influx of calcium ions into the presynaptic terminal is a critical step in the process of neurotransmitter release, and it is tightly regulated by various factors, such as the frequency and duration of the action potential, the availability of calcium ions, and the activity of calcium-binding proteins.

the release of neurotransmitters from synaptic vesicles via exocytosis is a fundamental mechanism for neuronal communication and synaptic plasticity, and it plays a crucial role in various physiological and pathological processes in the nervous system.

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