Using the Kf value of 1.2×109 calculate the concentration of Ni2+(aq) and Ni(NH3)62+ that are present at equilibrium after dissolving 1.47 gNiCl2 in 100.0 mL of NH3(aq) solution such that the equilibrium concentration of NH3 is equal to 0.20 M.
Express your answers in moles per liter to two significant figures separated by a comma.

Answers

Answer 1

This problem is describing the equilibrium whereby the formartion of a complex is attained when 1.47 g of nickel(II) chloride is dissolved in 100.0 mL of ammonia so that the latter's equilibium concentration is 0.20 M. Thus, it is asked to calculate the equilibrium concentrations of both nickel(II) ions and that of the complex.

Firstly, we can write out the chemical equation to be considered:

[tex]Ni^{2+}+6NH_3\rightleftharpoons Ni(NH_3)_6^{2+}[/tex]

Next, we can calculate the initial concentration of nickel(II) ions by using the concept of molarity:

[tex][Ni^{2+}]=\frac{1.47gNiCl_2*\frac{1molNiCl_2}{129.6g}*\frac{1molNi^{2+}}{1molNiCl_2} }{0.1000L}=0.113M[/tex]

Afterwards, we set up an equilibrium expression for this chemical reaction:

[tex]Kf=\frac{[Ni(NH_3)_6^{2+}]}{[Ni^{2+}][NH_3]^6}[/tex]

Which can be written in terms of the reaction extent, [tex]x[/tex]:

[tex]Kf=\frac{x}{(0.113-x)(0.2)^6}[/tex]

Now, for the calculation of [tex]x[/tex], we plug in Kf, and solve for it:

[tex]1.2x10^9=\frac{x}{(0.113-x)(0.2)^6}\\\\1.2x10^9=\frac{x}{(0.113-x)(6.4x10^{-5})}\\\\7.68x10^4(0.113-x)=x\\\\x=0.112999 M[/tex]

Which is about the same to the initial concentration of nickel(II) ions because the Kf is too large.

Thus, the required concentrations at equilibrium are about:

[tex][Ni(NH_3)_6^{2+}]=0.113M[/tex]

[tex][Ni^{2+}]=0M[/tex]

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Related Questions

in a certain reaction, Fe and O2 combine to form iron (iii) oxide. 14.7 moles of Fe and 13.0 moles of O2 are placed in a container and the reaction proceeds iwth 100% yield. which is the excess reactant

Answers

Answer:

Fe is the excess reactant

Reaction yields are the amount of the reactant and the products of a chemical reaction. In the reaction between iron and oxygen, iron is the excess agent.

What is excess reactant?

The reactant present in an extra quantity than the other reactant in a chemical reaction which reacts with the limiting reactant is called an excess reactant.

In a reaction mixture, the excess reactant is present even when the limiting agent is completely consumed.

The chemical reaction between iron and oxygen is shown as,

[tex]\rm 4 Fe(s) + 3 O_{2}(g) \rightarrow 2 Fe_{2}O_{3}[/tex]

From the reaction, it can be said that oxygen is a limiting reagent that limits the formation of iron (iii) oxide.

Therefore, iron is an excess reactant.

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a material that is not a mixture; has the same properties all the way through

Answers

Answer:

Explanation:

The material that is not a mixture; it has the same properties all the way through is called a substance. Thus the material that is not a mixture; it has the same properties all the way through is called a substance.

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1.) Calculation: If 9.02 x 1024 particles of vinegar (HC2H3O2)HC2H3O2) are added to 16.5 moles of eggshell (CaCO3) and 6.35 moles g of
calcium acetate is formed. What is the;
(a) theoretical yield,
(b) actual yield and,
(c) percent yield

Answers

The theoretical yield of acetate is 2607 g. The actual yield of acetate is 1066.8 g. The percentage yield of acetate is 41%.

If 1 mole of vinegar contains 6.02  x 10^23 particles

x moles of vinegar contains 9.02 x 10^24 particles

x = 1 mole x 9.02 x 10^24 /6.02 x 10^23

x = 15 moles of vinegar

The reaction is as follows;

2HC2H3O2 + CaCO3 -----> Ca(C2H3O2)2 + H2O + CO2

Since 2 moles of vinegar reacts with 1 mole of carbonate

x moles of vinegar reacts with 16.5 moles of carbonate

x =  2 moles x 16.5 moles/ 1 mole

x = 33 moles of vinegar

We can see that the vinegar is the reactant in excess hence the carbonate is the limiting reactant.

Theoretical yield = 16.5 moles x 158 g/mol = 2607 g

Actual yield = 6.35 moles  x 158 g/mol = 1066.8 g

Percent yield = 1066.8 g/2607 g × 100/1

= 41%

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Do you think the offspring produced by the two processes are genetically identical to organism 1? Explain your reasoning.


Font Sizes

Answers

Answer:

No they are not

Explanation:

I believe that if you under go 1 process then you only get half of the first organism but if you undergo 2 processes then you only get 1/4 of the first organism, but imight be mistaken so sorry if it is wrong.

Can someone help me out with this question and explain me the answer too!!! Please

Answers

Answer:

sorry i dont know

Explanation:

What is it called when you have hydrogen peroxide that just eventually turns into water

Answers

Answer:

chlorine

Explanation:

Answer:chlorine reacts with hydrogen peroxide

Explanation:

When magnesium chloride is formed what question will the student need to ask prior to writing the formula?

A.
What are the oxidation numbers of each atom?

B.
What is the total number of electrons for each atom?

C.
What is the state of matter of each element in the formula?

D.
What period does magnesium belong to?

Answers

Prior to writing the chemical formula of magnesium chloride, a question which any student will need to ask is: A.  What are the oxidation numbers of each atom?

A chemical formula can be defined as a scientific notation that is used to show (represent) the type and total number of atoms that constitute a particular chemical molecule or compound, by using the oxidation number, chemical symbols and subscripts.

Hence, a student would need to know the oxidation numbers of each atom when magnesium chloride is formed after a chemical reaction.

In Chemistry, an oxidation number represents the number of electrons gained or lost by an atom of a chemical element during a chemical reaction.

In conclusion, when magnesium chloride is formed, a question which the student will need to ask prior to writing the chemical formula is "what are the oxidation numbers of each atom?"

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solvent extraction explain ???​

Answers

Answer:

this the partial removal of a substance from a solution or mixture by dissolving it in another immiscible solvent in which it is more soluble.

Milkweed contains a poison known as cardenolides. Monarch butterflies eat the milkweed plant and hold on to this toxic compound. The chemical formula for cardenolides is shown below.
CH18C20H15CHCO2

How many atoms of each element are in one molecule of cardenolides?




A)
34 carbon atoms, 43 hydrogen atoms, and 2 oxygen atoms




B)
42 carbon atoms, 23 hydrogen atoms, and 2 oxygen atoms




C)
20 carbon atoms, 33 hydrogen atoms, and 2 oxygen atoms




D)
23 carbon atoms, 34 hydrogen atoms, and 2 oxygen atoms

Answers

Answer:

the answer is D) 23 carbon atoms, 34 hydrogen atoms, and 2 oxygen atoms

Explanation:

i took the test and got a 100%

What is the SI unit of time?
OA.
second
OB.
minute
OC. hour
OD. day
Res

Answers

[tex]▪▪▪▪▪▪▪▪▪▪▪▪▪  {\huge\mathfrak{Answer}}▪▪▪▪▪▪▪▪▪▪▪▪▪▪[/tex]

The correct choice is ~ A

S.I unit of time is Second

Disadvantage and advantage of iodine ?


- umoren sŭm..​

Answers

THE ADVANTAGE OF IODIN

IODINE CAN LEAD TO GOITER AND OTHER THYROID PROBLEMS.

THE DISADVANTAGE OF IODIN

IODIN MAY LEAD TO THYROIDITIS AND THYROID PAPILLARY CANCER

Question 1(Multiple Choice Worth 50 points)
(01.06 LC)
Which technology removes carbon dioxide from the air by binding to it?
Answers-
O Pyrolization
O Direct-air capture
() Engineered molecules
O Carbon ground injection

Answers

Answer:

Direct-air capture

Explanation:

To understand the technology I'm about to explain, I'll model it to something familiar. As you know, the process of  photosynthesis is where trees and plants use sunlight, water, and carbon dioxide to create energy for themselves, and release oxygen as a byproduct. Direct- air capture is exactly like this. Its pulls in air and then through a range of similiar chemical reactions, it extracts the carbon dioxide from it while returning the rest of the air to the surrounding environment. Except, the Direct-air capture does this at a much faster rate than nature does. The direct-air capture uses a ginormous fan that pulls air in which then passes over plastic surfaces that have potassium hydroxide solutions covered over them. The potassium hydroxide solution chemically binds with the carbon dioxide molecules, removing them from the air and trapping them in the liquid solution as a carbonate salt. The carbon dioxide is then contained where it is compressed and purified and then stored for later use.

What is the use of GMO?

Answers

Some benefits of genetic engineering in agriculture are increased crop yields, reduced costs for food or drug production, reduced need for pesticides, enhanced nutrient composition and food quality, resistance to pests and disease, greater food security, and medical benefits to the world's growing population.

Insect resistance: Corn

Herbicide tolerance: Soybean

In a constant-pressure calorimeter, 55.0 mL of 0.340 M Ba(OH), was added to 55.0 mL of 0.680 M HCI. The reaction caused the temperature of the solution to rise from 22.21 °C to 26.84 °C. If the solution has the same density and specific heat as water (1.00 g/mL and 4.184J/g • °C.) respectively), what is A4 for this reaction (per mole H,O produced)? Assume that the total volume is the sum of the individual volumes.​

Answers

Answer:

Ba(OH)2 + 2 HCl → BaCl2 + 2 H2O

The reactants are present in equimolar amounts, so there is no excess or limiting reactants.

(0.0500 L) x (0.600 mol/L HCl) x (2 mol H2O / 2 mol HCl) = 0.0300 mol H2O

(4.184 J/g·°C) x (50.0 g + 50.0 g) x (25.82 - 21.73)°C = 1711.256 J

(1711.256 J) / (0.0300 mol H2O) = 57042 J/mol = 57.0 kJ/mol H2O

Explanation:

Kinetic energy is described as - The answers are stored energy - destroyed energy movement or created energy if you answer the question I will give you the brainiest.

Answers

1Touch and hold a clip to pin it. Unpinned clips will be deleted after 1 hour.

__________ are negatively charged subatomic particles found in orbital clouds around the nucleus of an atom.

Answers

the answer is electrons :)

A pan containing 40 grams of water was allowed to cool from a temperature of 91.0 °C. If the amount of heat released is 1,300 joules, what is the approximate final temperature of the water? 74 °C 78 °C 81 °C 83 °C

Answers

Answer:

d. 83 °c

Explanation:

Answer:

D. 83 c

Explanation:

took the test

One night a student notices that one-quarter of the moon is visible. What is the likely explanation for this view?

Answers

If a student notices that  one-quarter of the moon is visible, a lunar eclipse has taken place.

Eclipse is said to occur when one of the heavenly bodies casts a shadow on another heavenly body causing it to be partly visible or completely invisible. When the earth comes between the sun and the moon, a lunar eclipse is said to occur.

When a lunar eclipse occurs, the moon may be partly visible or completely invisible. Therefore, if a student notices that  one-quarter of the moon is visible, a lunar eclipse has taken place.

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What is the freezing point, in Celsius, of a sucrose-water solution containing 2.23g sucrose per 100g water. The molal freezing point depression constant for water is 1.86oC/m.

Answers

The freezing point of the solution is - 0.12 oC.

We know that;

ΔT = K m i

ΔT = Freezing point depression

K = Freezing constant

m = molality

i = Van't Hoff factor

Number of moles of sucrose= 2.23g/342 g/mol = 0.0065 moles

Mass of solvent in Kg = 0.1 Kg

Molality of the solution = 0.0065 moles/ 0.1 Kg = 0.065 m

Now;

ΔT = 1.86 oC/m × 0.065 m × 1

ΔT = 0.12 oC

Freezing point of pure water = 0 oC

Freezing point of solution =  0 oC -  0.12 oC = - 0.12 oC

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Because electron delocalization stabilizes a compound, if the only way electrons can be moved is away from the most electroneagtive atom, that is better than no electron delocalization at all.

a. True
b. False

Answers

It’s is false because it is

As electron delocalization stabilizes the compound it is necessary that it takes place for compound to exist , hence the given statement is false.

What is a compound?

Compound is defined as a chemical substance made up of identical molecules containing atoms from more than one type of chemical element.

Molecule consisting atoms of only one element is not called compound.It is transformed into new substances during chemical reactions. There are four major types of compounds depending on chemical bonding present in them.They are:

1)Molecular compounds where in atoms are joined by covalent bonds.

2) ionic compounds where atoms are joined by ionic bond.

3)Inter-metallic compounds where atoms are held by metallic bonds

4) co-ordination complexes where atoms are held by co-ordinate bonds.

They have a unique chemical structure held together by chemical bonds .Compounds have different properties as those of elements because when a compound is formed the properties of the substance are totally altered.

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The Difference between the number of protons and electrons give an atom it’s _________.

Answers

Answer:

it gives an atom its charge

hydrodistillation explain ????​

Answers

Answer:

Explanation:

Hydrodistillation is a traditional method for the extraction of bioactive compounds from plants. In this method, plant materials are packed in a still compartment then water is added in sufficient amount and brought to a boil. ... The vapor mixture of water and oil is condensed by indirect cooling with water.

Draw the skeletal structure of 3-octanethiol

Answers

found a picture hope this helps

p-Nitrobenzaldehyde is more reactive toward nucleophilic additions than pmethoxybenzaldehyde. Explain

Answers

The presence of electron donating methoxy group in  p-methoxybenzaldehyde , makes it less reactive towards  nucleophilic additions.

Nucleophilic addition reactions that involve of p-Nitrobenzaldehyde and p-methoxybenzaldehyde both occur at the C=O functional group. The electron density around the carbonyl is a key factor that controls the reactivity of each compound.

In  p-Nitrobenzaldehyde, the electron withdrawing nitro group decreases the electron density around the carbonyl making it more vulnerable to nucleophilic attack.

In p-methoxybenzaldehyde, the methoxy group donates electrons by resonance towards the carbonyl thereby increasing the electron density around it so that it is less reactive towards nucleophillic addition reaction.

The nucleophilic attack on p-Nitrobenzaldehyde leads to more resonance structures than nucleophilic attack on p-methoxybenzaldehyde.

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My QUESTION
A car is travelling 35 miles per hour. How fast is it going when
measured in meters per minute?


Answers

Answer:

933.33 m/ min

Explanation:

1 mile = 1.6 km

So the car travels 1.6× 35 km in 1 hour

One hour has 60 minutes

So speed of car = 1.6×35 km / 60 minutes

1km = 1000 m

Speed = 1.6×35×1000 m/ 60 minutes

= 933.33 meters per minute

A car is traveling 35 miles per hour. The speed that is measured in meters per minute is 933.33 m/ min.

What is speed?

Speed is the dimension of distance. It is calculated in meters per second. It is the rate of change of an object in a direction. Speed is calculated by dividing the distance by time. It is a scalar quantity.

Given, that a car is traveling 35 miles per hour. The speed is given, in miles we just have to convert the miles into meters per minute. Miles if the English unit of measurement and meter is the SI unit of measurement.

1 mile = 1.6 km

So the car travels 1.6× 35 km in 1 hour

One hour has 60 minutes

So speed of car = 1.6×35 km / 60 minutes

1km = 1000 m

Speed = 1.6 × 35 × 1000 m/ 60 minutes

= 933.33 meters per minute

Thus, the speed of the car is 933.33 m/ min.

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When the pressure of an equilibrium mixture of SO2, O2, and SO3 is doubled at constant temperature, what the effect on Kp

Answers

When the pressure of the equilibrium mixture of SO2, O2, and SO3 is doubled at constant temperature, the Kp is also doubled.

The equation of the reaction is given by; 2SO2 + O2 → 2SO3. The Kp of the reaction is obtained from;

Kp = pSO3^2/pSO2^2 . pO2

Since the Kp depends on the individual partial pressures of each of SO2, O2, and SO3 at equilibrium, if the pressure of the equilibrium mixture is doubled, the Kp is also doubled.

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a. Calculate the change in enthalpy when 20.0 grams of aluminum metal is heated from 298 K to 573 K at constant pressure of 1 atm.
b. Calculate the change in enthalpy when 20.0 grams of metallic lead is taken through the same process. In both cases assume the heat capacity values predicted by equipartition are valid through the temperature range stated.

Answers

Choose all options that apply. Which of the following measurements are equivalent to six feet? a) 72 inches b) 3 meters c) 182.88 cm O d) 1.25 yards

1.An object that produces electrical energy through redox reactions is called ____________.

oxidation

reduction

galvanic/voltaic cell


2.Which species undergoes oxidation?

Pb

Cu

Answers

[tex] \huge \bf༆ Answer ༄[/tex]

Question : - 1

An object that produces electrical energy through redox reactions is called Galvanic cell

Question : - 2

Pb undergoes Oxidation

[tex]꧁ \: \large \frak{Eternal \: Being } \: ꧂[/tex]

Test I. Write the specialized body structures of the following animals that can enable them adapt in the land

1. snake

Answers

Answer: specialized body structures of Snakes

Explanation:

Snakes have many adaptations that allow them to move, hunt, eat and survive in their environments. Many animals have developed specific parts of the body adapted to survival in a certain environment. Among them are webbed feet, sharp claws, whiskers, sharp teeth, large beaks, wings, and hooves. In most aquatic animals, swimming is a must. To aid swimming, many animals have adapted and evolved with webbed feet.

describe radioisotope

Answers

Answer:

It is an unstable form of a chemical element that releases radiation as it breaks down and becomes more stable.

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