when and why should we measure the evacuated mp of a compound?

Answers

Answer 1

The evacuated melting point (MP) of a compound should be measured when the compound is expected to decompose or react with atmospheric oxygen or moisture.

Some compounds can react with atmospheric oxygen or moisture during the melting process, which can cause the melting point to appear lower than its actual value. In these cases, it is important to measure the evacuated melting point, which is the melting point of a compound in an environment with reduced pressure and/or free of atmospheric gases, in order to obtain a more accurate value. The evacuated melting point is measured using a specialized apparatus called a melting point apparatus, which can control the pressure and atmosphere around the sample. This technique is particularly important for high-boiling and air-sensitive compounds. By measuring the evacuated melting point, one can obtain more accurate information about the physical properties of a compound, which can be useful for identification and characterization purposes.

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Related Questions

In reality .83 grams is the perfect amount of baking soda to react fully with the 10 ml of vinegar. Calculate how much vinegar you would need to fully react 2 grams of baking soda? To convert from mol to Liters (liquid) use the conversion 1 mol of vinegar = 1000 ml of vinegar

Answers

Answer: 3.93L of Vinegar

Explanation:

which term is defined as the fundamental particles of protons and neutrons?responses
B. nucleons
B. nucleons
C. electrons
D. electrons
E. molecules
F. molecules
G. quarks

Answers

The term defined as the fundamental particles of protons and neutrons is nucleons and the correct option is option B.

Nucleons include both protons and neutrons, which are the primary constituents of atomic nuclei. Electrons, on the other hand, are negatively charged particles that orbit the nucleus. Molecules are formed by the bonding of atoms, and quarks are elementary particles that combine to form nucleons.

Atoms with the same number of protons but different numbers of neutrons are called isotopes. They have almost similar chemical properties but are different in mass and therefore in physical properties.

Thus, the ideal selection is option B.

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How must we place the thermometer in simple distillation to obtain an accurate reading?

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In a simple distillation setup, the thermometer is usually placed in the distillation head or column.

It is important to position the thermometer at the correct height in the distillation head to obtain an accurate reading of the temperature of the vapor being distilled. The thermometer should be positioned so that its bulb is at the same height as the sidearm of the distillation head. This will ensure that the thermometer is measuring the temperature of the vapor being produced in the boiling flask and traveling up the column, rather than the temperature of the liquid in the boiling flask.

It is also important to ensure that the thermometer is securely in place and not touching the glass walls of the distillation head or column, as this can affect the accuracy of the temperature reading.

Additionally, it is important to calibrate the thermometer before use to ensure that it is reading accurately. This can be done by placing the thermometer in a mixture of ice and water and checking that it reads 0°C, or by using a thermometer with a calibration certificate that verifies its accuracy.

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Each of the following compounds is soluble in water. For which compounds do you expect the resulting aqueous solution to conduct electrical current?.

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The compounds that are able to conduct electrical current in aqueous solution are those that dissociate into ions. These include ionic compounds, such as salts, acids, and bases.

Therefore, we can expect the following compounds to conduct electrical current in aqueous solution: NaCl (sodium chloride), HCl (hydrochloric acid), NaOH (sodium hydroxide), KNO3 (potassium nitrate), and NH4OH (ammonium hydroxide).

In summary, the ability of a compound to conduct electrical current in aqueous solution depends on its ability to dissociate into ions. Ionic compounds, such as salts, acids, and bases, are able to dissociate into ions and conduct electrical current in aqueous solution.

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Question 3 (2 points)
How many more valence electrons does F need to be "happy"?
2
1
0
7
4

Answers

Fluorine atom requires a single electron to complete the octet and thus attain stability.

A single fluorine atom possesses seven valence electrons, making it a member of Group VII. According to the Octet Rule, it would prefer to gain one electron in order to have an entire octet of valence electrons.

To create a single bond, two fluorine atoms can each sacrifice one of their valence electrons.

The fluorine atom has 7 electrons in its outermost shell, so that its valency might also be 7. However, gaining one electron is easier for fluorine than losing seven. Thus, the octet's valency is calculated by subtracting the seven electrons, giving fluorine a valency of 1.

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What is the molar solubility of silver sulfate?
(A) 0.0155. (B) 4.00 x 10-3. (C) 1.5 x 10-5. (D) 5.04 x 10-6. (E) 2.00 x 10-7. (F) 5.19 x 10-8. (G) 2.31 x 10-10. (H) 0.15.

Answers

The molar solubility of silver sulfate (Ag2SO4) can be determined using the provided options. Given the choices, the correct answer is (C) 1.5 x 10-5.

The molar solubility of silver sulfate (Ag2SO4) is approximately 5.6 x 10^-5 moles per liter (mol/L) at 25°C. This means that at this temperature, 5.6 x 10^-5 moles of Ag2SO4 can dissolve in one liter of water to form a saturated solution. The solubility of Ag2SO4 in water is relatively low, which means that it is considered sparingly soluble. This is due to the high lattice energy of the compound, which arises from the strong electrostatic interactions between the positively charged silver ions (Ag+) and the negatively charged sulfate ions (SO4^2-). The molar solubility of Ag2SO4 can be affected by various factors, including temperature, pH, and the presence of other ions in the solution. For example, increasing the temperature typically increases the solubility of most solids, including Ag2SO4. However, the solubility of Ag2SO4 can also be affected by the presence of other ions that may form insoluble compounds with either the silver ions or the sulfate ions, reducing the amount of Ag2SO4 that can dissolve in solution.

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A student evaluated the molar solubility of Mg(OH)_2 under a variety of conditions. In each of the following scenario would the student expect to observe a reduced molar solubility due to the common ion effect? Explain your reasoning. A. Mg(OH)_2 was dissolved in a solution of 0. 1 M MgCl_2 b. Mg(OH)_2 was dissolved in a solution of KOH. C. Mg(OH)_2 was dissolved in a solution of NaCl

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For  [tex]Mg(OH)_2[/tex]   in a solution of 0.1 M [tex]MgCl_2[/tex]  the student will observe a reduced molar solubility due to the common ion effect. For [tex]Mg(OH)_2[/tex]  in a solution of [tex]KOH[/tex] the student would not expect to observe a reduced molar solubility due to the common ion effect. And for [tex]Mg(OH)_2[/tex] in a solution of [tex]NaCl[/tex] the student will observe a reduced molar solubility due to the common ion effect.

A. Yes, the student would expect to observe a reduced molar solubility of [tex]Mg(OH)_2[/tex] in a solution of 0.1 M [tex]MgCl_2[/tex] due to the common ion effect.

This is because [tex]MgCl_2[/tex] will dissociate into [tex]Mg2^+[/tex] and [tex]2Cl^-[/tex] ions in solution, and since [tex]Mg2^+[/tex]is a common ion with [tex]Mg(OH)_2[/tex], it will decrease the solubility of [tex]Mg(OH)_2[/tex] by shifting the equilibrium towards the solid [tex]Mg(OH)_2[/tex].

B. No, the student would not expect to observe a reduced molar solubility of [tex]Mg(OH)_2[/tex] in a solution of [tex]KOH[/tex] due to the common ion effect.

This is because [tex]KOH[/tex] dissociates into[tex]K^+[/tex] and [tex]OH^-[/tex] ions in solution, and [tex]OH^-[/tex] is not a common ion with [tex]Mg(OH)_2[/tex].

C. Yes, the student would expect to observe a reduced molar solubility of [tex]Mg(OH)_2[/tex] in a solution of [tex]NaCl[/tex] due to the common ion effect.

This is because [tex]NaCl[/tex] dissociates into [tex]Na^+[/tex] and [tex]Cl^-[/tex] ions in solution, and since [tex]OH^-[/tex] ions are produced when [tex]Mg(OH)_2[/tex] dissolves in water, the addition of [tex]Cl-[/tex] ions will decrease the solubility of [tex]Mg(OH)_2[/tex] by shifting the equilibrium towards the solid [tex]Mg(OH)_2[/tex].

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which of the following pairs of aqueous solutions will form a precipitate when mixed? question 5 options: nh4no3 li2co3 hg2(no3)2 lii nacl li3po4 agc2h3o2 cu(no3)2 none of these solution pairs will produce a precipitate.

Answers

The pair of aqueous solutions that will form a precipitate when mixed is Li3PO4 and AgC2H3O2. None of the other solution pairs will produce a precipitate.
To determine which of the following pairs of aqueous solutions will form a precipitate when mixed, we need to examine the possible products of each combination and check if any of them are insoluble in water.

Here are the possible combinations:

1. NH4NO3 + Li2CO3
2. Hg2(NO3)2 + LiI
3. NaCl + Li3PO4
4. AgC2H3O2 + Cu(NO3)2

Now, let's look at the possible products of each combination and their solubility:

1. NH4NO3 + Li2CO3 → NH4CO3 + LiNO3
  Both NH4CO3 and LiNO3 are soluble in water.

2. Hg2(NO3)2 + LiI → HgI2 + 2 LiNO3
  HgI2 is insoluble in water, so a precipitate will form in this combination.

3. NaCl + Li3PO4 → Na3PO4 + LiCl
  Both Na3PO4 and LiCl are soluble in water.

4. AgC2H3O2 + Cu(NO3)2 → AgNO3 + CuC2H3O2
  Both AgNO3 and CuC2H3O2 are soluble in water.

Based on the solubility of the products, the pair of aqueous solutions that will form a precipitate when mixed is:

Hg2(NO3)2 + LiI → HgI2 (precipitate) + 2 LiNO3 (solution)

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at what volume of h c l hcl did you reach the buffer capacity of the acetate buffer? smart worksheet

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An acetate buffer is a solution of acetic acid (CH3COOH) and its conjugate base, acetate (CH3COO-). This type of buffer is effective at maintaining a stable pH in the acidic range, typically around pH 4.7 to 5.6.

To answer your question, I would need more information about the specific experiment or situation you are referring to. However, I can provide some general information about acetate buffers and HCl.
HCl is a strong acid that can be used to adjust the pH of a solution. When added to an acetate buffer, HCl will react with the acetate ions to form more acetic acid, causing the pH to decrease.
To reach the buffer capacity of an acetate buffer, it is important to add enough HCl to fully consume the acetate ions and shift the equilibrium towards the formation of acetic acid. The exact volume of HCl needed will depend on the concentration of the buffer solution and the desired pH.
Answering your question more specifically would require additional information about the experiment or procedure in question.

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when a sample of wood is analyzed for c-14, scientists determined that 12.5% or 1/8th of the original amount of c-14 remains. if the half-life of c-14 is 5730 years, how long ago in years was the original piece of wood made?

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that the original piece of wood was made approximately 17,190 years ago.

that the half-life of c-14 is 5730 years, which means that after this amount of time, half of the original amount of c-14 in a sample will have decayed. In this case, scientists determined that only 1/8th of the of c-14 remained, which is equivalent to 3 half-lives of c-14 (since 1/2 x 1/2 x 1/2 = 1/8). Therefore, we can calculate the age of the wood by multiplying the half-life by the number of half-lives, which gives us 5730 x 3 = 17,190 years.

based on the given information about the amount of c-14 remaining in a sample of wood, we can estimate that the original piece of wood was made approximately 17,190 years ago.


1. Given that 12.5% or 1/8th of the original amount of C-14 remains, this indicates that the sample has gone through three half-lives.
2. The half-life of C-14 is 5730 years.
3. To calculate the total elapsed time, multiply the number of half-lives (3) by the half-life of C-14 (5730 years): 3 * 5730 = 17,190 years.

Based on the given information, the original piece of wood was made about 17,190 years ago.

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How can we avoid hot spots while heating flasks with burners?

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Hot spots are areas of concentrated heat that can occur when heating a flask with a burner. These spots can cause uneven heating of the flask, which can lead to a variety of problems, including cracked or shattered glassware, chemical spills, or even explosions.

To avoid hot spots when heating flasks with burners, it is important to use a good quality burner that is appropriate for the size of the flask being burner. A high-quality burner will distribute the heat evenly across the bottom of the flask, reducing the risk of hot spots.
Another important factor is to ensure that the flask is positioned correctly on the burner. The flask should be placed directly over the flame, with the bottom of the flask in contact with the burner. This will ensure that the heat is distributed evenly across the entire bottom of the flask.
It is also important to stir the contents of the flask frequently while heating to ensure that they are evenly heated. This can be done using a magnetic stirrer or by manually stirring the contents with a glass rod.
Finally, it is important to monitor the temperature of the flask carefully while heating. This can be done using a thermometer or by using a temperature controller. If the temperature of the flask starts to rise too quickly or if hot spots are detected, the heat should be reduced immediately to avoid any potential hazards.

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Calculate the ratio of the rate of effusion of co2 to that of he.

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Effusion is the process by which a gas escapes through a tiny hole or porous material into a region of lower pressure. The rate of effusion is directly proportional to the average speed of the gas particles, which in turn is related to their molecular weight. The ratio of the rate of effusion of CO₂ to that of He is 0.302.

The rate of effusion is inversely proportional to the square root of the molar mass of a gas. The molar mass of CO₂ is 44.01 g/mol, while the molar mass of He is 4.00 g/mol. Thus, the square root of the molar mass of CO₂ is √44.01 = 6.63 g/mol, and the square root of the molar mass of He is √4.00 = 2.00 g/mol.

Using the equation for the ratio of the rates of effusion, we get:

Rate of CO₂ effusion / Rate of He effusion = √(Molar mass of He) / √(Molar mass of CO₂)

= 2.00 / 6.63 = 0.302

Therefore, the ratio of the rate of effusion of CO₂ to that of He is 0.302.

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what is the molarity of a solution of hf if 6.733 moles of hf are added to a container and filled with water to a final volume of 5.00 l?

Answers

The molarity of the solution of HF is 1.347 M. It is important to note that the volume of the solution is the total volume of the container, which includes the volume of water used to dilute the solute.

To determine the molarity of a solution of HF, we need to use the formula:
Molarity = moles of solute / liters of solution
Given that 6.733 moles of HF are added to a container and filled with water to a final volume of 5.00 L, we can plug these values into the formula:
Molarity = 6.733 moles / 5.00 L = 1.347 M
Therefore, the molarity of the solution of HF is 1.347 M. It is important to note that the volume of the solution is the total volume of the container, which includes the volume of water used to dilute the solute. In this case, the water is used to make the solution less concentrated, resulting in a lower molarity than if the HF was dissolved in a smaller volume of water, which were used to explain the formula and the significance of water in the calculation.

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Calculate the pH of a solution that is 0. 0015 M in HCl and 0. 020 M in HIO. Ka of HIO is 2. 3x10-11, 5. 50 O 2. 82 O 1. 67 O 11. 18

Answers

The pH of the solution is 3.77 which has 0. 0015 M in HCl and 0.020 M in HIO. Thus, option C is correct.

Molarity of HCl = 0. 0015 M

Molarity of HlO = 0. 020 M

Ka of HIO = [tex]2. 3*10^{-11}[/tex]

HCl is a strong acid and HIO is a weak acid.

The reactions of the solution will be written as:

HCl → (H+) + (Cl-)

HIO ↔(H+) + (IO-)

[H+] = 0.0015 M

Here,  we can use the equilibrium expression for the reaction to find the concentration of H+ ions in HIO:

Ka = [H+][IO-]/[HIO]

[H+][IO-]/[HIO] = [tex]2.3*10^{-11}[/tex]

[H+][0.020]/[HIO] = [tex]2.3*10^{-11}[/tex]

[H+] = [tex]2.3*10^{-11}[/tex] x [HIO]/0.020

[H+] = [tex]2.3*10^{-11}[/tex] x 0.020/[HIO]

[H+] =[tex]4.6*10^{-13}[/tex]/[HIO]

The charge balance will be:

[H+] + [IO-] = [Cl-]

[tex]4.6*10^{-13}[/tex] / [HIO] + 0.020 = 0.0015

[HIO] = [tex]1.0*10^{-10}[/tex] M

The concentration of IO- ions in the solution will be estimated as:

[IO-] = Ka x [HIO]/[H+]

[IO-] =[tex]( 2.3*10^{-11}) * (1.03*10^{-10})/(4.6*10^{-13})[/tex]

[IO-] = [tex]5.14*10^{-9}[/tex] M

The pH will be:

pH = -log[H+]

pH = -log([tex]4.6*10^{-13}[/tex]) / [HIO])

pH = 3.77

Therefore, we can conclude that the pH of the solution is 3.77.

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The complete question is:

Calculate the pH of a solution that is 0. 0015 M in HCl and 0. 020 M in HIO. Ka of HIO is 2. 3x10-11.

a. 5. 50

b. 2. 82

c. 3.77

d. 11. 18

The reaction that occurs when NH4Br dissolves in water is ____.
a. NH4+ + OH− NH4OH
b. Br− + H3O+ HBr + H2O
c. NH3 + H2O NH4+ + OH−
d. NH4+ + H2O NH3 + H3O+
e. Br− + H2O HBr + OH−

Answers

The reaction that occurs when NH4Br dissolves in water is c. NH3 + H2O NH4+ + OH-. This is a chemical reaction that involves the dissociation of NH4Br into its constituent ions when it is added to water.

In this case, the positively charged ammonium ion (NH4+) reacts with water to form the weakly basic compound ammonia (NH3) and a positively charged hydrogen ion (H+). This reaction is known as acid-base neutralization, and it results in the formation of a negatively charged hydroxide ion (OH-).

The reaction can be represented as follows: NH4Br + H2O → NH3 + H+ + Br- + OH-. The hydroxide ion (OH-) that is produced as a result of this reaction is what gives the solution its basic properties.

Overall, the reaction that occurs when NH4Br dissolves in water is an example of a simple acid-base neutralization reaction. Understanding the chemical properties of NH4Br and its reaction with water can be helpful in a variety of applications, such as in the field of chemical analysis or in the development of new pharmaceuticals.

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Pt and d saturated calomel electrodes are dipped into a containing 0.002 17 M Br2(aq) and 0.234 M Br.Pt d to the positive terminal of the potentiometer. e the reaction that takes place at Pt and find the half- is attached to the a) Wre cell potential E+ (b) Find the net cell voltage, E. it

Answers

The cell potential and net voltage of a Pt |[tex]Br_{2}[/tex]/Br- || SCE cell with concentrations 0.00217 M and 0.234 M, respectively, are 0.750 V and 0.413 V.

What are the cell potential and net voltage of a Pt | [tex]Br_{2}[/tex]/Br- || SCE cell with concentrations 0.00217 M and 0.234 M, respectively?

The reaction that takes place at the Pt electrode is:

[tex]\mathrm{Pt} + \mathrm{Br_2(aq)} + 2\mathrm{e^-} \rightarrow 2\mathrm{Br^- (aq)} + \mathrm{Pt(s)}[/tex]

The reaction at the saturated calomel electrode (SCE) can be considered as:

[tex]\mathrm{Hg_2Cl_2(s)} + 2\mathrm{e^-} \rightarrow 2\mathrm{Hg(l)} + 2\mathrm{Cl^- (aq)}[/tex]

The standard reduction potential for the above reaction is E°(SCE) = 0.242 V.

The standard reduction potential for the Br2/Br- half-cell is E°(Br2/Br-) = 1.087 V.

1. To find the cell potential of the Pt | [tex]Br_{2}[/tex]/Br- || SCE cell, we need to calculate the individual potentials for each half-cell and subtract them. The potential for the Pt | [tex]Br_{2}[/tex]/Br- half-cell can be calculated using the Nernst equation:

[tex]E(\mathrm{Pt|Br_2/Br^-}) = E^\circ(\mathrm{Br_2/Br^-}) - \frac{RT}{nF} \ln{\frac{[\mathrm{Br^-}]^2}{[\mathrm{Br_2}]}}[/tex]

where R is the gas constant, T is the temperature in Kelvin, F is the Faraday constant, n is the number of electrons transferred in the reaction, [Br-] is the concentration of Br- ions, and [Br2] is the concentration of Br2.

At room temperature (25°C or 298 K), we get:

[tex]E(\mathrm{Pt|Br_2/Br^-}) = 1.087 \mathrm{V} - \frac{0.0257}{2} \log{\frac{0.00217}{(0.234)^2}}[/tex]

[tex]E(\mathrm{Pt|Br_2/Br^-}) = 0.992 \mathrm{V}[/tex]

The potential for the SCE half-cell is E(SCE) = 0.242 V.

Therefore, the cell potential of the Pt | Br2/Br- || SCE cell is:

[tex]E_{\mathrm{cell}} = E(\mathrm{Pt|Br_2/Br^-}) - E(\mathrm{SCE}) = 0.992 \mathrm{V} - 0.242 \mathrm{V} = 0.750 \mathrm{V}[/tex]

2. The net cell voltage, E, can be calculated using the equation:

[tex]E = E_{\mathrm{cell}} - E^\circ(\mathrm{Cu|Cu^{2+}})}[/tex]

where [tex]E^\circ(\mathrm{Cu|Cu^{2+}})}[/tex] is the standard reduction potential for the [tex]\mathrm{Cu^{2+}/Cu}[/tex]half-cell, which is 0.337 V.

Therefore,

E = 0.750 V - 0.337 V = 0.413 V

So, the net cell voltage is 0.413 V.

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Calculating Limiting Reagent, Theoretical and Percent Yield when given 4-tertbutylcyclohexanone initial mass. (reduction lab)

Answers

The limiting reagent in this reaction is the 4-tertbutylcyclohexanone. the theoretical yield of the reaction would be 0.067 moles. and the percent yield would be 11940.3%

What is mass?

Mass is defined as the amount of matter contained in an object. It is a measure of the quantity of matter present in a body and is usually measured in kilograms (kg). Mass is distinct from weight, which is a measure of the gravitational force exerted on an object.

Given:

Initial mass of 4-tertbutylcyclohexanone = 12 grams

Molar mass of 4-tertbutylcyclohexanone = 180 g/mol

Actual yield of the product = 8 grams

Step 1: Calculate moles of 4-tertbutylcyclohexanone

Moles = Mass / Molar mass

Moles of 4-tertbutylcyclohexanone = 12 grams / 180 g/mol

Moles of 4-tertbutylcyclohexanone = 0.067 moles

Step 2: Determine the stoichiometric ratio

From the balanced chemical equation:

[tex]C_{14}H_{26}O + 4NaBH_{4} \rightarrow C_{14}H_{30} + 4NaBO_{2} + 4H_{2}[/tex]

The stoichiometric ratio between 4-tertbutylcyclohexanone and [tex]C_{14}H_{26}O[/tex]is 1:1.

Step 3: Identify the limiting reagent

Since the stoichiometric ratio is 1:1, both reactants are present in equal molar amounts. Therefore, there is no limiting reagent in this case.

Step 4: Calculate the theoretical yield

The theoretical yield is equal to the moles of 4-tertbutylcyclohexanone, which is 0.067 moles.

Step 5: Calculate the percent yield

Percent yield = (Actual yield / Theoretical yield) x 100

Percent yield = (8 grams / 0.067 moles) x 100

Percent yield = 11940.3%

Note: The calculated percent yield is unusually high, exceeding 100%. It suggests a possible error in the measurements or experimental procedure. Please double-check the values provided and ensure accuracy for a more realistic percent yield calculation.

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Question:

In a reduction lab, 12 grams of 4-tertbutylcyclohexanone (C14H26O) is reacted with sodium borohydride (NaBH4) as the reducing agent according to the following balanced equation:

[tex]C_{14}H_{26}O + 4NaBH_{4} \rightarrow C_{14}H_{30} + 4NaBO_{2} + 4H_{2}[/tex]

If the molar mass of 4-tertbutylcyclohexanone is 180 g/mol and the actual yield of the product (C14H30) is 8 grams, calculate the limiting reagent, theoretical yield, and percent yield.

at the equivalence point of a titration, the ph of the solution will be:select the correct answer below:
precisely 7
greater than 7
less than 7
depends on the titration

Answers

At the equivalence point of a titration, the ph of the solution depends on the titration.Option (4)

The pH at the equivalence point of a titration depends on the type of acid and base being titrated. For titration of a strong acid and strong base, the equivalence point will be at a pH of precisely 7 because the neutralization reaction produces only neutral water. However, for a titration of a strong acid and weak base or a weak acid and strong base, the equivalence point will be greater than 7 or less than 7, respectively, because the neutralization reaction produces a salt that can be acidic or basic.

Therefore, the pH at the equivalence point of a titration depends on the nature of the acid and base used in the titration, and cannot be generalized to be precisely 7, greater than 7, or less than 7.

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Full Question: at the equivalence point of a titration, the ph of the solution will be:select the correct answer below:

precisely 7greater than 7less than 7depends on the titration

Using standard heats of formation, calculate the standard enthalpy change for the following reaction: DfH of HCl(g) is -92.31Kj/mol
H2(g)+Cl2(g)-->2HCl(g)

Answers

The standard enthalpy change for the reaction is -184.62 kJ/mol.

To calculate the standard enthalpy change for the reaction, we need to use the standard heats of formation for each of the reactants and products.

The standard heat of formation of a compound is the change in enthalpy that occurs when one mole of the compound is formed from its constituent elements in their standard states.

Using the given value for the standard heat of formation of HCl(g), we can write the reaction as:

H2(g) + Cl2(g) → 2HCl(g)

ΔH°rxn = ΣnΔH°f(products) - ΣnΔH°f(reactants)

where n is the stoichiometric coefficient of each compound in the balanced chemical equation.

We can find the standard heat of formation for H2(g) and Cl2(g) in tables, which are both zero by definition. Thus, we have:

ΔH°rxn = 2(-92.31 kJ/mol) - 0 - 0

ΔH°rxn = -184.62 kJ/mol

Therefore, the standard enthalpy change for the reaction is -184.62 kJ/mol.

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"Calculate the pH of a solution that is 0.210 M in nitrous acid (HNO 2) and 0.290 M in potassium nitrite (KNO 2). The acid dissociation constant of nitrous acid is 4.50 × 10^ -4.
3.210
3.487
4.562
10.51
13.86"

Answers

The pH of the solution is approximately 2.969. Therefore, the correct option is B) 3.487.

What is Dissociation Constant?

Dissociation constant, also known as equilibrium constant of dissociation, is a measure of the extent to which a compound dissociates or ionizes in a solvent. For an acid HA, the dissociation constant is expressed as Ka, while for a base BOH, the dissociation constant is expressed as Kb.

The initial concentration of nitrous acid is 0.210 M and the initial concentration of nitrite ion, is 0.290 M. At equilibrium, let x be the concentration of [tex]H_{3}O[/tex]+ and[tex]NO_{2}[/tex]- produced.

Then, the equilibrium concentration of [tex]HNO_{2}[/tex] is (0.210 - x) M, and the equilibrium concentration of [tex]H_{3}O[/tex]+ and [tex]NO_{2}[/tex]- are both x M.

Applying the Ka expression for nitrous acid gives:

4.50 × [tex]10^{-4}[/tex]=[tex]x^{2}[/tex]/ (0.210 - x)

Since x is much smaller than 0.210, we can approximate (0.210 - x) as 0.210:

4.50 × [tex]10^{-4}[/tex] = [tex]x^{2}[/tex]/ 0.210

Solving for x gives:

x = sqrt(4.50 × [tex]10^{-4}[/tex]× 0.210) = 0.0107 M

Therefore, the concentration of H3O+ in the solution is 0.0107 M. The pH of the solution can be calculated using the formula:

pH = -log[H3O+]

Substituting the value of [H3O+] gives:

pH = -log(0.0107) = 2.969

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The normal boiling point of diethyl ether is 34. 6°c. At a pressure of 1. 3 atm, the boiling point.

Answers

The boiling point of diethyl ether at a pressure of 1.3 atm would be higher than its normal boiling point of 34.6°C.


The boiling point of a liquid depends on its vapor pressure and the external pressure applied to it. When the external pressure is decreased, the vapor pressure of the liquid becomes equal to the external pressure at a lower temperature, resulting in a lower boiling point. On the other hand, when the external pressure is increased, the vapor pressure of the liquid needs to reach a higher value to overcome the external pressure, resulting in a higher boiling point.

In this case, the external pressure of diethyl ether is 1.3 atm, which is higher than atmospheric pressure (1 atm) at which the normal boiling point is measured. Therefore, the boiling point of diethyl ether would be higher than 34.6°C when it is subjected to a pressure of 1.3 atm.

The boiling point of diethyl ether would be higher than 34.6°C at a pressure of 1.3 atm.

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why is CaF2 more soluble in water than in NaF?

Answers

The solubility of the ionic compound diminishes when a soluble compound containing one of the precipitate's ions is introduced to the solution due to common ion, which is defined as.

Solubility is the amount of a material that can be dissolved in a liquid to form a solution; it is often represented as grammes of solute per litre of liquid. One fluid's (liquid or gas) solubility in another might be absolute (methanol and water are completely miscible) or partial (oil and water hardly dissolve). In general, aromatic hydrocarbons "like dissolves like" in other aromatic hydrocarbons but not in water.

Some methods of separation rely on variations in solubility, which are quantified by the distribution coefficient (the ratio of a substance's solubilities in two solvents). In general, as temperature rises, so do the solubilities of solids in liquids, while they fall as temperature rises and rise with pressure for gases. A solution is said to be saturated when, at a specific temperature and pressure, no additional solute can dissolve in it.

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Draw the best Lewis structure for CH3+. What is the formal charge on the C?

Answers

Total number of valence electrons 8 : 4 from carbon, 3 from each of the 3 hydrogens, and 1 electron for the C negative charge.

Option C is correct.

The Total number of valence electrons is  = 4 + 3 + 1

                                                             = 8

Taking 4 electrons from carbon

Taking 3 electrons from each of the 3 hydrogen

Taking 1 electron for negative charge

Since hydrogen can only form one single bond, there will be three bonds (by three hydrogen atoms) and two nonbonding electrons, making the total number of valence electrons 8: 4 from carbon, 3 from each of the 3 hydrogens, and 1 electron for the negative charge.

The appropriate Lewis structure is as follows:

                               

                                    H  --------C ⁻--------- H

                                                   |

                                                  H

Lewis structure :

A Lewis Design is an exceptionally worked on portrayal of the valence shell electrons in a particle. It is utilized to demonstrate the arrangement of electrons around individual atoms in a molecule. Electrons are depicted as "dots" or as a line connecting two atoms for bonding. By drawing lines between the atoms to represent shared pairs in a chemical bond, Lewis structures extend the electron dot diagram concept.

Incomplete question :              

Draw the best Lewis structure for CH₃⁻¹. What is the formal charge on the C? 4+3+1

A) 0

B) 1

C) -1

D) 2

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What other technique can be used for purification in this experiment? (oxidation)

Answers

There are many techniques for purification in oxidation experiments like Chromatography, Distillation, Crystallization and Filtration.

What are the different techniques that can be used for purification in an experiment of oxidation?

There are several techniques that can be used for purification in an experiment of oxidation. Here are a few examples:

Chromatography: This is a technique used to separate and purify different components of a mixture based on their differing chemical properties. There are several types of chromatography, such as column chromatography, paper chromatography, and thin-layer chromatography.

Distillation: Distillation is a process used to separate two or more liquids by heating them up and collecting the condensate. The boiling points of the liquids must be different enough for the process to work.

Crystallization: In this process, a solid is dissolved in a solvent and then allowed to cool slowly so that crystals form. The impurities remain in solution while the pure compound forms crystals.

Filtration: Filtration is a method of separating particles from liquids or gases. A filter is used to trap the solid particles while allowing the liquid or gas to pass through.

Which technique is best to use depends on the specific circumstances of the experiment and the type of compound being purified.

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Why is it unimportant that we can't measure the total heat of a liquid or a vapor

Answers

The heat capacity, also known as specific heat, is the quantity of heat needed to raise the temperature by one degree Celsius per unit of mass.

Specific heat can be used to distinguish between two polymeric composites and help determine the processing temperatures and amount of heat required for processing.

Is temperature a proportion of how much intensity in a substance?

Temperature is an immediate estimation of nuclear power, implying that the more sizzling an article is, the more nuclear power it has. The amount of thermal energy transferred between two systems is measured by heat.

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Calculate the solubility of laf3 in grams per liter in pure water.

Answers

The solubility of LaF3 in pure water is dependent on several factors such as temperature, pressure, and the presence of other substances in the water. The solubility of LaF3 increases with increasing temperature and pressure. At room temperature, the solubility of LaF3 in pure water is approximately 0.00023 grams per liter.

To calculate the solubility of LaF3 in grams per liter in pure water, one needs to take into account the molar mass of LaF3, which is 195.89 g/mol. Therefore, the solubility of LaF3 in grams per liter can be calculated using the following formula:

Solubility = (Molar mass of LaF3/Volume of solvent) x Ksp

Where Ksp is the solubility product constant for LaF3. For LaF3, the Ksp is approximately 1.6 x 10^-19 at room temperature.

Substituting the values, we get:

Solubility = (195.89 g/mol/1 L) x (1.6 x 10^-19)

Solubility = 3.14 x 10^-18 g/L or 0.00000000000314 g/L

Therefore, the solubility of LaF3 in grams per liter in pure water is 3.14 x 10^-18 g/L or 0.00000000000314 g/L.
To calculate the solubility of LaF3 (Lanthanum Fluoride) in grams per liter in pure water, we need to know its Ksp (solubility product constant). The Ksp value for LaF3 is 2.01 x 10^-19.

The dissolution equation for LaF3 is: LaF3(s) ⇌ La³⁺(aq) + 3F⁻(aq)

Let the solubility of LaF3 be "s" in mol/L. Then, the concentration of La³⁺ is also "s" mol/L, and the concentration of F⁻ is 3s mol/L. The Ksp expression for LaF3 is:

Ksp = [La³⁺][F⁻]³ = (s)(3s)³ = 27s⁴

Now, we can solve for "s":

27s⁴ = 2.01 x 10^-19
s⁴ = 7.44 x 10^-21
s = ∛√(7.44 x 10^-21) ≈ 1.43 x 10^-5 mol/L

Now, convert solubility in mol/L to grams per liter:

1.43 x 10^-5 mol/L * (LaF3 molar mass) = solubility in g/L

The molar mass of LaF3 is 195.90 g/mol (La: 138.91 g/mol, F: 18.998 g/mol × 3):

1.43 x 10^-5 mol/L * 195.90 g/mol ≈ 2.8 x 10^-3 g/L

Therefore, the solubility of LaF3 in pure water is approximately 2.8 x 10^-3 g/L.

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Reason for difference in shape between water on waxed and unwaxed surfaced

Answers

Water beads up on waxed surfaces due to its much stronger cohesive forces than the adhesive forces between water and wax.

Why does water look different on wax paper?

Water and wax don't get along. Waxed paper repels and does not absorb water. It is reduced to a small, oblong blob as a result of the water's surface tension; these masses, or drops, can slide around waxed paper in light of the fact that the paper doesn't assimilate it.

What principle explains the shape of the water on the wax paper?

The cohesion of water molecules at the surface of a body of water is referred to as surface tension.  Attempt this at home: On a piece of wax paper, drop a drop of water.

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compare the chemical reactivities of nitrogen gas and argon gas based on sir ramsey's experiment using magnesium

Answers

Sir Ramsey's experiment involves the reaction of magnesium with nitrogen gas, and argon gas.

What is reaction?

Reaction is a response to an action or stimulus. It is a physical or emotional change that occurs in response to a stimulus, such as a thought, feeling, or external event. Reaction can be both conscious and unconscious, and it can range from mild to severe. Reaction includes both physical and psychological responses, such as laughing, crying, or feeling angry.

In the reaction of magnesium with nitrogen gas, the nitrogen gas is much more reactive than the argon gas. This is because nitrogen gas is able to form a strong bond with magnesium and it is readily oxidized to form nitrite ion, which then reacts with magnesium to form magnesium nitride. On the other hand, argon gas is not reactive enough to form any bond with magnesium and therefore, it does not react with the metal.

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A white ionic solid is dissolved in water. Addition of a solution of sodium chloride to this solution results in a white precipitate. What was the cation in the original ionic solid?.

Answers

The most likely cation in the original ionic solid is Ag⁺. Option C is correct.

The addition of a solution of sodium chloride (NaCl) to a solution containing a white ionic solid could result in the formation of a white precipitate if the cation in the original ionic solid forms an insoluble salt with chloride ions.

The most common cations that form insoluble chlorides include silver (Ag⁺), lead (Pb²⁺), and mercury (Hg²⁺). Other cations that can form insoluble chlorides include copper (Cu²⁺), iron (Fe²⁺ and Fe³⁺), and aluminum (Al³⁺).

When, we determine the cation in the original ionic solid then we need to perform additional tests to identify the specific cation present. One common method is to perform a flame test, where a small sample of the ionic solid is heated in a flame and the color of the flame is observed. Each metal ion produces a characteristic flame color, allowing us to identify the cation present.

Hence, C. is the correct option.

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--The given question is incomplete, the complete question is

"A white ionic solid is dissolved in water. Addition of a solution of sodium chloride to this solution results in a white precipitate. What was the cation in the original ionic solid? (A) Na⁺ (B) Fe³⁺ (C) Ag⁺ (D) Sr²⁺"--

Gravity Filtration
1) which labs its done
2) its use
3) definition
4) process

Answers

Gravity filtration is many times utilized in substance labs to channel encourages from precipitation responses as well as drying specialists, unacceptable side things, or remaining reactants.

Although vacuum filtration is more commonly used for this purpose, it can also be used to separate strong products.

Process :

Gravity filtration is the process of passing a mixture of solid and liquid through a filter paper-lined funnel, allowing the liquid to pass through while keeping the solid on the paper .

Gravity filtration uses :

Gravity filtration is the technique for decision to eliminate strong pollutions from a natural fluid. A drying agent, undesirable side product, or leftover reactant are all examples of impurities. Although vacuum filtration is typically used for this purpose due to its speed, gravity filtration can be used to collect solid products.

Definition Gravity filtration  :

Gravity filtration is a method of filtering impurities from solutions by using gravity to pull liquid through a filter. The two main kinds of filtration used in laboratories are gravity and vacuum/suction.

Incomplete question :

Explain the following about Gravity Filtration :

1) which labs its done

2) its use

3) definition

4) process

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