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1
a
C
Copper(II) nitrate decomposes on heating. The reaction is endothermic.
2Cu(NO),(s) → 2CuO(s) + 4NO2(g) + 0,(9)
Sketch a reaction pathway diagram for this reaction to include the
activation energy
[3]
b Draw an energy cycle to calculate the standard enthalpy change for
this reaction, using enthalpy changes of formation.
[3]
Calculate the enthalpy change for this reaction using the following
enthalpy changes of formation.
AH, [Cu(NO, ),(s)] = -302.9 kJ mol-'
AH, [CuO(s)] =-157.3 kJ mol-!
AH [NO,(g)] = +33.2 kJ mol-!
[3]
d Copper(II) sulfate is soluble in water. A student dissolved 25.0 g of
copper(II) sulfate in 100 cm of water in a polystyrene beaker stirring
all the time. The temperature of the water fell by 2.9 °C.
i Calculate the enthalpy change of solution of copper(II) sulfate.
(specific heat capacity of water = 4.18 Jg1 °C ; relative
molecular mass of copper(II) sulfate = 249.7 g mol-')
[3]
ii Suggest one source of error in this experiment and explain how
the error affects the results.
[2]
[Total: 14]

Answers

Answer 1

This problem provides information about the decomposition of copper(II) nitrate to copper(II) oxide and dinitrogen monoxide; for example, it is endothermic, the enthalpies of formation and the chemical reaction, as well as copper (II) sulfate which when dissolved in water, exhibits a temperature decrease:

[tex]2Cu(NO_3)_2(s) \rightarrow 2CuO(s) + 4NO_2(g) + O_2(g)[/tex]

First of all, we can draw the reaction pathway as shown on the attached figure, by taking into account the positive enthalpy change as it is endothermic, so that the products turn out with higher energy than the reactants, for it to be positive. In addition, keep in mind that top point is the activation energy the reaction needs to take place.

Next, we calculate the enthalpy change for this reaction by using the general formula which subtracts the enthalpy of formation of products and reactants with each species' correct stoichiometric coefficient:

[tex]\Delta H=2\Delta _fH_{CuO}+4\Delta _fH_{NO_2}+\Delta _fH_{O_2}-2\Delta _fH_{Cu(NO_3)_2}[/tex]

So we plug in the given enthalpies of formation:

[tex]\Delta H=2(-157.3)+4(33.2)+(0)-2(-302.9)=424.0 kJ/mol[/tex]

Finally, we go over the calorimetry experiment, whereby the total heat absorbed by the copper(II) sulfate is calculated via the general heat equation, which includes the heat loss from the solution of water and the salt:

[tex]Q_{rxn}=-mC_w\Delta T\\\\Q_{rxn}=-(100+25)g*4.18\frac{J}{g\°C}*-2.9\°C=1515.25J[/tex]

By dividing the previous answer by the moles of salt:

[tex]n=25.0g*\frac{1mol}{249.7g}=0.100mol[/tex]

We can obtain the enthalpy change of solution of the copper salt:

[tex]\Delta _{dissolution}H=\frac{1,515.25J}{0.100mol} \\\\\Delta _{dissolution}H=15,134J/mol=15.1kJ/mol[/tex]

To conclude, it is important to note that one possible source of error is we are assuming the solution has the same specific heat to that of water and that is not necessarily true. Also, we are neglecting any heat transfer to and from the surroundings despite the polystyrene beaker is considered a heat isolator, which means the results cannot necesarilly be accurate and the enthalpy change could have turned out higher or lower in a rigoruous experiment.

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1aCCopper(II) Nitrate Decomposes On Heating. The Reaction Is Endothermic.2Cu(NO),(s) 2CuO(s) + 4NO2(g)

Related Questions

If Temperature 25 C and volume is 117.5 cm³. Explain volume temperature relationship using Charles’s law.

(No links or else I'll report.
Don't answer if u dont know.)

Thank You.​

Answers

Explanation:

According to Charles law : V/T=k (constant).

the volume temperature relationship will be

V/T = 117.5/25 = 4.7

hope this helps you.

Why are you more likely to become dehydrated in hot weather?

Answers

Answer:

sweat

Explanation:

you get dehydrated in hot weather because your body will release sweat to try and keep you cool

Answer:

Well, the heat can sometimes be very subtle in how it affects the body. If you're out in the sun, it can take just 30 minutes or up to a few hours for the heat to cause dehydration, nausea or it could cause trouble concentrating. When it's hot and humid, your risk of dehydration and heat illness increases. That's because when the air is humid, sweat can't evaporate and cool you as quickly as it normally does, and this can lead to an increased body temperature and the need for more fluids.

I HOPE DAT THIS HELPS :)

Explanation:

Hg2(NO3)2 + Na2CO3 = NaNO3 + HgCO3 balance this

Answers

Answer:

Hg(NO3)2 + Na2CO3 --> 2NaNO3 + HgCO3

What is the amount, in mol, of 15g of carbonate ions, C03^2-​

Answers

24 electrons.............

A sample of gaseous arsine (AsH3) in a 460 mL flask at 332 Torr and 223 K, is heated to 437 K, at which temperature arsine decom- poses to solid arsenic and hydrogen gas. The flask is then cooled to 273 K, at which tem- perature the pressure in the flask is 488 Torr. What percentage of arsine molecules have de- composed?
Answer in units of %.

Answers

Answer:

28/95 = 29.,5 % of Arsine decomposed

Explanation:A sample of gaseous arsine (AsH3) in a 460 mL flask at 332 Torr and 223 K, is heated to 437 K, at which temperature arsine decom- poses to solid arsenic and hydrogen gas. The flask is then cooled to 273 K, at which tem- perature the pressure in the flask is 488 Torr. What percentage of arsine molecules have de- composed?

Answer in units of %.

initial pressure 332 Torr initial volume 0.46 L initial temperature 223K

final pressure 488 Torr final volume 0.46 L final 273 K

Torr is 1/760 atm 332 torr = 0.437 atm 488 Torr =0.642 atm

PV = nRT so n=RT/PV

INITIAL n= 0.082 X 223/(0.437)(0.46) = 91 moles

final n= 0.082 X 273 / (.437)(488) = 105 moles

2AsH3----------> 2As + 3H2

x moles of Arsine decomposed to make 1.5 moles of H2

the final number of moles was

(91 -X)+ 1.5 X = 105 moles

91 + 0.5 X = 105

0.5 X = 14

X =28

CHECK

if 28 moles of Arsine , then the container would have

91 --28 + 1.5(28) = 91 +14 =105 check

so 28/95 = 29.,5 % of Arsine decomposed

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Are all the wax rings melting at the same time?

Answers

Answer:yes

Explanation:

this is because the distance doesnt matter

Which would best describe the way an organism reacts to other organisms or to its
environment?
A. Instinct
B. Behavior
C. Conditioning
D. Imprinting

Answers

Answer:

Explanation:

Behavior

What is the chemical name of NaCl₂

Answers

Answer:

It’s sodium chloride

Explanation:

Hope that helps

It is Sodium chloride

Help will give brainlyness
Use your periodic table, notes on transition metals, and polyatomic ion table to correctly answer the following:
What is the ionic compound formed from calcium and sulfide ions?
Select one:
O a.
Cas
O b. Ca s
O c. CaSO4
O d. CazS2

Answers

Answer:

The high melting point is also consistent with its description as an ionic solid. In the crystal, each S2− ion is surrounded by an octahedron of six Ca2+ ions, and complementarity, each Ca2+ ion surrounded by six S2− ions.

Explanation:

You can use the periodic table to predict whether an atom will form an anion or a cation, and you can often predict the charge of the resulting ion. Atoms of many main-group metals lose enough electrons to leave them with the same number of electrons as an atom of the preceding noble gas. To illustrate, an atom of an alkali metal (group 1) loses one electron and forms a cation with a 1+ charge; an alkaline earth metal (group 2) loses two electrons and forms a cation with a 2+ charge, and so on. For example, a neutral calcium atom, with 20 protons and 20 electrons, readily loses two electrons. This results in a cation with 20 protons, 18 electrons, and a 2+ charge. It has the same number of electrons as atoms of the preceding noble gas, argon, and is symbolized Ca2+. The name of a metal ion is the same as the name of the metal atom from which it forms, so Ca2+ is called a calcium ion.

When atoms of nonmetal elements form ions, they generally gain enough electrons to give them the same number of electrons as an atom of the next noble gas in the periodic table. Atoms of group 17 gain one electron and form anions with a 1− charge; atoms of group 16 gain two electrons and form ions with a 2− charge, and so on. For example, the neutral bromine atom, with 35 protons and 35 electrons, can gain one electron to provide it with 36 electrons. This results in an anion with 35 protons, 36 electrons, and a 1− charge. It has the same number of electrons as atoms of the next noble gas, krypton, and is symbolized Br−. (A discussion of the theory supporting the favored status of noble gas electron numbers reflected in these predictive rules for ion formation is provided in a later chapter of this text.)

1.The table below lists some of the common ingredients in toothpaste.
What is the name of the ingredient responsible for preventing decay?

Sodium sulfate
Sodium fluoride
Sodium fluorine
Nitrogen fluoride

Answers

Fluoride, a naturally occurring mineral, helps prevent cavities and can even reverse the earliest stages of tooth damage. Because of its benefits for teeth, fluoride is added to many public water supplies. It's also a common ingredient in toothpaste and mouth rinses

Question 7 (1 point)
Which of the following organelles helps organisms maintain homeostasis by controlling what substances may enter or leave cells?

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Answer:

Cell membranes (plasma membranes) help organisms maintain homeostasis by controlling what substances may enter or leave cells.

Is the gin world scary? ​

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Answer:

Gin= Machine that picks cotton

Explanation:

This Machine was used in the early 1940s to help pick cotton to make things.

PLEASE HELP
What is the chemical equation for cellular respiration?
What role does photosynthesis play in our environment?

Answers

Answer:

Cellular Respiration:

C6H12O6 + 6O2 → 6CO2 + 6H20 + energy (Glucose + Oxygen yields Carbon Dioxide + Water + Energy) 

Photosynthesis is important to living organisms because it is the number one source of oxygen in the atmosphere. Without photosynthesis, the carbon cycle wouldn't occur/exist, oxygen-requiring life would not survive and plants would die. Without photosynthesis there would be little to no oxygen on the planet and Earth would be impossible to live on.

what wouldn't be a redox reaction?​

Answers

Answer:

Explanation:

Combination of oxidation and reduction reactions.

Where there is oxidation, there is reduction too.

When iodine is added to foods with no starches it turns

Answers

Answer:

Add Iodine-KI reagent to a solution or directly on a potato or other materials such as bread, crackers, or flour. A blue-black color results if starch is present. If starch amylose is not present, then the color will stay orange or yellow

What is the function of tendons?

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Answer:

A tendon is a fibrous connective tissue that attaches muscle to bone. Tendons may also attach muscles to structures such as the eyeball. A tendon serves to move the bone or structure.

Explanation:

How many grams of zinc chloride could be formed from the reaction of 3. 57g zinc with excess hcl?.

Answers

Zn+2HCl = ZnCl2 + H2
Zn= ZnCl2
65.38g Zn= 136.315 g ZnCl2
1g Zn = 136.315/65.38 g ZnCl2
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assume you are performing the calibration step of experiment 8 and you begin with 80 g of water at 20 oc and 80 g of water at 80 oc. after adding the two portions of water into your calorimeter setup and following the procedure outlined in the experiment, you determine the temperature of the mixed portions of water to be 45 oc. what is the heat capacity of the calorimeter?

Answers

The heat capacity of the calorimeter is 133.76 J°/C.

A calorimeter is an apparatus employed when estimating the amount of heat required in a chemical reaction.

For the given calorimetric function:

the heat lost by the hot water = to the heat gained by the cold water and the calorimeter.

These can be computed mathematically as:

[tex]\mathbf{m_wC_w\Delta \theta _w = m_cC_c\Delta \theta _c + C_{cal} \Delta_c}[/tex]

[tex]\mathbf{80 \ g\times 4.18 J/g^0 C \times (80-45)^0 \ C = 80 g \times 4.18\ J/g^0 \ \times (45- 20)^0 +C_{cal} \times (45- 20)^0 \ C}[/tex]

[tex]\mathbf{11704 \ J =8360 \ J+C_{cal} \times (25)^0 \ C}[/tex]

[tex]\mathbf{(11704 -8360) \ J= C_{cal} \times (25)^0 \ C}[/tex]

[tex]\mathbf{ C_{cal} = \dfrac{3344 \ J} { (25)^0 \ C}}[/tex]

[tex]\mathbf{ C_{cal} =133.76 \ J/^0 C}[/tex]

Therefore, the heat capacity of the calorimeter is 133.76 J°/C.

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A substance that can behave as either an acid or a base is: anthocyanin a neutral substance an indicator an amphiprotic substance

Answers

Answer:

These substances are called amphiprotic. Water, amino acids, hydrogen carbonate ions, and hydrogen sulfate ions are common examples.

Explanation:

A substance is amphoteric (from Greek amphoteros = "each of two") if it can act as an acid or a base.

For example, aluminum hydroxide is amphoteric because it can act as a base and neutralize strong acids.

Complete combustion of 6.4g of compound K produced 8.8 g of carbon dioxide and 7.2 g of water. Calculate the empirical formula of K. ​

Answers

Lh (x1)78.009+1= 0.0000567

Find the volume v of the solid obtained by rotating the region bounded by the given curves about the specified line. Y = 8x3, y = 0, x = 1; about x = 2.

Answers

The volume v of the solid obtained is 15.08

By using the cylindrical shell method to find the volume v of the solid which can be expressed by the formula;

V = 2πrh dr

Then, it is paramount to determine the radius and height of the shell.

From the given information;

The cylindrical shell formed by the rotation about the line x = 2Let consider the radius to be 2 - xThe circumference = 2π(2 - x)The height = 8x³

Then, the volume v of the solid can be estimated by using the cylindrical shell method as follows;

[tex]\mathbf{V = \int ^1_0 2 \pi (2-x) (8x^3) \ dx}[/tex]

Open brackets;

[tex]\mathbf{V = 2 \pi \int ^1_0 (16x^3 -8x^4) \ dx}[/tex]

Taking the integral form;

[tex]\mathbf{V = 2 \pi \Big [ \dfrac{16x^4}{4}-\dfrac{8x^5}{5} \Big]^1_0}[/tex]

Solving the terms in the bracket

[tex]\mathbf{V = 2 \pi \Big [ \dfrac{16(1)^4}{4}-\dfrac{8(1)^5}{5} -0\Big]}[/tex]

[tex]\mathbf{V = 2 \pi \Big [ 4-\dfrac{8}{5} \Big]}[/tex]

[tex]\mathbf{V = 2 \pi \Big [ \dfrac{20-8}{5} \Big]}[/tex]

[tex]\mathbf{V = 2 \pi \Big [ \dfrac{12}{5} \Big]}[/tex]

[tex]\mathbf{V = \dfrac{24\pi}{5}}[/tex]

[tex]\mathbf{V =15.08}[/tex]

Therefore, we can conclude that the volume v of the solid obtained is 15.08

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The volume of a gas must be measured at several points during an experiment. Which units should be used to describe the volume of the gas?

liters

centimeters

degrees Celsius

milligrams

Answers

the unit should be liters

Answer:liters

Explanation:

about how many bacteria colines will grow in a agar plate with a swab of ginger oil

Answers

about 6 to 9 colines

if its from mouth if thats the case

What is Most likely true about forensic scientist

Answers

Answer:

They collect all of the evidence for cases

Explanation:

What is carbon? What does it do?

Answers

Answer:

Carbon is in carbon dioxide, which is a greenhouse gas that works to trap heat close to Earth. Carbon is the chemical backbone of life on Earth. Carbon compounds regulate the Earth's temperature, make up the food that sustains us, and provide energy that fuels our global economy. Most of Earth's carbon is stored in rocks and sediments. The rest is located in the ocean, atmosphere, and in living organisms

Explanation:

Hope it helps. Can you give me BRAINLIEST ANSWER. Thank you

Describe how calcium and fluorine bond together to form calcium fluoride

Answers

Answer:   A transfer of electrons occurs when fluorine and calcium react to form an ionic compound. This is because calcium is in group two and so forms ions with a two positive charge. ... A pairs of shared electrons makes one covalent bond. The compound formed is known as a molecule***

A compound contains 36.48% Na, 25.41% S, and 38.11% O. Find it’s empirical formula

Answers

Answer:

we can use 100g of compounds as the basis.

Explanation:

How are polypeptides and proteins similar?
A. They are both made of amino acids.
B. They are both polysaccharides.
O C. They are both nucleic acids.
D. They are both made of carbohydrates.

Answer is A

Answers

Answer:

The answer is A.

Explanation:

They are both made of amino acids.

how well did the landmases fit together this time

Answers

Answer:

The theory of continental drift is most associated with the scientist Alfred Wegener. In the early 20th century, Wegener published a paper explaining his theory that the continental landmasses were “drifting” across the Earth, sometimes plowing through oceans and into each other. He called this movement continental drift.

Explanation:

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Which group of nonmetals will react with alkaline earth metals to form a compound in a one-to-one ratio?

Question 3 options:

Group 15


Group 16


Group 17


Group 18

Answers

Answer:

Group 17

Explanation:

Group 16 of nonmetals will react with alkaline earth metals to form a compound in a 1 : 1 ratio. Therefore, option (b) is correct.

What is the alkaline earth metals?

Alkaline earth metals or Group 2 includes six elements which are Beryllium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), and Radium (Ra).

This group contains smooth, silver metals with a less metallic character than group 1.  All alkaline earth metals have two valence electrons, giving a valency of 2. These metals easily lose electrons to form compounds via ionic bonds and become more stable.

The valency of calcium is 2 and the valency of the elements of group 16 is also 2. Therefore they can combine 1 : 1 ratio to form a neutral compound.

Ca²⁺    +   O²⁻   →  CaO

Therefore, the nonmetals of group 16 will react with alkaline earth metal.

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