An ideal gaseous reaction occurs at a constant pressure of 35.0 atm and releases 66.8 kJ of heat. Before the reaction, the volume of the system was 8.20 L. After the reaction, the volume of the system was 2.21 L. Calculate the total change in internal energy for the system. Enter your answer numerically in units of kJ.

Answer:

The molarity is 0.359[tex]\frac{moles}{L}[/tex]

The molality is 0.354 [tex]\frac{moles}{kg}[/tex]

The mass percent of the solution es 3.45%

Explanation:

Molarity is a unit of concentration that indicates the amount of moles of solute that appear dissolved in each liter of the mixture. It is determined by:

[tex]Molarity (M)=\frac{number of moles of solute}{volume}[/tex]

Being:

The molar mass of KNO₃ is:

KNO₃=  39 g/mole + 14 g/mole + 3*16 g/mole= 101 g/mole

You can apply the following rule of three: if 101 grams of KNO₃ are present in 1 mole, 72.5 grams in how many moles are present?

[tex]moles of KNO_{3}=\frac{72.5 grams*1 mole}{101 grams}[/tex]

moles of KNO₃= 0.718

So you have:

Applying this quantity in the definition of molarity:

[tex]molarity=\frac{0.718 moles}{2 L}[/tex]

Molarity= 0.359[tex]\frac{moles}{L}[/tex]

The molarity is 0.359[tex]\frac{moles}{L}[/tex]

Molality is a way of measuring the concentration of solute in solvent and indicates the amount of moles of solute in each kilogram of solvent.

Then the molality is calculated by:

[tex]Molality=\frac{moles of solute}{mass of solvent in kilograms}[/tex]

Density is defined as the property that matter, whether solid, liquid or gas, has to compress in a given space. That is, it is the amount of mass per unit volume. So, if the density of 1.05 g / mL for the solution indicates that in 1 mL of solution there are 1.05 grams of solution, in 2000 mL (where 2L = 2000 mL, because 1 L = 1000mL) how much mass is there?

[tex]mass=\frac{2000 mL*1.05 grams}{1 mL}[/tex]

mass= 2100 grams

Since mass solution = mass water + mass KNO₃

then mass water = mass solution - mass KNO₃

Being mass solution 2100 grams and mass KNO₃ 72.5 grams, and replacing you get: mass water= 2100 grams - 72.5 grams

mass water= 2,027.5 grams

Then, being:

Replacing in the definition of molality:

[tex]molality=\frac{0.718 moles}{2.0275 kg}[/tex]

molality= 0.354 [tex]\frac{moles}{kg}[/tex]

The molality is 0.354 [tex]\frac{moles}{kg}[/tex]

The mass percent of a solution is the number of grams of solute per 100 grams of solution. Then the mass percent is the mass of the element or solute divided by the mass of the compound or solute and the result of which is multiplied by 100 to give a percentage.

[tex]mass percent=\frac{mass of solute}{mass of solution} *100[/tex]

So, in this case:

[tex]mass percent=\frac{72.5 grams}{2100 grams} *100[/tex]

mass percent= 3.45 % KNO₃ by mass

The mass percent of the solution es 3.45%

The molarity of the solution is 0.36 mol/L. The molality of the solution is 0.34 m. The mass percent of the solution is   3.33%.

Number of moles of  KNO3 = mass/molar mass =  72.5 g/101 g/mol = 0.72 moles

Molarity = Number of moles / volume =  0.72 moles/ 2.00 L = 0.36 mol/L

The molality = Number of moles of solute/Mass of solution in kilograms

mass of solution =  1.05 g/mL × 2000 mL = 21000 g or 2.1Kg

Molality of solution =  0.72 moles/2.1 Kg = 0.34 m

Mass percent of solution = mass of solute/mass of solution × 100/1

Mass percent of solution =  72.5 g/ (72.5 g + 2100 g) × 100/1

= 3.33%

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Answer:

E. The ratio of [HNO2] / [NO2-] will increase

D. The pH will decrease.

Explanation:

Nitrous acid ( HNO₂ ) is a weak acid and NaNO₂ is its salt . The mixture makes a buffer solution .

pH = pka + log [ salt] / [ Acid ]

= 3.4 + log .32 / .42

= 3.4 - .118

= 3.282 .

Now .16 moles of nitric acid is added which will react with salt to form acid

HNO₃ + NaNO₂ = HNO₂ + NaNO₃

concentration of nitrous acid will be increased and concentration of sodium nitrite ( salt will decrease )

concentration of nitrous acid = .42 + .16 = .58 M

concentration of salt = .32 - .16 = .16 M

ratio of [HNO₂ ] / NO₂⁻]

= .42 / .32 = 1.3125

ratio of [HNO₂ ] / NO₂⁻] after reaction

= .42 + .16 / .32 - .16

= 58 / 16

= 3.625 .

ratio will increase.

Option E is the answer .

pH after reaction

= 3.4 + log .16 / .58

= 2.84

pH will decrease.

Answer:

answer is in exaplation

Explanation:

Answer. Chemical reaction had occurred and both the powders are different substances.

Explanation:

As density is an intensive property of the substance.Which means that different substance have different densities.

Density = \frac{mass}{volume}

volume

mass

Density of powder 1, d_1=\frac{0.5g}{45cm^3}=0.11g/cm^3d

1

=

45cm

3

0.5g

=0.11g/cm

3

Density of powder 2, d_2=\frac{1.3g}{65cm^3}=0.02g/cm^3d

2

=

65cm

3

1.3g

=0.02g/cm

3

On comparing both the densities of the powders we can say that both the substances are different. So we can conclude that the chemical reaction had occurred.

Answer: 8 (feet)

Explanation:

24 inches = 2 feet

48 inches = 4 feet

12 inches = 1 foot

To find volume you do Base * Width * Height

2*4*1 = 8

Hope this helps!

The correct answer is  8 (feet).

How to calculate ?

Therefore, 2*4*1 = 8

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Answer:

pH of the acid

Explanation:

Answer:

7 mol

Explanation:

Caffeine molecular formula C8H10N4O2. It has 2 atoms of oxygen.

                          C8H10N4O2         - 2O

                           1 mol                        2 mol

                           3.5 mol                    x mol

x = 3.5*2/1 = 7 mol

Answer:

an atom with a half-filled subshell - hydrogen

an atom with a completely filled outer shell - argon

an atom with its outer electrons occupying a half-filled subshell and a filled subshell- copper

Explanation:

The outermost shell or the valence shell of the atom is the last shell in the atom. Chemical reactions occur at this outer most shell. The number of electrons on the outermost shell of an atom determines the group to which it belongs in the periodic table as well as its chemical properties.

Hydrogen has a half filled 1s sublevel. Only one electron is present in this sublevel.

Let us consider argon

1s2 2s2 2p6 3s2 3p6

The outermost ns and np levels are completely filled. Thus the outermost shell is completely filled.

In the last case; let us look at the electronic configuration of nitrogen;

1s2 2s2 2p3

The outermost 2p subshell is exactly half filled while the 2s sublevel is fully filled. The outermost shell of nitrogen is made up of 2s2 and 2p3 sublevels.

Answer:

24 carbons

48 hydrogens

24 oxygen

Explanation:

Answer:

b) sp^2

Explanation:

Hybridization refers to the concept that atomic orbitals fuse to form newly hybridized orbitals, which in turn, influences molecular geometry and bonding properties. In chemistry, orbital hybridisation (or hybridization) is the implies the mixing of atomic orbitals to form hybrid orbitals (with different energies, shapes, etc., different from that of the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds according to the principles of the valence bond theory.

In 1931 Linus Pauling proposed the idea of “mixing” the orbitals or “hybridizing” them to account for certain observed bonding patterns. Pauling proposed a sort of a combination of the orbitals giving you an orbital that has partial characters.

Hybridization is merely a mathematical construct. It is never an actual “process” that occurs within orbitals . Hybridization is a mathematical model that describes how the atomic orbitals would’ve looked like based on the observable molecular orbitals.

sp2 hybridization leads to the formation of a double bond. sigma bonds may also be formed depending on the valency of the central atom. In alkenes, an sp2 hybridized carbon atom forms a double bond in addition to two sigma bonds to other atoms.

The predicted hybridization is:

b) [tex]sp^2[/tex]

It is the integration of atomic orbitals to shape new orbitals with exclusive energies and shapes than the unique orbitals.

Given: An atom that's surrounded with the aid of using a double bond and unmarried bonds.

[tex]sp^2[/tex]  hybridization ends in the formation of a double bond. sigma bonds can also be shaped relying at the valency alkenes, an   [tex]sp^2[/tex]sigma bonds to different atoms.

Thus, correct option is b.

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Answer:

D

Explanation:

trust me its correct i think

answer

1)maximise your software efficiency

2)Prevention against viruses and malware

3)Early detection of problematic issues

4)prevent data loss

5)Speed up your computer

Answer:

pH = - log [concentration]

pH = - log (0.0043M)

pH = 2.37

Answer:

Some of the methods in Methods in electrochemistry that can be used for the separation of proteins and enzymes are as follows:

Redox transformations: In this method enzymes or proteins would be adsorbed on the electrode surface and facilitates direct electron transfer that causes denaturation and loss of their electrochemical activities and bioactivities. It is widely used in biosensors and biofuel cells.

Protein electrophoresis: In this process proteins are seperated by placing them in a gel matrix in the presence of an electrical field. In this method a negative charge is applied so that proteins move towards a positive charge.

Answer:

Part A

The natural abundance of Si-30 = 3.1

Part B

The mass of Si-30 = 29.9551 amu

Explanation:

Part A

The sum of the natural abundances = 100

Si-28 has a mass of 27.9769 amu and a natural abundance of 92.2%.

Si-29 has a mass of 28.9765 amu and a natural abundance of 4.67%

Si-30's mass and natural abundance are unknown.

Natural abundance for Si-30 = 100% - 92.2% - 4.67% = 3.13% = 3.1% to 2 s.f.

Part B

The total atomic mass of an element is an addition combination of the mass and natural abundances of all the isotopes of that element.

Molar mass of Silicon normally = 28.0855 amu

Let the mass of Si-30 be m

28.0855 = (27.9769×0.922) + (28.9765×0.0467) + (m×0.0313)

28.0855 = 27.14790435 + 0.0313m

0.0313m = 28.0855 - 27.14790435 = 0.93759565

m = (0.93759565/0.0313) = 29.9551325879 amu = 29.9551 amu

Hope this Helps!!

Part A:  The natural abundance of Si-30 = 3.1

  Lets solve the question:

Natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet.

Natural abundance for Si-30 = [tex]100\% - 92.2\% - 4.67\% = 3.13\% = 3.1\%[/tex] in significant figures.

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Answer:

vaporization

Explanation:

The molar enthapy of _vaporization______ is the heat required to vaporize one mole of a liquid”

Answer:

0.031 m

HgO(s) ⇒ Hg(l) + 1/2 O₂(g)

Chemical change

Element

Explanation:

A 75 gram solid cube of mercury (II) oxide has a density of 2.4 × 10³ kg/m³.  What is the length of one side of the cube in cm?

Step 1: Convert the mass to kilograms

We will use the relationship 1 kg = 1,000 g.

[tex]75g \times \frac{1kg}{1,000g} = 0.075kg[/tex]

Step 2: Calculate the volume (V) of the cube

[tex]0.075kg \times \frac{1m^{3} }{2.4 \times 10^{3} kg} = 3.1 \times 10^{-5} m^{3}[/tex]

Step 3: Calculate the length (l) of one side of the cube

We will use the following expression.

[tex]V = l^{3} \\l = \sqrt[3]{V} = \sqrt[3]{3.1 \times 10^{-5} m^{3} }=0.031m[/tex]

The mercury (II) oxide completely dissociates and forms liquid mercury and oxygen gas. Write a balanced chemical equation and indicate if this process is a chemical or physical change?

The balanced chemical equation is:

HgO(s) ⇒ Hg(l) + 1/2 O₂(g)

This is a chemical change because new substances are formed.

The oxygen gas escapes and now you are left with liquid grey substance. Is this grey substance a compound, element, homogeneous mixture or heterogeneous mixture?

The liquid gray substance is Hg(l), which is an element because it is formed by just one kind of atoms.

Answer:

[tex]M=0.0637M[/tex]

Explanation:

Hello,

In this case, the undergoing chemical reaction is:

[tex]Pb(NO_3)_2(aq)+2NaI(aq)\rightarrow PbI_2(s)+2NaNO_3(aq)[/tex]

Thus, for 0.904 g of precipitate, that is lead (II) iodide, we can compute the initial moles of lead (II) ions in lead (II) nitrate:

[tex]n_{Pb^{2+}}=0.904gPbI_2*\frac{1molPbI_2}{461gPbI_2}*\frac{1molPb(NO_3)_2}{1molPbI_2} *\frac{1molPb^{2+}}{1molPb(NO_3)_2} =1.96x10^{-3}molPb^{2+}[/tex]

Finally, the resulting molarity in 30.8 mL (0.0308 L):

[tex]M=\frac{1.96x10^{-3}molPb^{2+}}{0.0308L}\\ \\M=0.0637M[/tex]

Regards.

Answer:

D

Explanation:

gr. 2.3 at 25°C; valence +3. Boron is a nonmetallic element existing as a dark brown to black amorphous powder or as an extremely hard, usually jet-black to silver-gray, brittle, lustrous, metallike crystalline solid

it is a network solid, a lattice of many covalent bonds (like diamond, except that it is black rather than transparent).

Network solid kind of solid is crystalline boron (B). Hence, option D is correct.

A network solid is a solid where all the atoms are covalently bonded in a continuous network.

Boron is a nonmetallic element existing as a dark brown to black amorphous powder or as an extremely hard, usually jet-black to silver-grey, brittle, lustrous, metallike crystalline solid

It is a network solid, a lattice of many covalent bonds (like a diamond, except that it is black rather than transparent).

Hence, option D is correct.

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Answer:

Molarity: 0.111M

% (w/w): 0.666

Explanation:

The reaction of NaOH with acetic acid (CH₃COOH) is:

NaOH + CH₃COOH → CH₃COO⁻Na⁺ + H₂O

where 1 mole of NaOH reacts per mole of acetic acid producing 1 mole of water and 1 mole of sodium acetate.

As 39.26mL ≡ 0.03926L of 0.1062M are required to titrate the solution of acetic acid. Moles are:

0.03926L × (0.1062mol / L) = 4.169x10⁻³ moles of NaOH. As 1 mole of NaOH reacts per mole of acetic acid:

4.169x10⁻³ moles of CH₃COOH.

Molarity is defined as ratio between moles of substance and volume of solution in liters. Thus, molarity of acetic acid solution is:

4.169x10⁻³ moles of CH₃COOH / 0.03754L = 0.111M

As molar mass of acetic acid is 60g/mol, 4.169x10⁻³ moles weights:

4.169x10⁻³ moles × (60g / mol) = 0.2501 g of acetic acid

Now, assuming density of solution as 1.00g/mL, 37.54mL weights 37.54g.

Thus, percent by weight is:

0.2501g CH₃COOH / 37.54g × 100 = 0.666% (w/w)

The molarity of acetic acid is 0.11M and the percent by weight is 0.666%.

Molarity of any solution is used to define their concentration and it will be calculated as:

M = n/V, where

n = moles

V = volume

Molarity of acetic acid will be calculated as:

M₁V₁ = M₂V₂, where

M₁ = molarity of acetic acid = ?

V₁ = volume of acetic acid = 37.54mL = 0.037L

M₂ = molarity of NaOH = 0.1062M

V₂ = volume of NaOH = 39.26mL = 0.039L

On putting all these values on the above equation we can calculate the molarity as:

M₁ = (0.1062)(39.26) / (37.54) = 0.11M

Now we calculate the moles of acetic acid by using the molarity formula as:

n = 0.11M × 0.037L = 0.00407 moles

Molar mass of acetic acid = 60g/mole

Mass of 0.00407 moles of acetic acid = 4.1x10⁻³ moles×(60g / mol) = 0.2501 g

Density of solution = 1.00 g/mL

So, 37.54mL in 1g/mL = 37.54g/mL

Percent by weight will be calculated as:

%w/w = 0.2501g CH₃COOH / 37.54g × 100 = 0.666% (w/w)

Hence, molarity and %(w/w) of acetic acid is 0.11M and 0.666% respectively.

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Answer:

Ozone has dipole moments because its molecular chemical structure is no linear.

Explanation:

This molecular form refers to the geometry of said gas, which is potentially toxic and dangerous.

This non-linear geometric shape is what makes it have dipolarity.

Answer:

A. the law of constant composition

Explanation:

The molecules in the container would have the same composition because they would have traded around atoms until an equilibrium was reached with every molecule having 1 Hydrogen and 1 Chlorine.

Answer:

Explanation:

The objective here is to prepare  1 liter of LB + Kan (100 μg/ml final concentration) + Amp (50 μg /ml final concentration) liquid media.

Given that :

the Stock concentration of Amp: 100 mg/ml (since 1 mg/ml = 1000 μg/ml)

it is required that we convert stock concentration in  μg/ml since 100 mg/ml = 100000  μg/ml

However, using formula C₁V₁=C₂V₂ (Ampicilin),

where:

C₁ = 100000 μg/ml,

V₁=?,

C₂= 50  μg/ml,

V₂=1000 ml

100000 μg/ml × V₁ = 50  μg/ml × 1000 ml

V₁ =  50  μg/ml × 1000 ml/100000 μg/ml

V₁ =   0.5 ml

Given that:

the Stock concentration of Kan: 25 mg/ml (since 1 mg/ml = 1000 μg/ml)

it is required that we convert stock concentration in  μg/ml , 25 mg/ml = 25000 μg/ml

Now by using formula C₁V₁=C₂V₂ (Kanamycin),

C₁ = 25000 μg/ml,

V₁=?,

C₂= 100  μg/ml,

V₂=1000 ml

25000 μg/ml × V₁ = 100  μg/ml × 1000 ml

V₁ =  100  μg/ml × 1000 ml/25000 μg/ml

V₁ =   4 ml

Thus; in 1 lite of Lb+ Kan+Amp preparation;

0.5 ml of Amp & 4 ml of kanamycin is used for their stock preparation.

Finally;

Sterilization step should be carried out in flask (Clean dry glass wares) for media in an autoclave, the container size should be twice the volume of media which is prepared.

Answer:

(a) [tex]m=2.69m[/tex]

(b) [tex]x_{LiBr}=0.099[/tex]

(c) [tex]\% LiBr=18.9\%[/tex]

Explanation:

Hello,

In this case, given the molality in mol/L, we can compute the required units of concentration assuming a 1-L solution of acetonitrile and lithium bromide that has 1.80 moles of lithium bromide:

(a) For the molality, we first compute the grams of lithium bromide in 1.80 moles by using its molar mass:

[tex]m_{LiBr}=1.80mol*\frac{86.845 g}{1mol}=156.32g[/tex]

Next, we compute the mass of the solution:

[tex]m_{solution}=1L*0.826\frac{g}{mL}*\frac{1000mL}{1L}=826g[/tex]

Then, the mass of the solvent (acetonitrile) in kg:

[tex]m_{solvent}=(826g-156.32g)*\frac{1kg}{1000g}=0.670kg[/tex]

Finally, the molality:

[tex]m=\frac{1.80mol}{0.670kg} \\\\m=2.69m[/tex]

(b) For the mole fraction, we first compute the moles of solvent (acetonitrile):

[tex]n_{solvent}=669.68g*\frac{1mol}{41.05 g} =16.31mol[/tex]

Then, the mole fraction of lithium bromide:

[tex]x_{LiBr}=\frac{1.80mol}{1.80mol+16.31mol}\\ \\x_{LiBr}=0.099[/tex]

(c) Finally, the mass percentage with the previously computed masses:

[tex]\% LiBr=\frac{156.32g}{826g}*100\%\\ \\\% LiBr=18.9\%[/tex]

Regards.

Answer:

Explanation:

Step 1: NaCl(s) → Na(s) + 1/2 Cl2(g)  ΔHf   (ionization energy) in this step energy is required to change the phase of the compound

Step 2: Na(s) + 1/2 Cl2(g) → Na(g) + 1/2 Cl2(g)  ΔHa  (elements needed to be in gaseous state for born-haber cycle so metal changes from solid to gas state by changing the enthalpy.

Step 3: Na(g) + 1/2 Cl2(g) → Na(g) + Cl (g)  1/2ΔHd  

Step 4: Na(g) + Cl(g) → Na⁺(g) + Cl⁻(g)  IE+EA  ( in this step both ionization energy and electron affinity was involved because in metal (Na) electron is added which needs the energy and this energy draw from the step 3 and Chlorine require releasing electron to be in ionic state so when electron leaves the orbit energy releases.

Step 5: final step is Hess Law which is the combination of all the steps which step 4 again go back to step 5 and this cycle continues by repeating same steps    Na⁺(g) + Cl⁻(g)→NaCl(s)

at this step heat of formation is calculated

Heat of formation= atomization energy+ dissociation energy+ sum of ionization energies + sum of electron affinity + lattice energy.

2:  if we look at the electron configuration of the nitrogen it has 5 electrons in its outermost shell which indicates it can make 5 bonds 4 bonds and 1 lone pair usually and Oxygen has 6 electrons in its outermost shell. So nitrate ion have the total number of 24 electrons including the 1 electron which shows on the compound.

So when they make nitrate ion NO₃⁻¹ it shows that nitrate has 3 resonance structures. Nitrogen's three sigma bonds are attached to oxygen and fourth one make 1 pie bond which can rotate, delocalized and change its position anytime from one Oxygen atom to other oxygen atom.

Answer:

C6H6<C7H15OH<C6H13OH<C2H5OH​

Explanation:

Organic substances are ordinarily nonpolar. This means that they do not dissolve in water. However, certain homologous series of organic compounds actually dissolve in water because they possess certain functional groups that effectively interact with water via hydrogen bonding.

A typical example of this is alcohol family. All members of this homologous series contain the -OH functional group. This group can effectively interact with water via hydrogen bonding, leading to the dissolution of low molecular weight alcohols in water.

Low molecular weight alcohols are miscible with water in all proportions. This implies that they are highly soluble in water. However, as the size of the alkyl moiety in the alcohol increases, the solubility of the alcohol in water decreases due to less effective interaction of the -OH group with water via hydrogen bonding. This explains the fact that C2H5OH​ is the most soluble alcohol in the list.

C6H6 is insoluble in water since it is purely a hydrocarbon with no -OH group capable of interaction with water via hydrogen bonding.

Answer:

[tex]m=20kg[/tex]

Explanation:

Hello,

In this case, we define the kinnetic energy as:

[tex]K=\frac{1}{2} m*v^2[/tex]

Thus, for finding the mass we simply solve for it on the previous equation given the kinetic energy and the velocity:

[tex]m=\frac{2*K}{v^2}=\frac{500kg*\frac{m^2}{s^2} }{(5\frac{m}{s})^2} =\frac{500kg*\frac{m^2}{s^2} }{25\frac{m^2}{s^2}}\\\\m=20kg[/tex]

Best regards.

Answer:

The answer is 40 kg

Explanation:

You will this formula below:

m=[tex]\frac{2*\\KE}{v^{2} }[/tex]

Now we know our formula, now we plug in the given numbers:

m=[tex]\frac{2(500J)}{(5m/s)^2}[/tex]

Simplify and we get:

m=40 kg

I hope this was helpful.

Answer:

Gold(III) chloride

Answer:

N2H4

Explanation:

A hydride is a binary compound of hydrogen and another element. Binary compounds contain only two atoms. We have to x-ray the hydrides of nitrogen given in the question in order to make our choice. Remember that we were told that that the hydride contains its own volume of nitrogen and twice its volume of hydrogen.

Now consider the hydride N2H4.

N2H4(g) -----> N2(g) + 2H2(g)

The volume ration of nitrogen gas to hydrogen gas in N2H4 is 1:2.

The molecular mass of the compound is;

N2H4= 2(14) + 4(1)= 28+4= 32

Since

molecular mass= 2 vapour density

Vapour density= molecular mass/2

Vapour density= 32/2

Vapour density = 16

Therefore the hydride of nitrogen referred to in the question is N2H4

Answer:I hope it will be beneficial for you

Force of attraction between the particles of solid is very strong the particles of solid are held together by strong inter molecular forces leading to the formation of a rigid structure

Force of attraction between the particles of the liquid is weak as compare to solids there particles are far away from each other and have the property to move easily.

Force of attraction between the particles of gases is very weak than the two states hence the particles of gases are highly compressible having week intermolecular interaction between them and have indefinite shape and volume

Answer:

Forces between particles in Liquids are closely packed  compared to other states of matter like the liquid and gaseous state of matter.

Explanation:

Answer : The correct answer is 1.46

Explanation :

The following rules are used to round off a number to the required number of significant figures:

(1) If the rightmost digit to be removed is more than 5, the preceding number is increased by one.

(2) If the rightmost digit to be removed is less than 5, the preceding number is not changed.

(3) If the rightmost digit to be removed is 5, then the preceding number is not changed if it is an even number but it is increased by one if it is an odd number.

(4) The same procedure is follow for decimal values.

As we are given, 1.4593

In the given answer, there are 5 significant figures. Now we have to convert it into 3 significant figures.

According to the rules, round off the given measurement in three significant figures as 1.46

Therefore, the correct answer is 1.46