Answer:
The name of the hotel can be the Red dust hotel. And the theme could red and rocky
Explanation:
Define Acid dissociation constant constant
Answer:
An acid dissociation constant, K a, (also known as acidity constant, or acid-ionization constant) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction ↽ − − ⇀ − + + known as dissociation in the context of acid–base reactions.
Explanation:
how can the hemlock woolly upset natural ecosystem?
Answer:
The HWA attacks eastern hemlock trees in forests and ornamental hemlock trees found in our residential landscaping. It feeds on the hemlock trees' young twigs by sucking the sap, causing their buds to die and needles to dry out and drop from the plant prematurely i think
hope i helped!!
What volume of hydrogen will be produced at STP by the reaction of 67.3 g of tin with excess water according to the following reaction?
Answer:
Sn + 2H2O ==> Sn(OH)2 + 2H2
67.3 g Sn x 1 mol/119 g x 2 mol H2/mol Sn x 22.4 L/mole = answer in liters
Explanation:
Sn + 2H2O ==> Sn(OH)2 + 2H2
67.3 g Sn x 1 mol/119 g x 2 mol H2/mol Sn x 22.4 L/mole = answer in liters
The volume of hydrogen that will be produced from the reaction of 67.3 g of tin with excess water is 12.68 L
How to determine the mole of tin Mass of Sn = 67.3 gMolar mass of Sn = 119 g/mol Mole of Sn =?Mole = mass / molar mass
Mole of Sn = 67.3 / 119
Mole of Sn = 0.566 mole
How to determine the volume of H₂ producedSn + 2H₂O —> Sn(OH)₂ + H₂
From the balanced equation above,
1 mole of Sn reacted to produce 1 mole of H₂.
Therefore,
0.566 mole of Sn will also react to produce 0.566 mole of H₂
Recall
1 mole of H₂ = 22.4 L at STP
Therefore,
0.566 mole of H₂ = 0.566 × 22.4
0.566 mole of H₂ = 12.68 L
Thus, 12.68 L of H₂ were obtained from the reaction.
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Classify the following as an element, compound, homogeneous mixture, or heterogeneous
Mixture :
Iron and rust
A. Element
B. Compound
C. Homogenous mixture
D. Heterogenous mixture
Answer:
It's an homogeneous Mixture
hehe
Why does common table salt (NaCl) have a high melting point?
A.
It forms an ionic bond with a crystal lattice structure.
B.
It forms a covalent bond with a Lewis dot structure.
C.
It forms a metallic bond with an electron sea model structure.
D.
It forms a covalent bond by sharing electrons.
E.
It forms a metallic bond with a Lewis dot structure.
Answer:C is not the answer. I just got it wrong in Edmentum
Explanation:
Please I need this answer quick I will give brainliest
A student decreases the temperature of a 417 cm³ balloon from 278 K to 231 K.
Assuming constant pressure, what should the new volume of the balloon be?
376 cm³
417 cm³
462 cm³
924 cm³
Answer:
The new volume of the balloon is [tex]346.5\ cm^3[/tex].
Explanation:
Initial volume of a balloon is 417 cm³
The temperature decreases from 278 K to 231 K.
It is required to find the new volume of the balloon if the pressure is constant pressure. At constant pressure, volume is directly proportional to the temperature. So,
[tex]V\propto T[/tex]
i.e.
[tex]\dfrac{V_1}{V_2}=\dfrac{T_1}{T_2}[/tex]
V₂ is final volume.
[tex]V_2=\dfrac{V_1T_2}{T_1}\\\\V_2=\dfrac{417\times 231}{278}\\\\V_2=346.5\ cm^3[/tex]
So, the new volume of the balloon is [tex]346.5\ cm^3[/tex].
What is the converse of the conditional statement?
Ifx is even, then x + 1 is odd.
If x is not even, then x + 1 is not odd.
Ifx + 1 is odd, then x is even.
Ifx + 1 is not odd, then x is not even
Ifx is even, then x + 1 is not odd.
Answer:
Conversing the conditional statement is nothing but switching the hypothesis and conclusion. Therefore, the converse of the given conditional statement will be “If x is odd, then x+1 is even.
Explanation:
The converse of the conditional statement is if x is odd, then x+1 is even.
What is conditional statement?A conditional statement is defined as a specific kind of compound sentence that meets the "if...then" requirement. If the hypothesis is correct but the conclusion is untrue, a conditional statement is false. Programming language elements called conditional statements, expressions, or simply conditionals instruct the computer to take specific actions.
Reversing the two statements that make up a categorical or implicational statement yields its opposite. Carry on a discussion is more properly referred to as "converse." Let's say there is a conditional statement of the form "If p then q." If q, then p is the converse. In a symbolic sense, q p is the opposite of p q. The reverse of a conditional assertion is not logically comparable.
Thus, the converse of the conditional statement is if x is odd, then x+1 is even.
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What is the potential energy of the bowling ball as it sits on top of a building?
Answer:
Potential energy is the amount of energy calculated from an object's height off the ground.
Explanation:
Potential energy = Mass x Height x Gravity
hii:) how to do (c)?
Answer:
C
Explanation:
C shows a mixture of CO2 and H2O, 2 compounds
Answer:
C
Explanation:
C shows a mixture of CO2 and H2O, 2 compounds
Atoms with a high electronegativity, like oxygen have a strong attractive force
for electrons because
A. they have only a few valence electrons and need a total of eight to
fulfill the octet rule
O B. they're trying to share electrons with other elements of high
electronegativity
O C. opposites attract
O D. they re close to filling their outer shell, fuffilling the octet rule
Answer:
D. they're close to filling their outer shell, fulfilling the octet rule
Explanation:
:)
What’s the answer to this?
Answer : The balanced chemical reaction will be:
[tex]3Ca(s)+2Al(NO_2)_3(aq)\rightarrow 2Al(s)+3Ca(NO_2)_2(aq)[/tex]
Explanation :
Balanced chemical reaction : It is defined as the reaction in which the number of atoms of individual elements present on reactant side must be equal to the product side.
When solid calcium metal reacts with aqueous aluminum nitrate then it gives aqueous calcium nitrate and solid aluminium.
The balanced chemical reaction will be:
[tex]3Ca(s)+2Al(NO_2)_3(aq)\rightarrow 2Al(s)+3Ca(NO_2)_2(aq)[/tex]
4. What is the name of A13+?
A)Aluminum ion
B)Aluminum
C)Aluminous ion
D)Aluminide ion
Answer:
Aluminum ion
Explanation:
I used Google tbh but it has a higher charge then a regular Aluminum atom
Neutralization Reactions
PREDICT THE PRODUCTS OF THE FOLLOWING REACTIONS
+
HNO3+ Ba(OH)2
+
H3PO4 + Ca(OH)2
→
Answer:
2HNO3+ Ba(OH)2 = Ba(NO3)2 + 2H2O
H3PO4 + Ca(OH)2 = Ca3(PO4)2 + 6H2O
Explanation:
2HNO3+ Ba(OH)2 = Ba(NO3)2 + 2H2O
H3PO4 + Ca(OH)2 = Ca3(PO4)2 + 6H2O
H+
O2-
OH-
Ba2+
Ca2+
NO3-
P 5+, 3+, 3-
H2O
What happens to the motion of the atoms in a spoon after is placed in hot soup?
Answer:
they move faster
Explanation:
Answer:
They move faster.
PLZ HELP QUICKLY!!!!!!!!
Portfolio: Reflection
Review everything from your portfolio thoughtfully. Answer the following questions carefully and specifically. Use your answers as a guide to prepare for your presentation. Your presentation will focus on your goals and your development and improvements this semester. As you answer these questions, evaluate your strengths as a student. Consider how your growth this semester has prepared you for advancement. Use complete sentences or a paragraph to respond to each item.
WHAT DOES THIS QUESTION MEAN: When you look through your portfolio, what improvements do you notice in your work?
What do they mean by WORK?
Answer:
they meen like what youve learned or like what youve been tonight....all that is work stuff you did for example school work.
Arrange the following rock particles which occur in soil in the decreasing order of their sizes:
Sand, Clay, Gravel, Silt.Immersive Reader
(1 Point)
Clay>Silt>Sand>Gravel
Silt>Clay>Sand>Gravel
Gravel >Sand>Silt>Clay
Answer:
Gravel >Sand>Silt>Clay
Explanation:
Sand, Clay, Gravel and Silt
Clay: all particles smaller than 0.002 mm
Silt: all particles within the size range of 0.002-0.05 mm;
Sand: all particles within the size range of (2.0 mm - 0.05 mm)
Gravel particles are larger than sand, ranging in size from 4.75 mm to 75 mm
Going through the options, the correct option is;
Gravel >Sand>Silt>Clay
could some please help me with this? thank you
Answer:
C
Explanation:
Oxidation occurs at the anode. That means the element's oxidation number should increase. Mg has an oxidation number of 0, but Mg2+ has an oxidation number of 2, showing it was oxidized.
Molybdenum metal requires a photon with a minimum frequency of 1.09x1015s-1before it can emit an electron via the photoelectric effect.
a) What is the minimum energy needed to eject an electron?
b)What wavelength of radiation (in nm) will provide a photon of this energy?
c)How many electrons can be freed by a burst of radiation whose total energy is 1.00 μJ, assuming one photon causes one electron to be freed? (μ= micro = 10-6)
d) If molybdenum is irradiated with light of 122nm, what is the maximum kinetic energy of the emitted electrons?
Answer:
a) 7.22 × 10⁻¹⁹ J; b) 275 nm; c) 1.38× 10¹² electrons; d) 9.1 × 10⁻¹⁹ J
Explanation:
a) Minimum energy to eject photon
E = hf = 6.626× 10⁻³⁴ J·s × 1.09 × 10¹⁵ s⁻¹ = 7.22 × 10⁻¹⁹ J
b) Wavelength required
fλ = c
[tex]\lambda = \dfrac{c}{f } = \dfrac{2.998 \times 10^{8}\text{ m/s}}{1.09 \times 10^{15}\text{/s}} = 2.75 \times 10^{-7} \text{ m} = \textbf{275 nm}[/tex]
c) Electrons required
[tex]\text{No. of electrons} = 1.00 \times 10^{-6}\text{ J} \times \dfrac{\text{1 electron}}{7.22 \times 10^{-19}\text{ J}} = 1.38 \times 10^{12}\text{ electrons}[/tex]
d) Kinetic energy of electrons
a) Energy of photon
[tex]E = hf = \dfrac{\text{hc}}{\lambda} = \dfrac{6.626 \times 10^{-34} \text{ J$\cdot$ s}\times 2.998 \times 10^{8} \text{ m/s}}{122 \times 10^{-9}\text{ m}}= 1.63 \times 10^{-18} \text{ J}[/tex]
b) Maximum kinetic energy
The equation for the photoelectric effect is
hf = φ + KE, where
φ = the work function of the metal — the minimum energy needed to eject an electron
KE = hf - φ = 1.63× 10⁻¹⁸ J - 7.22× 10⁻¹⁹ J = 9.1 × 10⁻¹⁹ J
a. The energy of molybdenum to eject electron has been [tex]\rm \bold{7.22\;\times\;10^{-19}}\;J[/tex].
b. The wavelength of the radiation has been 275 nm.
c. The number of electrons present in [tex]\rm 1\;\mu J[/tex] energy has been [tex]\rm \bold{1.38\;\times\;10^1^2}[/tex].
d. The kinetic energy of the emitted electrons as been [tex]\rm \bold{9.1\;\times\;10^-^1^9\;J}[/tex].
The metal emits the energy when it returns from the excited state to ground state.
a. The energy (E) to eject electron has been given by:
[tex]E=h\nu[/tex]
Where, the value of constant, [tex]h=6.626\;\times\;10^{-34}\;\rm J.s[/tex]
The value of frequency has been given, [tex]\nu=\rm 1.09\;\times\;10^{15}\;s^{-1}[/tex]
Substituting the values for energy:
[tex]E=6.626\;\times\;10^{-34}\;\times\;1.09\;\times\;10^{15} \rm J\\\textit E=7.22\;\times\;10^{-19}\;J[/tex]
The energy of molybdenum to eject electron has been [tex]\rm \bold{7.22\;\times\;10^{-19}}\;J[/tex].
b. The wavelength ([tex]\lambda[/tex]) of the radiation has been given by:
[tex]\lambda=\dfrac{c}{\nu}[/tex]
Where, the speed of light, [tex]c=3\;\times\;\rm m/s[/tex]
The frequency has been given as, [tex]\nu=1.09\;\times\;10^{15}\;\rm s^-^1[/tex].
Substituting the values for wavelength:
[tex]\lambda=\dfrac{3\;\times\;10^8}{1.09\;\times\;10^{15}}\;\rm m\\ \lambda=2.75\;\times\;10^-^7\;m\\\lambda=275\;nm[/tex]
The wavelength of the radiation has been 275 nm.
c. The electrons ([tex]e^-[/tex]) burst out can be given as:
[tex]e^-=\dfrac{E}{E'}[/tex]
Where, the energy of radiations, [tex]E=1\;\times\;10^{-6}\;\rm J[/tex]
The energy of each electron has been calculated as, [tex]E'=7.22\;\times\;10^{-19}\;\rm J[/tex]
Substituting the values for number of electrons:
[tex]e^-=\dfrac{1\;\times\;10^-^6}{7.22\;\times\;10^-^1^9} \\e^-=1.38\;\times\;10^1^2[/tex]
The number of electrons present in [tex]\rm 1\;\mu J[/tex] energy has been [tex]\rm \bold{1.38\;\times\;10^1^2}[/tex].
d. The maximum kinetic energy (K.E.) of the radiation has been given as:
[tex]K.E.=\dfrac{hc}{\lambda} -E^'[/tex]
Where, the value of constant, [tex]h=6.626\;\times\;10^{-34}\;\rm J.s[/tex]
The speed of light, [tex]c=3\;\times\;\rm m/s[/tex]
The wavelength of the radiation, [tex]\lambda=122\;\times\;10^-^9\;\rm m[/tex]
Energy of each electron, [tex]E'=7.22\;\times\;10^{-19}\;\rm J[/tex]
Substituting the values, for kinetic energy:
[tex]K.E.=\dfrac{6.626\;\times\;10^{-34}\;\times\;3.0\;\times\;10^8}{122\;\times\;10^-^9}\;-\;7.22\;\times\;10^-^1^9\;\rm J \\\textit {K.E.}=9.1\;\times\;10^{-19}\;J[/tex]
The kinetic energy of the emitted electrons as been [tex]\rm \bold{9.1\;\times\;10^-^1^9\;J}[/tex].
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Is the answer B? Help
Answer:
A
Explanation:
Hmm, so we have the following in the diagram
Pt(s)
Cl2(g)
Ag(s)
NaCl(aq)
AgNO3(aq)
Pt 2+, 4+, 6+ Though it states Pt is inert
Cl 2-
Ag 1+
Na 1+
NO3-
Anode definition: the positively charged electrode by which the electrons leave an electrical device.
Electrode definition: a conductor through which electricity enters or leaves an object, substance, or region.
Cations attracted to cathode pick up electrons
Anions attracted to anode release electrodes+
Reduction at Cathode (red cat gain of e)
Oxidation at Anode (ox anode loss of e)
So from the diagram we can see that the charge is being generated through the 2 metal plates.
So the answer is A, the anode material is Pt and the half reaction is 2Cl- = Cl2 + 2e-
Compounds formed from only non-metals consist of particles called
Answer:
Compounds formed from non-metals consist of molecules.
Explanation:
The atoms in a molecule are joined together by covalent bonds. These bonds form when atoms share pairs of electrons.
I hope I helped, please correct me if I'm wrong!
Considering the definition of covalent bond and molecules, compounds formed from only non-metals consist of particles called molecules.
But you have to know that the covalent bond is the chemical bond between atoms where electrons are shared, forming a molecule.
Covalent bonds are established between non-metallic elements, such as hydrogen H, oxygen O and chlorine Cl. These elements have many electrons in their outermost level (valence electrons) and have a tendency to gain electrons to acquire the stability of the electronic structure of noble gas.
The shared electron pair is common to the two atoms and holds them together.
In other words, a covalent bond is a type of chemical bond where two atoms of non-metallic elements join to form a molecule, where the atoms share pairs of electrons from their most superficial layer or valence layer to achieve stability in the molecule and thus complying with the octet rule.
In summary, compounds formed from only non-metals consist of particles called molecules.
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https://brainly.com/question/12661797?referrer=searchResultshttps://brainly.com/question/4461443?referrer=searchResultshttps://brainly.com/question/11693996?referrer=searchResultsNeed help please: How many mL of 0.150 Molarity CaBr2 solution must be used to react with 50 mL of 0.115 Molarity AgNO3?
CaBr2 + 2AgNO3 --> Ca(No3)2 + 2AgBr
Answer:
0.019 L or 19.1 mL
Explanation:
Given the equation of the reaction; we have:
CaBr2 + 2AgNO3 --> Ca(No3)2 + 2AgBr
We must first obtain the number of moles of AgNO3 reacted. This can be obtained from;
Concentration of AgNO3 reacted= 0.115 M
Volume of AgNO3 reacted= 50 ml
Since
Number of moles of AgNO3= concentration of AgNO3 × volume of AgNO3
Number of moles = 0.115 M × 50/1000 = 5.75 ×10^-3 moles
From the reaction equation;
2 moles of AgNO3 reacts with 1 mole of CaBr2
5.75 ×10^-3 moles of AgNO3 reacts with 5.75 ×10^-3 moles × 1 /2 = 2.875×10^-3 moles of CaBr2
Now;
Number of moles of CaBr2= concentration of CaBr2 × volume of CaBr2
Number of moles of CaBr2= 2.875×10^-3 moles
Volume of CaBr2= ????
Concentration of CaBr2= 0.150 M
Hence;
Volume of CaBr2= number of moles of CaBr2/ concentration of CaBr2
Volume of CaBr2= 2.875×10^-3 moles / 0.150
Volume of CaBr2= 0.019 L or 19.1 mL
Answer:
19 mL of CaBr₂ solution should be used to react with AgNO₃
Explanation:
By stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction) react:
AgNO₃: 2 molesCaBr₂: 1 mole50 ml of 0.115 M AgNO₃ react. Since molarity is the number of moles of solute per liter of solution, then you can do the following rule of three: if there are 0.115 moles of AgNO₃ in 1 L, in 0.05 L (being 1 L = 1000 mL, then 50 mL = 0.05 L How many moles are there?
[tex]moles of AgNO_{3}=\frac{0.05L*0.115 moles}{1 L}[/tex]
moles of AgNO₃=5.75*10⁻³
Now we can make a new rule of three to calculate the amount of moles necessary for CaBr₂ to react with moles of AgNO₂: if stoichiometry 2 moles of AgNO₃ react with 1 mole of CaBr₂, 5.75*10⁻³ moles of AgNO₃ with how many moles of CaBr₂ react ?
[tex]moles of CaBr_{2} =\frac{5.75*10^{-3}moles of AgNO_{3}*1 mole of CaBr_{2} }{2moles of AgNO_{3}}[/tex]
moles of CaBr₂=2.875*10⁻³ moles
Being 0.150 the molarity of the CaBr₂ compound, you can apply the following rule of three: if by definition of molarity 0.150 moles are in 1 L, 2.875 * 10⁻³ moles in how much volume is it present?
[tex]volume=\frac{2.875*10^{-3} moles*1L}{0.150 moles}[/tex]
volume=0.019 L
Being 1 L = 1000 mL, then 0.019 L = 19 mL
19 mL of CaBr₂ solution should be used to react with AgNO₃
Is Raisin Bran cereal with milk homogeneous
Answer:
no
Explanation:
Homogeneous means that the substance looks uniform throughout. This means that all of it looks the same (ex. juice or water). Because you can see the different parts of raisin bran cereal with milk it is not homogeneous, it is heterogeneous.
Will Mark Brainly thing please help
Balance this equation. If a coefficient of "1" is required, choose "blank" for that box.
CO + O ₂ → CO ₂
Answer:
2CO + O ₂ → 2CO ₂
Explanation:
CO + O ₂ → CO ₂
Left Side
C = 1
O = 3
Right Side
C = 1
O = 2
So we'll balance the oxygen first
2CO + O ₂ → 2CO ₂
Left Side
C = 2
O = 4
Right Side
C = 2
O = 4
Ok so balancing the O has also balanced the C
Which of the following atoms has the largest atomic radius? Provide an explanation
a Hydrogen
b. Sodium
C Lithium
d Rubidium
Answer:
d Rubidium
Explanation:
The atomic radius of an atom is the distance from the center of the nucleus to its outermost electron.
The atomic radius of elements varies in the periodic table, it increases as you go down in a group and decreases along the period from left to right.
All the elements listed: Hydrogen, Sodium, Lithium and Rubidium belong to the same group in the periodic table (group 1), Since atomic radius increases from top to bottom in a group, Rubidium has the largest atomic radius.
l Active transport
IL Simple diffusion
lll Facilitated diffusion
IV. Osmosis
Which of the above type of transport moves molecules against a concentration gradient?
Your answer:
ll and lV only
l only
ll only
Answer:
l only
Explanation:
The movement of substances in living cells can either require energy (active) or not (passive) depending on the direction of movement across concentration gradient. Naturally, substances tend to move down a concentration gradient i.e. difference in concentration, which is from a region of high concentration of water to a region of low concentration. This is the passive type of transport, which does not require energy input. Examples are osmosis, simple diffusion and facilitated diffusion.
However, another type of transport exists in which substances move against the concentration gradient i.e. from a less concentrated region to a more concentrated region. In this case, energy input in form of ATP is required for this kind of transport to occur. This transport is referred to as ACTIVE TRANSPORT. Hence, the answer is I only.
Name three group l bases and three group ll bases
Answer:
Group 1: LiOH, NaOH, KOH
Group 2: Ca(OH)2, Sr(OH)2, Ba(OH)2
Explanation:
2 The precipitate formed when sodium hydroxide reacts with solutions
containing metal ions is the corresponding METAL HYDROXIDE.
a Write word equations and symbol equations including state symbols)
to show how the following solutions react with sodium hydroxide:
magnesium sulfate, MgSO4
ii iron(II) sulfate, FeSO4
ili iron(III) chloride, FeCl3
iv copper(ll) chloride, CuCl2
Answer:
Explanation:
MgSO4 + 2NaOH -------> Mg(OH)2 + 2NaSO4
CuCl2 +2NaOH -------> Cu (OH)2 + 2Nacl
FeCl3 + 3NaOH ----> Fe(OH)3 + 3NaCl
based on this can you try for the FeSO4. similar to first reaction showed above
For the reaction NH4Cl (s)→NH3 (g) + HCl (g) at 25°C, ΔH = 176 kJ/moland ΔS = 0.285 kJ/(mol - K).
What is the ΔG, and will this reaction be spontaneous in the forward direction?
169 kJ/mol; no
-91 kJ/mol; yes
91 kJ/mol; no
91 kJ/mol; yes
please answer quick
Answer:
91kj/mol;no
Explanation:
Took this before I gotchu.
What is the ΔG, and will this reaction be spontaneous in the forward direction? 91 kJ/mol; no
What does ΔG mean in chemistry?
Gibbs is a free number of power converters
In the active and frequent use of the Gibbs free energy change equation, ΔG is calculated from the fixed values that scientists can measure: the enthalpy and entropy changes of the reaction, and the temperature at which the reaction occurs.
What is Delta G measured in?
joules
measured in joules in SI) is the maximum amount of non-expansion work that can be extracted from a closed system (one that can exchange heat and work with its surroundings, but no matter) at fixed temperature and pressure. This maximum can be attained only in a completely reversible process.
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Why do you subtract the mass of the solute from the total mass desired when making mass percent calculations?
We can represent the concentration of a material even when we don't know its molecular mass, since mass percentage and parts per million or a billion are just alternative ways of expressing the ratio of the mass of a solute to the mass of the solution.
What is molecular mass ?The mass of a certain molecule is its molecular mass, which is expressed in daltons. Because they contain various isotopes of an element, multiple molecules of the same substance can have distinct molecular weights.
More solute can be dissolved in a given volume of solution to increase concentration, since doing so increases the mass of the solute. By allowing some of the solvent to evaporate, which reduces the volume of the solution, concentration can be increased.
The amount of a solute that is present in a specific amount of solvent or solution is known as the concentration of a solution. Controlling the stoichiometry of reactants for solution reactions requires knowledge of the solute concentration.
Thus, We can represent the concentration of a material even when we don't know its molecular mass.
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Neutrons are in the nucleus of the atom. A neutron has
a) A positive charge
b) No charge
c) A negative charge
d) Twice as much positive charge as a proton
Answer: B. (No charge)
Explanation:
Protons have a positive charge, electrons have a negative charge.
Neutrons are neutral and therefore have no change.