Answer:
a. 181.5 kcal
Explanation:
Step 1: Calculate the enthalpy of the process (ΔH°).
Let's consider the following process.
CO₂(s) → CO₂(g)
We can calculate the enthalpy of the process using the following expression.
ΔH° = ∑ np × ΔH°f(p) - ∑ nr × ΔH°f(r)
ΔH° = 1 mol × ΔH°f(CO₂(g)) - 1 mol × ΔH°f(CO₂(s))
ΔH° = 1 mol × (-393.5 kJ/mol) - 1 mol × (-427.4 kJ/mol) = 33.9 kJ
According to the balanced equation, 33.9 kJ are required to sublime 1 mole of CO₂.
Step 2: Convert 986 g of CO₂ to moles
The molar mass of CO₂ is 44.01 g/mol.
986 g × 1 mol/44.01 g = 22.4 mol
Step 3: Calculate the enthalpy needed to sublime 22.4 moles of CO₂
22.4 mol × 33.9 kJ/1 mol = 759 kJ
We can convert it to Kcal using the conversion factor 1 kcal = 4.184 kJ.
759 kJ × 1 kcal/4.184 kJ = 181.5 kcal
calculate the pH of 0.01moldm-3 of trioxonitrate (v) acid
Answer:
pH = 2
Explanation:
Trioxonitrate (v) acid is also known as nitric acid (HNO₃) and is one of the strong acid set which when dissolved in water, ionizes 100%. That is,
0.01M HNO₃ => 0.01M H⁺ + 0.01M NO₃⁻ => pH = -log[H⁺] = -log(0.01) = -(-2) = 2
consider the following thermochemical reaction for kerosene
2C12H26+37O2=24CO2+15026kj.
a. when 21.3g of CO2 are made, how much heat is released?
b. if 500.00kj of heat are released by thye reaction, how many grams of C12H26 have been consumed.?
c. if this reactionwere being used to generate heat, how many grams of C12H26 would have to be reacted to generate enough heat to raise the temperature of 750g of liquid water from 10 degrees celcius to 90 degrees celcius
Thermochemistry has to do with heat evolved or absorbed in a chemical reactions. Thermochemical equations are equations in which the heat of reaction is included in the reaction equation. The reaction of moles and heat of reaction is important here.
This question has to do with thermochemistry and thermochemical equations.
The answers to each of the questions are shown below;
a) 300.52 KJ
b) 11.39 g
c) 5.78 g
The equation of the thermochemical reaction is;
2C12H26 + 37O2-------> 24CO2 + 15026KJ
Number of moles of CO2 released = 21.3g/44g/mol = 0.48 moles
From the reaction equation;
15026KJ is released when 24 moles of CO2 is released
x KJ is released when 0.48 moles of CO2 is released
x = 15026KJ * 0.48 moles/24 moles
x = 300.52 KJ
b) If 2 moles of C12H26 released 15026KJ of heat
x moles of C12H26 released 500.00KJ
x = 2 * 500.00KJ/15026KJ
x = 0.067 moles
Mass of C12H26 consumed = 0.067 moles * 170 g/mol = 11.39 g
c) Heat gained by water = heat released by combustion of kerosene
Heat gained by water = 0.75 Kg * 4200 * (90 -10)
Heat gained by water = 252 KJ
If 2 moles of C12H26 produced 15026KJ
x moles of C12H26 produces 252 KJ
x = 2 * 252/15026
x = 0.034 moles
Mass of C12H26 = 0.034 moles * 170 g/mol = 5.78 g
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Calculate the percent error in the atomic weight if the mass of a Cu electrode increased by 0.4391 g and 6.238x10-3 moles of Cu was produced. Select the response with the correct Significant figures. You may assume the molar mass of elemental copper is 63.546 g/mol. Refer to Appendix D as a guide for this calculation.
Answer:
10.77%
Explanation:
Molar mass of Cu = mass deposited/number of moles of Cu
Molar mass of Cu = 0.4391 g/6.238x10^-3 moles
Molar mass of Cu = 70.391 g/mol
%error = 70.391 g/mol - 63.546 g/mol/63.546 g/mol × 100
%error = 10.77%
Consider the preparation of methyl benzoate by reacting benzoic acid with methanol using sulfuric acid as a catalyst. Reaction scheme of benzoic acid with methanol, conc. sulfuric acid, and heat over the arrow, and methyl benzoate and water as products. Calculate the molar masses of the reactant and product. Report molar masses to 1 decimal place. Molar mass of benzoic acid g/mol Molar mass of methyl benzoate
Answer:
See explanation
Explanation:
The molecular mass is the sum of the relative atomic masses of all the atoms in the molecule.
The relative atomic mass of reactants and products are calculated as follows;
Benzoic acid is C7H6O2 hence the molar mass of benzoic acid is ;
7(12) + 6(1) + 2(16) = 84 + 6 + 32 = 122.0 g/mol
Methyl benzoate is C8H8O2
8(12) + 8(1) + 2(16) = 96 + 8 + 32 = 136.0 g/mol
Carbon disulfide is formed by the reaction of coke (carbon) with sulfur dioxide. How many moles of CS2 will be generated if 8.0 moles of coke react with a surplus of sulfur dioxide? 5C +2502 - CS2 + 4CO A. 0.8 moles B. 1.6 moles C. 3.2 moles OD. 6.4 moles
Determine the total pressure of a mixture that contains 5.25 g of He and 3.25 g of N2 in a 7.75-L flask at a temperature of 27ºC.
Answer:
4.54 atm
Explanation:
Step 1: Calculate the total number of gaseous moles
We will calculate the moles of each gas using its molar mass.
He: 5.25 g × 1 mol/4.00 g = 1.31 mol
N₂: 3.25 g × 1 mol/28.01 g = 0.116 mol
The total number of moles is:
n = 1.31 mol + 0.116 mol = 1.43 mol
Step 2: Convert 27 °C to Kelvin
We will use the following expression.
K = °C + 273.15 = 27 + 273.15 = 300 K
Step 3: Calculate the total pressure of the mixture
We will use the ideal gas equation.
P × V = n × R × T
P = n × R × T / V
P = 1.43 mol × (0.0821 atm.L/mol.K) × 300 K / 7.75 L = 4.54 atm
Draw the structure of the organic product(s) of the Grignard reaction between methyl benzoate and excess phenylmagnesium bromide, followed by aqueous workup. You do not have to consider stereochemistry. If a compound is formed more than once, add another sketcher and draw it again. Alternatively, you may use the square brackets tool to add stoichiometries greater than one. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the sign from the drop-down menu.
Answer:
See explanation and image attached
Explanation:
The product of the Grignard reaction between methyl benzoate and excess phenylmagnesium bromide is triphenyl methanol.
The reaction proceeds by nucleophillic reaction as the carbonyl moiety is attacked. A tetrahedral intermediate is formed. Loss of the -OMe group is accompanied by the attack of the first molecule of PhMgBr.
Attack by a second PhMgBr molecule yields trimethyl phenoxide. Protonation of this specie yields the final product which is obtained by aqueous workup.
10. At 573K, NO2(g) decomposes forming NO and O2. The decomposition reaction is second order in NO2 with a rate constant of 1.1 M-1s-1. If the initial concentration of NO2 is 0.056 M, how long will it take for 75% of the NO2 to decompose
Answer:
48.67 seconds
Explanation:
From;
1/[A] = kt + 1/[A]o
[A] = concentration at time t
t= time taken
k= rate constant
[A]o = initial concentration
Since [A] =[A]o - 0.75[A]o
[A] = 0.056 M - 0.042 M
[A] = 0.014 M
1/0.014 = (1.1t) + 1/0.056
71.4 - 17.86 = 1.1t
53.54 = 1.1t
t= 53.54/1.1
t= 48.67 seconds
Hence,it takes 48.67 seconds to decompose.
Ggggggggggggggggg666666666666666
Suppose you are studying the Ksp of CaCl2, which has a molar mass of 110.98 g/mol, at multiple temperatures. You dissolve 4.99 g of CaCl2 in 10.0 mL of water at 100 oC and cool the solution. At 90 oC, a solid begins to appear. What is the Ksp of CaCl2 at 90 oC
Answer:
Hence the Solubility product,
Ksp = [Ca2+] [Cl-]2
or, Ksp = (4.5) (9)2
or, Ksp = 364.5
Explanation:
Mass of CaCl2 = 4.99 g
Molar mass of CaCl2 = 110.98 g/mol
Moles of CaCl2
= given mass/ molar mass
= 4.99/ 110.98
= 0.045
Volume = 10.0 mL = 0.01 L
CaCl2 dissociates into its ion as:
CaCl2 (s) \rightleftharpoons Ca2+ (aq) + 2 Cl- (aq)
At 90°C, the solution is saturated with Ca2+ and Cl- ions.
Moles of Ca2+ = Moles of CaCl2 dissolved = 0.045
Moles of Cl- = 2 x ( Moles of CaCl2 dissolved) = 2 x 0.045 = 0.09
[Ca2+] = Moles/ Volume = 0.045/ 0.01 = 4.5 M
[Cl-] = 0.09/ 0.01 = 9 M
Solubility product,
Ksp = [Ca2+] [Cl-]2
or, Ksp = (4.5) (9)2
or, Ksp = 364.5
How many Noble gases we have in Periodic Table???
Answer:
Six
Explanation:
A reaction rate increases by a factor of 500. in the presence of a catalyst at 37oC. The activation energy of the original pathway is 106 kJ/mol. What is the activation energy of the new pathway, all other factor being equal
Answer:
[tex]E_2=999984KJ/mole[/tex]
Explanation:
From the question we are told that:
Factor [tex]dK=500[/tex]
Temperature [tex]T=37 C=310k[/tex]
Activation energy [tex]E=10^6kJ/mol[/tex]
Generally the Arhenius equation is mathematically given by
[tex]ln \frac{K_2}{K_1}=\frac{ E_1-E_2}{RT}[/tex]
Where
[tex]\frac{K_2}{K_1}=500[/tex]
[tex]ln 500=\frac{ 10^6-10^3-E_2}{8.314*310}[/tex]
[tex]E_2=999984KJ/mole[/tex]
The activation energy of the new reaction is 105.99 kJ/mol.
Using the Arrhenius equation;
ln(k2/k1) = -Ea2/RT2 + Ea1/RT1
Now, from the information in the question;
k2/k1 = 500
Ea = ?
R = 8.314 JKmol-1
T2 = 37oC + 273 = 310 K
T1 = 37oC + 273 = 310 K
Substituting values;
ln (500) =- Ea2 + Ea1
6.2 = -Ea2 + 106 × 10^3 J
Ea = 106 × 10^3 J - 6.2
Ea = 105.99 × 10^3 J or 105.99 kJ/mol
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Hypercalcemia sign and symptoms severe symptoms
Answer:
Hypercalcemia can cause stomach upset, nausea, vomiting and constipation. Bones and muscles. In most cases, the excess calcium in your blood was leached from your bones, which weakens them. This can cause bone pain and muscle weakness.
Some symptoms are:
Fatigue, bone pain, headaches.
Nausea, vomiting, constipation, decrease in appetite.
Forgetfulness.
Lethargy, depression, memory loss or irritability.
Muscle aches, weakness, cramping and/or twitches.
g An aqueous solution of nitric acid is standardized by titration with a 0.137 M solution of calcium hydroxide. If 19.0 mL of base are required to neutralize 21.8 mL of the acid, what is the molarity of the nitric acid solution
Answer:
M of HNO₃ is 0.119M
Explanation:
A basic concept of titration is that in equivalence point:
mmoles of acid = mmoles of base
We have data from base and we only have data from volume of acid.
In a case our titration is a strong acid against a strong base.
We apply formula:
M of acid . Vol of acid = M of base . Vol of base
M of acid . 21.8 mL = 0.137M . 19 mL
M of acid = (0.137M . 19 mL) / 21.8 mL
M of acid = 0.119 M
When we neutralize all the titrant we reach the equivalence point.
At this point, pH = 7
2HNO₃ + Ca(OH)₂ → Ca(NO₃)₂ + 2H₂O
A solution is made by dissolving 5.84 grams of NaCl in enough distilled water to give a final volume of 1.00 L. What is the molarity of the solution
Group of answer choices
0.0250 M
0.400 M
0.100 M
1.00 M
Answer:
Explanation:
1. A solution is made by dissolving 5.84g of NaCl is enough distilled water to a give a final volume of 1.00L. What is the molarity of the solution? a. 0.100 M b. 1.00 M c. 0.0250 M d. 0.400 M 2. A 0.9% NaCl (w/w) solution in water is a. is made by mixing 0.9 moles of NaCl in a 100 moles of water b. made and has the same final volume as 0.9% solution in ethyl alcohol c. a solution that boils at or above 100°C d. All the above (don't choose this one) 3. In an exergonic process, the system a. gains energy b. loses energy c. either gains or loses energy d. no energy change at all
Answer:
[tex]\boxed {\boxed {\sf 0.100 \ M }}[/tex]
Explanation:
Molarity is a measure of concentration in moles per liter.
[tex]molarity = \frac{moles \ of \ solute}{liters \ of \ solution}}[/tex]
The solution has 5.84 grams of sodium chloride or NaCl and a volume of 1.00 liters.
1. Moles of SoluteWe are given the mass of solute in grams, so we must convert to moles. This requires the molar mass, or the mass of 1 mole of a substance. These values are found on the Periodic Table as the atomic masses, but the units are grams per mole, not atomic mass units.
We have the compound sodium chloride, so look up the molar masses of the individual elements: sodium and chlorine.
Na: 22.9897693 g/mol Cl: 35.45 g/molThe chemical formula (NaCl) contains no subscripts, so there is 1 mole of each element in 1 mole of the compound. Add the 2 molar masses to find the compound's molar mass.
NaCl: 22.9897693 + 35.45 = 58.4397693 g/molThere are 58.4397693 grams of sodium chloride in 1 mole. We will use dimensional analysis and create a ratio using this information.
[tex]\frac {58.4397693 \ g\ \ NaCl} {1 \ mol \ NaCl}[/tex]
We are converting 5.84 grams to moles, so we multiply by that value.
[tex]5.84 \ g \ NaCl *\frac {58.4397693 \ g\ NaCl} {1 \ mol \ NaCl}[/tex]
Flip the ratio. It remains equivalent and the units of grams of sodium chloride cancel.
[tex]5.84 \ g \ NaCl *\frac {1 \ mol \ NaCl}{58.4397693 \ g\ NaCl}[/tex]
[tex]5.84 *\frac {1 \ mol \ NaCl}{58.4397693 }[/tex]
[tex]0.09993194823 \ mol \ NaCl[/tex]
2. MolarityWe can use the number of moles we just calculated to find the molarity. Remember there is 1 liter of solution.
[tex]molarity= \frac{moles \ of \ solute}{liters \ of \ solution}[/tex]
[tex]molarity= \frac{ 0.09993194823 \ mol \ NaCl}{1 \ L}[/tex]
[tex]molarity= 0.09993194823 \ mol \ NaCl/L[/tex]
3. Units and Significant FiguresThe original measurements of mass and volume have 3 significant figures, so our answer must have the same. For the number we calculated, that is the thousandths place. The 9 in the ten-thousandths place tells us to round the 9 to a 0, but then we must also the next 9 to a 0, and the 0 to a 1.
[tex]molarity \approx 0.100 \ mol \ NaCl/L[/tex]
1 mole per liter is 1 molar or M. We can convert the units.
[tex]molarity \approx 0.100 \ M \ NaCl[/tex]
The molarity of the solution is 0.100 M.
What effect does the anion of an ionic compound have on the appearance of the solution?
A. The anion affects the intensity of the color more than the color of the solution.
B. The anion affects the color of the solution more than the intensity of the color
C. The anion does not affect the color or color intensity of the solution
D. The anion only affects the intensity of the color in a solution.
Answer: B. The anion affects the color of the solution more than the intensity of the color.
Explanation:
An ionic bond is gotten when an electron is transferred from a metal atom to a non-metal one. It should be noted that the ionic bonds simply has an anion and a cation.
An anion is formed when a valence election is gained by a non metal while a cation is formed when the metal ion misplaces a valence electron.
The effect of the anion of an ionic compound on the appearance of the solution is that the anion affects the color of the solution more than the intensity of the color.
The anions affect the color of the solution more than the intensity of the color.
How do anions affect the color of the solution?Anions are the molecules or atoms that have one or more extra electrons in the valence cell.
When the number of electrons is increased or decreased in the solute molecule it completely change the color of the solution.
For example - Yellow chromate and orange dichromate
Therefore, the anions affect the color of the solution more than the intensity of the color.
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What is the concentration of HI in the final solution when 65 mL of a 3.0 M HI solution is diluted with pure water to a total volume of 0.15 L g?
Answer:
The concentration of HI in the final solution is 1.3 M.
Explanation:
Dilution is the reduction in concentration of a chemical in a solution. It is achieved by adding more solvent to the same amount of solute.
In other words, in a dilution, the amount of solute does not change, but the volume of the solvent does: as more solvent is added, the concentration of the solute decreases, since the volume (and weight) of the solution increases.
When dealing with dilution you will use the following equation:
C1*V1= C2*V2
C1 = initial concentration V1 = initial volume C2 = final concentration V2 = final volumeIn this case:
C1 = 3 M V1 = 65 mL= 0.065 L (being 1000 mL= 1 L) C2 = ? V2 = 0.15 LReplacing:
3 M* 0.065 L= C2*0.15 L
Solving:
[tex]C2=\frac{3 M*0.065 L}{0.15 L}[/tex]
C2= 1.3 M
The concentration of HI in the final solution is 1.3 M.
At what velocity (m/s) must a 20.0g object be moving in order to possess a kinetic energy of 1.00J
Answer:
10 ms-1
Explanation:
Kinetic energy = 1/2 × m × v^2
1 = 1/2× 20 ×10^ -3 × v^2
v ^ 2 = 100
v = 10 ms-1
note : convert grams in to kg before substitution as above
Given:
Kinetic energy,
K.E = 1.00 JMass,
m = 20.0 gWe know the formula,
→ [tex]K.E = \frac{1}{2} mv^2[/tex]
By putting the values, we get
[tex]1 = \frac{1}{2}\times 20\times 10^{-3}\times (v)^2[/tex]
[tex]v^2 = 100[/tex]
[tex]v = \sqrt{100}[/tex]
[tex]v = 10 \ m/s[/tex]
Thus the above response is correct.
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HELP ASAP PLS
Reactions, products and leftovers
Answer:
See the answer below
Explanation:
From the original equation in the image, the mole ratio of C:CO2:CO is 1:1:2. This means that for every 1 mole of C and CO2, 2 moles of CO would be produced.
Now, looking at the simulation below the equation of the reaction, 3 moles of C and 8 moles of CO2 were supplied as input. Applying this to the original equation of reaction, C seems to be a limiting reagent for the reaction because the ratio of C to CO2 should 1:1.
Hence, taking all the 3 moles of C available means that only 3 moles out of the available 8 for CO2 would be needed. 3 moles c and 3 moles CO2 means that 6 moles CO would be produced (remember that the ratio remains 1:1:3 for C, CO2, and CO). This means that 5 moles CO2 would be leftover.
In other words, all the 3 moles C would be consumed, 3 out of 8 moles CO2 would be consumed, and 6 moles CO would be produced while 5 moles CO2 would be leftover.
A solution is made by dissolving 0.565 g of potassium nitrate in enough water to make up 250. mL of solution. What is the molarity of this solution?
Please explain and show work.
[tex]\\ \large\sf\longmapsto KNO_3[/tex]
[tex]\\ \large\sf\longmapsto 39u+14u+3(16u)[/tex]
[tex]\\ \large\sf\longmapsto 53u+48u[/tex]
[tex]\\ \large\sf\longmapsto 101u[/tex]
[tex]\\ \large\sf\longmapsto 101g/mol[/tex]
Now
[tex]\boxed{\sf No\:of\:moles=\dfrac{Given\:mass}{Molar\:mass}}[/tex]
[tex]\\ \large\sf\longmapsto No\:of\:moles=\dfrac{0.565}{101}[/tex]
[tex]\\ \large\sf\longmapsto No\:of\:moles=0.005mol[/tex]
We know
[tex]\boxed{\sf Molarity=\dfrac{Moles\:of\:solute}{Vol\:of\:Solution\:in\:L}}[/tex]
[tex]\\ \large\sf\longmapsto Molarity=\dfrac{0.005}{\dfrac{250}{1000}L}[/tex]
[tex]\\ \large\sf\longmapsto Molarity=\dfrac{0.005}{0.250}[/tex]
[tex]\\ \large\sf\longmapsto Molarity=0.02M[/tex]
[tex] \: \: \: \: \: \: \: \: \: [/tex]
Copper wire has a high electrical conductivity.
True
False
Answer:
True
Explanation:
Copper has the highest electrical conductivity rating of all non-precious metals: the electrical resistivity of copper = 16.78 nΩ•m at 20 °C. Specially-pure Oxygen-Free Electronic (OFE) copper is about 1% more conductive (i.e., achieves a minimum of 101% IACS).
True is the correct answer.
A chlorine (CI) atom has 7 valence electrons. Which of the following would be the most likely way for a chlorine atom to become stable?
A. Lose 5 electrons
B. Gain 2 electrons
C. Gain 1 electron
D. Lose 7 electrons
Answer:
Option C. Gain 1 electron
Explanation:
Valence electron(s) are the electron(s) located on the outermost shell of an atom. Valency is simply defined as the combining power of an atom.
Chlorine (Cl) atom has 7 valence electron. This implies that Cl needs just one electron to complete it's octet configuration. It will be difficult for Cl to lose any of it's valence electron(s). Cl can either gain or share 1 electron to become stable.
Thus, considering the options given in the question above, option C gives the correct answer to the question.
Describe a NAMED example of a non-equilibrium system with respect to it’s energetic nature and equilibrium status.
Answer:
Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of variables (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium.
Explanation:
Which is the electronic configuration for oxygen?
What is the molecule shown below?
A. Pentane
B. Trimethylethane
C. 2,2-dimethylpropane
D. 3-dipropane
Q2
Answer:
C
Explanation:
if we were to followw the IUPAC
When a solute is dissolved in water, it forms……
Answer:
an aqueous species is the answer
Write a balanced chemical equation for the reaction that occurs
when:
(a) titanium metal reacts with O21g2;
(b) silver(I) oxide decomposes into silver metal and oxygen gas when heated;
(c) propanol, C3H7OH1l2 burns in air;
(d) methyl tert-butyl ether, C5H12O1l2, burns in air.
Answer:
Explanation:
A balanced chemical equation refers to the reaction taking place whereby the number of atoms associated in the reactants side is equivalent to the number of atoms on the products side.
From the given information, the balanced equations are as follows:
[tex]\mathbf{(a) \ \ \ Ti(s) + O_{2(g)} \to TiO_{2(s)}}[/tex]
[tex]\mathbf{(b) \ \ \ 2Ag_{2}O \to 4Ag_{(s)} + O_{2(g)}}[/tex]
[tex]\mathbf{(c) \ \ \ 2C_3H_7OH + 9O_2 \to 6CO_2+8H_2O}[/tex]
[tex]\mathbf{(d) \ \ \ 2C_5 H_{12}O \to 10 CO_2 + 12 H_2O}[/tex]
Is pre ap chemistry hard in high school?
If you don't practice enough it's obviously going to be hard but if you practice enough it's going to be a piece of cake so don't think if it's going to be hard or not just think it's going to be worth the try at the very end
draw all the possible isomers of octane
Answer:
helps
Explanation:
How many moles of HCl are contained in 0.600 L of 0.120 M HCl?
Please explain and show work.
We know
[tex]\boxed{\Large{\sf Molarity=\dfrac{No\:of\:moles\:of\:solute}{Volume\:of\:solution\:in\;\ell}}}[/tex]
[tex]\\ \Large\sf\longmapsto No\:of\:moles\:of\:HCl=0.6\times 0.12[/tex]
[tex]\\ \Large\sf\longmapsto No\:of\:moles\:of\:HCl=0.072mol[/tex]
Answer:
0.0.72
Explanation:
moles = V*CM=0.6*0.12=0.0.72
