Answer:
(A). C6H5Br + Mg(in ether) -----------> C6H5MgBr.
(B). C6H5MgBr + O = C = O -----------> C6H5-COO^- Mg^+ Br.
(C). C6H5-COO^- Mg^+ Br + HCl --------> C6H5-COOH + Mg^+Br(OH).
PRODUCTS=> C6H5-COOH and Mg^+Br(OH).
Explanation:
A Grignard reagent is a reagent that/which is an organometallic compound that is R -Mg- X. The R = alkyl, vinyl or allyl and the X = halogens.
It must be noted that an important reaction of Grignard reagent is its reaction with compounds containing the Carbonyl that is -CO functional group and this kind of Reaction is known as a Grignard Reaction.
So, in this question we are told that;
=> "1-bromo-benzene andits subsequent reaction with solid carbon dioxide (CO2) followed by acidic workup (using HCl asthe acid). "
Thus;
(A). C6H5Br + Mg(in ether) -----------> C6H5MgBr.
(B). C6H5MgBr + O = C = O -----------> C6H5-COO^- Mg^+ Br.
(C). C6H5-COO^- Mg^+ Br + HCl --------> C6H5-COOH + Mg^+Br(OH).
WILL GIVE BRAINLIEST!!!!! will give brainliest!!!! ******According to the reaction in question I above, how many grams of solid copper will theoretically be
produced when 14.4 g of aluminum are reacted with 14.4 g of copper (II) sulfate? Which reactant is the
limiting reactant? Show your work. Be sure to include units!
Answer:
5.73 g Cu
Explanation:
M(CuSO4) = 159.6 g/mol
M(Al) = 27.0 g/mol
M(Cu) = 63.5 g/mol
14.4 g Al * 1 mol/27.0 g = 0.5333 mol Al
14.4 g CuSO4 * 1 mol/159.6 g = 0.0902 mol CuSO4
2 Al + 3CuSO4 -------> 3Cu + Al2(SO4)3
from reaction 2 mol 3 mol
given (0.5333 mol )x 0.0902 mol
needed 0.0601 mol
x= 2*0.0902/3 = 0.0601 mol Al
Al is excess, CuSO4 is a limiting reactant.
2 Al + 3CuSO4 -------> 3Cu + Al2(SO4)3
from reaction 3 mol 3 mol
given 0.0902 mol x mol
x = 0.0902 mol Cu
0.0902 mol Cu * 1 mol/63.5 g Cu = 5.73 g Cu
Suppose that a wave has a period of 0.03 seconds what is its frequency be sure to show the steps for your work
Answer:
f = 33.34 Hz
Explanation:
A wave has a period of 0.03 seconds. It is required to find the frequency of a wave. The relation between time period and frequency is inverse. The time period of a wave is given by :
T = 1/f, f = frequency of wave
[tex]f=\dfrac{1}{T}\\\\f=\dfrac{1}{0.03}\\\\f=33.34\ Hz[/tex]
So, the frequency of the wave is 33.34 Hz.
Compare the conjugate bases of these three acids. Acid 1: hypochlorous acid , HClO Acid 2: phosphoric acid , H3PO4 Acid 3: hydrogen sulfide , HS- What is the formula for the weakest conjugate base ?
Answer:
The weakest conjugate is HClO-.
Explanation:
As a general rule, the stronger the Bronsted-Lowry acid, the weaker its conjugate base, and vice versa.
Acid 1: HClO is a strong acid, hence its conjugate base would be weak
Acid 2: H3PO4 is a weak acid, hence its conjugate base would be strong
Acid 3: hydrogen sulphide is also a moderately weak acid with a moderately strong conjugate base.
In order of increasing strengths:
HClO < H2S < H3PO4
The chemical equation and thermodynamic data for the melting of tungsten are given above. Based on this information, which of the following provides the best predictions correc whether a sample of pure tungsten will melt at 3723 K?
A. The sample will not melt because T > H/s
B. The sample will not melt because T< H/s
C. The sample will mel because T>
D. The sample will mel because T
Based on the information above provided, the best predictions correct whether a sample of pure tungsten will melt at 3723 K is The sample will mel because T>
TungstenTungsten is a very hard and brittle material. It properties include a very high melting point, a low vapor pressure and the highest hardness and strength of all metals. Tungsten has good corrosion resistance against most acids and alkalis.
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A compound has an empirical formula of CHN. What is the molecular formula, if it’s molar mass is 135.13 g/mol? (C=12.01 amu, H=1.008 amu, N= 14.01)
Answer:
well the MF is 224.78 g/mol
Explanation:
just times them all by the molor mass and divide it by 3
what happens when you combine Mg2 and NO3
Answer: they blow up
Explanation: add them together and they will blow up
Answer:
Magnesium nitrate Reactions
Magnesium nitrate has a high affinity towards water. Therefore, heating it results to decompose into magnesium oxide, nitrogen oxides, and oxygen. 2 Mg(NO3)2 → 2 MgO + 4 NO2 + O2.
what type of bonds do compounds formed from non metal consist of?
Compounds formed from non-metals consist of molecules. The atoms in a molecule are joined together by covalent bonds. These bonds form when atoms share pairs of electrons.
How many grams of the salt CaF2 (g) are formed when 15.7 mL of 0.612 M KF reacts with an excess of aqueous calcium bicarbonate (Ca(HCO3)2) via a metathesis reaction?
Answer:
[tex]m_{CaF_2}0.375gCaF_2[/tex]
Explanation:
Hello,
In this case, for the studied reaction:
[tex]2KF+Ca(HCO_3)_2\rightarrow CaF_2+2KHCO_3[/tex]
Thus, the first step is to compute the reacting moles of potassium fluoride by using its volume and molarity:
[tex]n_{KF}=0.0157L*0.612\frac{mol}{L} =9.61x10^{-3}molKF[/tex]
Then, we apply the 2:1 molar ratio between potassium fluoride and calcium fluoride to compute the produced moles of calcium fluoride:
[tex]n_{CaF_2}=9.61x10^{-3}molKF*\frac{1molCaF_2}{2molKF} =4.80x10^{-3}molCaF_2[/tex]
Finally, by using the molar mass of calcium fluoride (78.07 g/mol) we can compute its produced grams:
[tex]m_{CaF_2}=4.80x10^{-3}molCaF_2*\frac{78.07gCaF_2}{1molCaF_2} \\\\m_{CaF_2}0.375gCaF_2[/tex]
Best regards.
The solubility of N2 in water at a particular temperature and at a N2 pressure of 1 atm is 6.8 × 10–4 mol L–1. Calculate the concentration of dissolved N2 in water under normal atmospheric conditions where the partial pressure of N2 is 0.78 atm.
Answer:
The correct answer is 5.30 * 10^-4 mol per L.
Explanation:
Based on Henry's law, in a solution solubility of the gas is directly proportional to the pressure, that is, C is directly proportional to P. Here P is the pressure and C is the concentration of the dissolved gases.
Therefore, it can be written as,
C2/C1 = P2/P1
Here, C1 is 6.8 * 10^-4 mol/L, P1 is 1 atm and P2 is 0.78 atm, then the value of C2 obtained by putting the values in the equation,
C2/(6.8*10^-4) = 0.78/1
C2 = 0.78 * 6.8*10^-4
C2 = 5.30 * 10^-4 mol per L.
Hence, the concentration of dissolved nitrogen at 0.78 atm is 5.30*10^-4 mol/L.
The boiling point of ethanol is 78.40°C. A student conducts an
experiment and finds a boiling point of 75.70°C. How far off
from the accepted value was the student's result?
Error = °C
Answer:
2.7 °C
Explanation:
78.4-75.7=2.7
The student's result is 2.7° C less than the expected result.
We have a student conducting an experiment to find the boiling point of ethanol.
We have to determine how far off from the accepted value is the student's result.
What is Measurement error ?Measurement Error (also called Observational Error) is the difference between a measured quantity and its true value.
According to the question, we have -
True value of the boiling point of ethanol [T] = 78.40°C.
Measured value of the boiling point of ethanol [M] = 75.70°C.
The Error (E) in the measurement will be -
E = T - M
E = 78.40° - 75.70° = 2.7° C
Hence, the student's result is 2.7° C less than the expected result.
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Dry chemical hand warmers utilize the oxidation of iron to form iron oxide according to the following reaction: 4Fe(s)+3O2(g)→2Fe2O3(s) Standard thermodynamic quantities for selected substances at 25 ∘C Reactant or product ΔH∘f(kJ/mol) Fe(s) 0.0 O2(g) 0.0 Fe2O3(s) −824.2 Calculate ΔH∘rxn for this reaction.
Answer:
-1648.4 kJ/mol
Explanation:
Based on Hess's law:
ΔHr = ∑n×ΔH°f(products) - ∑n×ΔH°f(reactants)
In the reaction:
4Fe(s) + 3O₂(g) → 2Fe₂O₃(s)
ΔHr = 2 ΔH°f {Fe₂O₃} - (4ΔH°f {Fe(s)} + 3ΔH°f{O₂(g)}
As:
ΔH°f {Fe₂O₃} = -824.2kJ/mol
ΔH°f {Fe(s)} = 0.0kJ/mol
ΔH°f{O₂(g)} = 0.0kJ/mol.
Thus,
ΔHr = 2 ₓ -824.2kJ/mol =
-1648.4 kJ/molAnswer:
-1648.4 kJ
Explanation:
The product has the only nonzero heat of formation, so it is the only value needed to calculate the enthalpy of this reaction. Normally, you would want to express the enthalpy of a reaction with respect to one mole of a chemical species, whether it is a reactant or product. However, since the balanced chemical equation contains only coefficients greater than 1, you should consider how the enthalpy relates to one mole of each substance according to the coefficients. In other words, − 1648.4 kJ of heat is released when 4 mol of Fe reacts with 3 mol of O2 to produce 2 mol of Fe2O3 .
Which best explains how heat plays a role in the movement of materials within Earth's interior?
Answer:
Hot material near the core is less dense and rises, when it cools, it becomes more dense and sinks.
Explanation:
This best explains how heat plays a role in the movement of materials within Earth's interior because it's how convection works. Convection is the circular motion that happens when warmer air or liquid which has faster moving molecules, making it less dense rises, while the cooler air or liquid drops down. Convection currents within the earth move layers of magma, and convection in the ocean creates currents.
Earth’s interior is like a closed chamber, hot material near Earth's surface is more denser and sinks, and when it cools, it becomes less dense and Rises.
What is Convection?Convection is the process of heat transfer by the bulk movement of molecules within fluids such as gases and liquids. The heat transfer take place from solid to no solid material. like air and water.
As we take example of home. In home heat take nearer the roof and cold air will be nearer to the flour. It is because of hot is less denser then the cold air. Hot air will become less denser and move towords upside. Cold air become denser move towards down.
Similarly, on earth. Nearer to earth hot materials are more dense and sinks. When it cools, it become less dense and rises.
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2 FONS
How does the electric force between two charged particles change if the
distance between them is increased by a factor of 22
A. It increases by a factor of 4.
B. It increases by a factor of 2.
C. It decreases by a factor of 4
O
D. It decreases by a factor of 2.
SUB
Answer:
C. It decreases by a factor of 4
Explanation:
F1 = kq1*q2/r²
F2 = kq1*q2/(2r)² = kq1*q2/(4r²) = kq1*q2/(r²*4) = F1/4
Two samples of the same rainwater are tested using two indicators at an environrnental lab. The first indicator, Methyl Orange, reveals a distinct yellow color when added to the sample. The second indicator, Litmus, turns red when placed in contact with the water sample.
Required:
a. Identify a possible pH value for the rainwater.
b. Explain, in terms of hydronium ions and hydroxide ion concentrations, the pH value of the rainwater.
Answer:
A. The pH value of rainwater is acidic about 4.4
B. The molar concentrations of the Hydronium ions are more than that of the hydroxide ions. That is why the rainwater is acidic with a pH of less than 7
Explanation:
A. Methyl orange is an acid indicator that is used to detect acidic solutions which have pH values that fall within the range of about 4.4 to 7. The distinct yellow colour change that was shown by the methyl orange as it was added to the water shows that the pH value is acidic, with a value above 4.4. (it has to be like this before methyl orange changes to yellow colour)
B. The Hydronium ( H30+) ion concentrations and the hydroxide (OH-) ion concentrations are used to measure the pH values of substances.
We can tell that the Hydronium ( H30+) ion concentrations are more than the hydroxide (OH-) ion concentrations in the sample of rainwater tested. This can be detected from the colour change that both the methyl orange and the litmus paper gave. The indicators showed that the rainwater solution was indeed acidic. Hence, the pH value will be less than 7, but greater than 4.4.
If the Moon rises at 7 P.M. on a particular day, then approximately what time will it rise six days later?
Answer:
below
Explanation:
28th 10;24 am
If the Moon rises at 7 P.M. on a particular day, then approximately what time will it rise six days later at 12A.M.
How much time changes between Moon rises from one day to the next?This movement is from the Moon's orbit, which takes 27 days, 7 hours and 43 minutes to go full circle. It causes the Moon to move 12–13 degrees east every day. This shift means Earth has to rotate a little longer to bring the Moon into view, which is why moonrise is about 50 minutes later each day.
So knowing that moonrise is about 50 minutes later each day, we have:
[tex]7+50 minutes = 7:50\\8:40\\9:30\\10:20\\11:10\\12:00 A.M[/tex]
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How is the mass of the atom calculated?
by adding the number of protons and electrons
by adding the number of protons and neutrons
by subtracting the number of electrons from the number of protons
by adding the number of neutrons and electrons
The mass of the atom is calculated by adding the number of protons and neutrons .
What do you mean by atomic mass of an element ?The total mass of one atom of an element is defined as its atomic mass. The atomic mass is taken as the mass of protons and neutrons in an atom.
1 a m u = 1.66 ×10⁻²⁴g
To calculate the atomic mass of an element -:
The atomic mass of the single atom can be calculated by adding the total number of protons and the total number of neutrons of that particular atom.
Atomic mass Number = Number of protons + number of neutrons
Hence ,in this way the atomic mass is calculated of an atom .
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What is in period 6 group 8
Answer:
Osmium
Explanation:
If you take a look at the attached image of a periodic table below, you will see that the element in the 6th period and 8th group is Osmium. Hope this helps!
A sample of 6.022 x 1023 particles of gas has a volume of 22.4 L at 0°C and a pressure of 1.000 atm. Although it may seem silly to contemplate, what volume would 1 particle of gas occupy?
pv=nRT
Answer:
1 particle of the gas would occupy a volume of 3.718*10⁻²³L
Explanation:
Hello,
1. The sample has a particle of 6.022×10²²particles
2. Volume of the sample = 22.4L
3. Temperature of the sample = 0°C = (0 +273.15)K = 273.15K
4. Pressure of the sample = 1.0atm
What volume would 1 particle of the gas occupy?
But we remember that 1 mole of any substance = 6.022×10²² molecules or particles or atoms
What would be the number of moles for 1 particule?
1 mole = 6.022×10²² particles
X moles = 1 particle
X = (1 × 1) / 6.022×10²² particles
X = 1.66×10⁻²⁴ moles
Therefore, 1 particle contains 1.66×10⁻²⁴ moles
Since we know our number of moles, we can proceed to use ideal gas equation,
Ideal gas equation holds for all ideal gas and is defined as
PV = nRT
P = pressure of the ideal gas
V = volume the gas occupies
n = number of moles of the gas
R = ideal gas constant = 0.082 L.atm / mol.K
T = temperature of the gas
PV = nRT
Solving for V,
V = nRT/ P
We can now plug in our values into the above
equation.
V = (1.66*10⁻²⁴ × 0.082 × 273.15) / 1
V = 3.718*10⁻²³L
Therefore, 1 particule of the gas would occupy a volume of 3.718*10⁻²³L.
Glycine, C2H5O2N, is important for biological energy. The combustion reaction of glycine is given by the equation 4C2H5O2N(s) + 9O2(g) → 8CO2(g) + 10H2O(l) + 2N2(g) ΔH°rxn = –3857 kJ/mol Given that ΔH°f[CO2(g)] = –393.5 kJ/mol and ΔH°f[H2O(l)] = –285.8 kJ/mol, calculate the enthalpy of formation of glycine.
Answer:
ΔH°f C₂H₅O₂N(s) = -537.2kJ
Explanation:
Based on the reaction:
4 C₂H₅O₂N(s) + 9O₂(g) → 8CO₂(g) + 10H₂O(l) + 2N₂(g)
ΔHrxn = ΔH°f products - ΔH°f reactants.
As:
ΔH°fO₂(g) = 0
ΔH°fCO₂(g) = -393.5kJ/mol
ΔH°fH₂O(l) = -285.8kJ/mol
ΔH°fN₂(g) = 0
The ΔHrxn is:
ΔHrxn = (8×-393.5kJ/mol + 10×-285.8kJ/mol) - (4×ΔH°fC₂H₅O₂N(s)) = -3857kJ/mol
-6006kJ/mol - (4×ΔH°fC₂H₅O₂N(s)) = -3857kJ/mol
-4×ΔH°fC₂H₅O₂N(s) = 2149kJ/mol
ΔH°fC₂H₅O₂N(s) = 2149kJ/mol / -4
ΔH°f C₂H₅O₂N(s) = -537.2kJPropane (C3H8) is widely used in liquid form as a fuel for barbecue grills and camp stoves. For 67.7 g of propane, determine the following.(a) Calculate the moles of compound.mol(b) Calculate the grams of carbon.g
Answer:
A. 1.54 mole.
B. 55.39g of carbon
Explanation:
A. Determination of the number of mole in 67.7g of C3H8.
Mass of C3H8 = 67.7g
Molar mass of C3H8 = (3x12) + (8x1) = 44g/mol
Number of mole of C3H8 =..?
Number of mole = Mass/Molar Mass
Number of mole of C3H8 = 67.7/44
Number of mole of C3H8 = 1.54 mole
B. Determination of the mass of carbon in the compound.
This is illustrated below:
The mass of C in compound can be obtained as follow:
=> 3C/C3H8 x 67. 7
=> 3x12 / 44 x 67.7
=> 36/44 x 67.7
=> 55.39g
Therefore, 55.39g of carbon is present in the compound.
If a solution containing 23.81 g of lead(II) acetate is allowed to react completely with a solution containing 7.410 g of sodium sulfate, how many grams of solid precipitate will be formed g
Answer:
The correct answer is 15.80 grams.
Explanation:
The reaction taking place in the given question,
Pb(CH₃COO)₂ + Na₂SO₄ ⇒ PbSO₄ + 2NaCH₃COO
The number of moles can be calculated by using the formula,
n = weight / molecular mass
Based on the given question, the weight of lead (II) acetate is 23.81 grams and the weight of sodium sulfate is 7.410 grams.
The number of moles of Pb(CH₃COO)₂ is,
n = 23.81 g / 325.29 g/mol = 0.0732 moles
The number of moles of Na₂SO₄ is,
n = 7.410 g / 142.04 g/mol = 0.0521 moles
As one mole of lead (II) acetate needs one mole of sodium sulfate. Therefore, 0.0732 moles of lead (II) acetate needs 0.0732 moles of sodium sulfate.
However, as sodium sulfate is less, that is, 0.0521, therefore, Na₂SO₄ is a limiting reactant.
One mole of sodium sulfate produces one mole of PbSO₄. So, 0.0521 moles of Na₂SO₄ produces 0.0521 moles of PbSO₄.
Now the mass of PbSO₄ is,
mass = moles × molecular mass
mass = 0.0521 × 303.26 g/mol
mass = 15.80 grams.
One of the radioactive isotopes used in chemical and medical research is sulfur-35, which has a half-life of 87 days. How long would it take for 0.25 g to remain of a 1.00 g sample of sulfur-35
Answer:
Time taken = 174 days
Explanation:
Half life is the time take for a subsrtance taken to decay to half of it's origial or initial concentration.
In this probel, the haf life is 87 days, this means that after evry 87 days, the concentration or mass of sulfur-35 decreases by half.
If the starting mass is 1.00g, then we have;
1.00g --> 0.5g (First Half life)
0.5g --> 0.25g (Second half life)
This means that sulphur-335 would undergo two half lives for 0.25g to remain.
Total time taken = Number of half lives * Half life
Time taken = 2 * 87
Time taken = 174 days
What mass of carbon dioxide is produced from the complete combustion of 7.30×10−3 g of methane?
Choose the slope and Y intercept that correspond with the graph
y=3x + 4
Explanation:
Where 3 is the slope and 4 is the y-intercept
RUIGA GIRLS
CHEMISTRY FORM 3. 23/06/2020
MR. GICHURU
IZ
1
Narne the elements present in
Common salt
(2 miks)
Hydrated copper (11) Sulphate.
(2 ks)
Sulphuric (VI) acid,
2 Why is a reaction between zinc metal and Nitric acid not suitable for preparing
hydrogen gae in the laboratory
(2 mi)
(1 m)
3.
What is relative atomic mass?
b)
Define 'isotopes
c)Determine the relative atomic mass of element K whose isotople misure occur in
the proportione:
(2 marks)
Hot coffee in a mug cools over time and the mug warms up. Which describes the energy in this system? The average kinetic energy of the particles in the mug decreases. The average kinetic energy of the particles in the coffee increases. Thermal energy from the mug is transferred to the coffee. Thermal energy from the coffee is transferred to the mug.
Answer:
d
Explanation:
Answer:
D
Explanation:
Edge 2021
1. Which statement describes the particles of an ideal gas, based on the
kinetic molecular theory?*
O There are attractive forces between the particles.
O The particles move in circular paths.
O The collisions between the particles reduce the total energy of the gas.
О
The volume of the gas particles is negligible compared with the total volume of the
gas.
Answer:the volume of the gas particles is negligible compared with the total volume of the gas.--D
Explanation:
According to the Kinetic Molecular Theory for ideal gases, it states that
--Gases are composed of larges molecules which are in constant random motion in a straight line
--The volume of the gas particles is negligible compared to the total volume in which the gas is contained.
-----The Attractive and repulsive forces between gas molecules is insignificant ie There are no interactive forces.
----The collisions of the particles are perfectly elastic and energyis being transferred between the particles but the total energy remaining constant
From the statements of the kinetic Molecular theory of ideal gases, it can be seen that the statement which describes the particles of an ideal gas is option D which is The volume of the gas particles is negligible compared with the total volume of the gas--- ---This gives the reason why gases can be compressed. Since there are no inter molecular forces between them. The particles of an ideal gas will move at the same random motion resulting to high pressures, compressing the gas and making the volume negligible or insignificant.
Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, write only NR. LiNO₃
Answer:
It is neutral (NR)
Explanation:
Salts are formed when the ionizable hydrogens in an acid is replaced by metallic or ammonium ions from bases. The reaction is known as a neutralization reaction.
The nature of a salt formed from this reaction depends on the nature of the reacting acid and base.
If the reaction is between a strong acid and strong base, the salt produced is a neutral salt.
If the reaction occurs between a strong acid and a weak base, the salt produced is acidic.
If the reaction occurs between a strong base and a weak acid, the salt produced is a basic salt.
Considering the salt above, LiNO3.
On hydrolysis, addition of water, the following products are obtained:
LiNO3 + H2O ----> LiOH + HNO3
The products obtained, LiOH and HNO3 are a strong base and a strong acid respectively. Therefore, the salt, LiNO3, is a neutral salt.
The salt, LiNO₃ is a neutral, NR salt as it's a salt formed from the reaction of a strong acid and a strong base.
In neutralisation reactions, acids and bases react to form salt and water.
However, the salt formed may be acidic, basic or neutral. This is dependent on the type of acid and base which form the salt.
A strong acid and a strong base react to yield a neutral salt like, LiNO₃.
The equilibrium equation when LiNO₃ is dissolved in aqeous solution is;
LiNO₃ + H2O ==>. LiOH + HNO₃Evidently, LiOH and HNO₃ are an example strong base and acid respectively.
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Round off the following measurement to three significant digits: 29.950g
Answer:
30.0 g.
Explanation:
Hello,
In this case, for us to round the given number off to three significant figures, we firstly realize it has initially five significant figures. Thus, cutting at the third digit, which is the second nine, we will have 29.9 g, nonetheless, as a five is after such nine, we should round the nine to ten, so the result is 30.0 g.
Best regards.
A 25.0 mL solution of quinine was titrated with 1.00 M hydrochloric acid, HCl. It was found that the solution contained 0.125 moles of quinine. What was the pH of the solution after 50.00 mL of the HCl solution were added
Answer:
pH = 9.08
Explanation:
Quinine, C₂₀H₂₄O₂N₂, Q, is a weak base that, in water, has as equilibrium:
Q + H₂O ⇄ QH⁺ + OH⁻
Where pKb is 5.10
Using H-H equation for weak bases:
pOH = pKb + log₁₀ [QH⁺] / [Q]
The reaction of quinine with HCl is:
Q + HCl → QH⁺ + Cl⁻
Initial moles of quinine are 0.125 moles and moles added of HCl are:
0.05000L × (1.00mol / L) = 0.05000moles.
That means after the addition of 50.00mL of the HCl solution, moles of Q and QH⁺ are:
Q = 0.125mol - 0.050mol = 0.075 moles
QH⁺ = 0.050 moles
Replacing in H-H equation:
pOH = 5.10 + log₁₀ [0.050] / [0.075]
pOH = 4.92
As pH = 14 - pOJ
pH = 9.08