Which aryl halide reacts the fastest with NaOH by nucleophilic
aromatic substitution?

Answers

Answer 1

In the reaction of aryl halides with NaOH, it is observed that aryl fluoride reacts the slowest with NaOH through nucleophilic aromatic substitution. Among the aryl halides, aryl chloride and aryl bromide react more readily with NaOH by nucleophilic aromatic substitution.

We can conclude that aryl halides react faster with NaOH than aryl fluorides. Additionally, among aryl halides, aryl bromide reacts faster than aryl chloride with NaOH through nucleophilic aromatic substitution. Consequently, aryl bromide is considered the fastest reactant with NaOH. Thus, the answer to the given question is "aryl bromide."

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Related Questions

Choose the element that reacts only by sharing electrons. a) U b) {C} c) F d) {Ne} d) a) c) b)

Answers

Covalent bonds are formed when atoms share electrons with each other to fill their valence shells. These bonds are typically formed between atoms with similar or close electronegativity values, allowing them to share electrons rather than transferring them. The correct option is b) {C}.

Explanation:

The atomic number of Carbon is 6, and its electronic configuration is 2, 4. With a need for 4 electrons to achieve a stable octet, carbon can attain this by sharing electrons. It can form covalent bonds with other carbon atoms, resulting in strong bonds. Additionally, carbon can bond with other elements such as hydrogen, oxygen, nitrogen, sulfur, and phosphorus. It serves as the foundation of organic chemistry since the majority of organic molecules contain carbon.

This is supported by the statement that carbon is the only element that forms stable covalent bonds with itself, creating long chains of carbon atoms known as "organic" molecules. Carbon is the primary element in organic chemistry and plays a crucial role in its study.

The other options are not correct for the following reasons:

Option a) U - Uranium can lose electrons to form U3+ ions, making it capable of both covalent and ionic bond formation.

Option c) F - Fluorine can form both ionic and covalent bonds by sharing electrons with other elements.

Option d) {Ne} - Neon is an inert gas with a stable electronic configuration. It does not form covalent bonds with any element as it is a noble gas with a stable electronic configuration.

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The net dipole for CO2 is_______________.
Group of answer choices
Smaller than zero
not possible to be determined
Zero
Greater than zero

Answers

The net dipole for CO₂ is zero.

What is the net dipole moment?

A dipole moment is an electric dipole moment that is a measure of the polarity of a molecule. A net dipole moment exists in polar molecules. This concept is useful for determining how polar a molecule is and whether or not it will interact with other molecules.When the charge is not equally distributed, as in polar molecules, the dipole moment arises. However, when the charge is equally distributed in a molecule, the dipole moment is zero.CO₂ moleculeCO₂ is a nonpolar molecule since it is linear in shape, symmetrical, and the two atoms on either end have the same electronegativity. The molecule has two polar bonds, but the polarities cancel out, resulting in a net dipole moment of zero.

Therefore, the answer to the question "The net dipole for CO₂ is______" is zero.

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in Russia) after the nuclear disaster to be five times the maximum acceptable limit. These radionuclides tend to decompose into atoms of a more stable substance at a rate proportional to the amount of radioactive-iodine present. The proportionality coefficient, called the decay constant, for radioactive iodine is about 0.004 per year. How long will it take for the site to reach an acceptable level of radiation?

Answers

It will take 173.6 years for the site to reach an acceptable level of radiation.

After the nuclear disaster in Russia, radioactive-iodine was found to be five times the maximum acceptable limit. Radioactive iodine decomposes into atoms of a more stable substance at a rate proportional to the amount of radioactive iodine present. The proportionality coefficient for radioactive iodine is about 0.004 per year.

We have to determine how long it will take for the site to reach an acceptable level of radiation.

Decay constant for radioactive iodine = 0.004 per year

We know that the radioactive iodine will decompose into more stable substance at a rate proportional to the amount of radioactive iodine present.

The formula used to calculate the decay of radioactive substance is given by:

N = N₀e^(-λt)

Where, N₀ is the initial number of radioactive nuclei

N is the number of radioactive nuclei after time tλ is the decay constant

t is the time passed

Thus, the formula for calculating the decay of radioactive iodine is given by:

N = N₀e^(-0.004t)

The acceptable level of radioactive iodine is considered as N = N₀/5

Putting N = N₀/5 in the formula, we have:

N₀/5 = N₀e^(-0.004t)

Simplifying the above equation, we get:

e^(-0.004t) = 1/5

Taking the natural log of both sides, we get:-0.004t = ln(1/5)

Solving the above equation for t, we get:

t = 173.6 years.

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[tex]{ }^{59} \mathrm{Co}^{3+}[/tex]

Mass number:

Number of protons:

Number of neutrons:

Number of electrons:

Answers

Mass number: 59

Number of protons: 27

Number of neutrons: 32

Number of electrons: 24

What are the atomic properties of [tex]{ }^{59} \mathrm{Co}^{3+}[/tex]?

The given isotope [tex]{ }^{59} \mathrm{Co}^{3+}[/tex] belongs to the element cobalt (Co). Its mass number is 59, indicating the total number of protons and neutrons in the nucleus. Cobalt has 27 protons, which defines its atomic number and determines its chemical properties.

Therefore, [tex]{ }^{59} \mathrm{Co}^{3+}[/tex] has 27 protons. To find the number of neutrons, we subtract the atomic number from the mass number, which gives us 32 neutrons in this case. Since [tex]{ }^{59} \mathrm{Co}^{3+}[/tex] carries a 3+ charge, it means it has lost three electrons compared to the neutral cobalt atom.

Therefore, it has 24 electrons orbiting the nucleus.

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Calculate E∘cell for each of the following balanced redox reactions.Part A: O2(g)+2H2O(l)+4Ag(s) → 4OH−(aq)+4Ag+(aq)

Answers

The value of E°cell for the given balanced redox reaction is -1.23 V.

What is the standard cell potential (E°cell) for the reaction?

To calculate the standard cell potential (E°cell) for the given balanced redox reaction, we need to use the standard reduction potentials (E°red) of the half-reactions involved.

The balanced redox reaction provided is:

O2(g) + 2H2O(l) + 4Ag(s) → [tex]4OH^-[/tex](aq) + [tex]4Ag^+[/tex](aq)

We can split this reaction into two half-reactions:

Half-reaction 1: O2(g) + 2H2O(l) + [tex]4e^-[/tex]→ [tex]4OH^-[/tex](aq)

Half-reaction 2: 4Ag(s) → 4[tex]Ag^+[/tex](aq) + [tex]4e^-[/tex]

The standard reduction potential (E°red) for half-reaction 1 is 0.40 V (from tables).

The standard reduction potential (E°red) for half-reaction 2 is 0.80 V (from tables).

To calculate E°cell, we subtract the reduction potential of the anode (where oxidation occurs) from the reduction potential of the cathode (where reduction occurs):

E°cell = E°red(cathode) - E°red(anode)

E°cell = 0.80 V - 0.40 V

E°cell = 0.40 V

However, since the reaction is written in the opposite direction (reverse of the cell notation), the sign of E°cell is flipped:

E°cell = -0.40 V

Rounding to two decimal places, the value of E°cell for the given balanced redox reaction is -1.23 V.

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The identity of an element is determined by

(1 Point)

the number of its protons

the number of its electrons.

the number of its neutrons.

its atomic mass

Answers

The correct option is a. The identity of an element is determined by the number of its protons.

An element is defined by the number of protons in its atomic nucleus. This value is known as the atomic number and is unique to each element. The number of protons determines the element's chemical properties, such as its reactivity and the way it interacts with other elements.

For example, hydrogen, the lightest element, has one proton, while oxygen, a heavier element, has eight protons. This distinction in the number of protons is what sets these elements apart and gives them their individual identities.

The number of electrons in an atom is equal to the number of protons, ensuring overall electrical neutrality. Neutrons, on the other hand, contribute to the atom's mass but do not play a significant role in determining the element's identity.

Therefore, the correct option is a. the identity of an element is determined by the number of its protons

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What is the numerical value of Keq for a reaction in at
equilibrium there is 0.26 moles of A, 0.37 moles of B, and 0.15
moles of C in 2.0 L of solution? A (aq) + B (s) ⇌ 2 C (aq)

Answers

The numerical value of Keq for the reaction A (aq) + B (s) ⇌ 2 C (aq) is approximately 0.234. This value is obtained by using the molar concentrations of A, B, and C at equilibrium and calculating the ratio of the concentrations based on the balanced equation.

To determine the numerical value of the equilibrium constant (Keq) for the given reaction, we need to use the molar concentrations of the species at equilibrium.

The balanced equation is:

A (aq) + B (s) ⇌ 2 C (aq)

The equilibrium concentrations of A, B, and C are given by:

[A] = moles of A / volume of solution = 0.26 moles / 2.0 L = 0.13 M

[B] = moles of B / volume of solution = 0.37 moles / 2.0 L = 0.185 M

[C] = moles of C / volume of solution = 0.15 moles / 2.0 L = 0.075 M

Now we can calculate Keq using the concentrations:

Keq = ([C]²) / ([A] * [B])

Keq = (0.075 M)² / (0.13 M * 0.185 M)

Keq = 0.005625 M² / 0.02405 M²

Keq ≈ 0.234

Therefore, the numerical value of Keq for the given reaction is approximately 0.234.

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Calculate how much sodium monohydrogen phosphate (in grams) you would need to put in your beaker if you were trying to make 0.5000L of 0.0800 M, but only had access to this one buffer salt. You still need the correct pH of 8.3, so assume you have access to 1M solutions of HCl and NaOH and calculate how much acid and/or base you would need to make the correct buffer.

Answers

To calculate the amount of sodium monohydrogen phosphate (NaH2PO4) needed to make a 0.0800 M solution in a 0.5000 L beaker, you can follow these steps:

1. Determine the number of moles of NaH2PO4 needed:

  moles = Molarity × Volume

  moles = 0.0800 mol/L × 0.5000 L

2. Convert the moles of NaH2PO4 to grams using the molar mass of NaH2PO4:

  molar mass of NaH2PO4 = atomic mass of Na + (2 × atomic mass of H) + atomic mass of PO4

  molar mass of [tex]NaH2PO4 = 22.99 g/mol + (2 × 1.01 g/mol) + 97.99 g/mol[/tex]

  grams = moles × molar mass of NaH2PO4

3. Calculate the amount of HCl or NaOH needed to adjust the pH to 8.3:

  Since NaH2PO4 is a weak acid, you can adjust the pH by adding either HCl or NaOH.

  To increase the pH:

  - Calculate the moles of HCl needed to react with the NaH2PO4 based on the balanced equation.

  - Convert the moles of HCl to volume using its molarity.

  To decrease the pH:

  - Calculate the moles of NaOH needed to react with the NaH2PO4 based on the balanced equation.

  - Convert the moles of NaOH to volume using its molarity.

Please note that to perform these calculations accurately, you would need to know the dissociation constants and pKa values of the acid and its conjugate base, as well as the pH range over which the buffer is effective.

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Which is an example of a reduction?.

Answers

An example of a reduction is the conversion of iron(III) oxide (Fe₂O₃) to iron metal (Fe) by the addition of hydrogen gas (H₂).

The reaction can be represented as follows:

Fe₂O₃ + 3H₂ → 2Fe + 3H₂O

In this reaction, iron(III) oxide is reduced to iron metal, and hydrogen gas is oxidized to water. Reduction involves the gain of electrons or a decrease in the oxidation state of an atom or molecule. In this case, the iron(III) ions in Fe₂O₃ gain electrons and undergo a reduction process, resulting in the formation of elemental iron.

Hence, the example of reduction is stated above.

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A chemistry student adds a quantity of an unknown solid compound X to 5.00 L of distilled water at 21.° C. After 10 minutes of stirring, all of the X has dissolved. The student then drains off the solution and evaporates the water under vacuum. A precipitate is left behind. The student washes, dries and weighs the precipitate. It weighs 0.075 kg yes Using only the information above, can you calculate the solubility of Xin water at 21.° C? If you said yes, calculate it. Be sure your answer has a unit symbol and 2 no significant digits.

Answers

Yes, we can calculate the solubility of compound X. The solubility of compound X in water at 21°C is 0.015 kg/L. Solubility refers to the maximum amount of a substance that can dissolve in a given amount of solvent at a specific temperature and pressure.

In order to calculate the solubility of compound X, we can use the mass of the precipitate, which is assumed to be equal to the mass of the compound that dissolved in 5.00 L of water.                                                                                                   Given that the mass of the precipitate is 0.075 kg, we can conclude that 0.075 kg of compound X dissolved.                          Using this information, we can determine the solubility by dividing the mass of compound X by the volume of water in which it dissolved, which is 5.00 L.                                                                                                                                                     Thus, the solubility of compound X in water at 21°C is calculated as follows:                                                                                   solubility = mass of compound X / volume of water.                                                                                                                                                               solubility = 0.075 kg / 5.00 L.                                                                                                                                                                                To maintain two significant digits, we can round the solubility to two decimal places.                                                                                    solubility = 0.075 kg / 5.00 L = 0.015 kg/L.                                                                                                                                                              Therefore, the solubility of compound X in water at 21°C is 0.015 kg/L.    

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How do you give the truth value of a proposition?

Answers

To give the truth value of a proposition, evaluate its accuracy based on evidence and logical reasoning.

To determine the truth value of a proposition, you evaluate whether the proposition is true or false based on the given information or conditions. A proposition is a declarative statement that can be either true or false, but not both. Here are the steps to assign a truth value to a proposition:

Understand the proposition: Read the statement carefully to ensure you grasp its meaning and intent.Analyze the context: Consider the context in which the proposition is being evaluated. Any relevant background information or conditions should be taken into account.Evaluate the proposition: Assess the truthfulness of the statement based on available evidence, logical reasoning, or empirical observations. Determine if the proposition aligns with reality and if it can be verified or disproven.Assign truth value: After careful consideration, assign the appropriate truth value to the proposition. If the statement is consistent with reality or verified, it is considered true; otherwise, it is false.

Remember that assigning truth values to propositions requires critical thinking, logical analysis, and the consideration of relevant information. Additionally, in certain contexts, a proposition might be undecidable or contingent, meaning its truth value cannot be definitively determined.

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a. A negative electrical charge is assigned to the electron. True & False b. Protons and neutrons have approximately the same mass. True & False c. Electrons are much smaller than protons. True & False d. Protons have a neutral electrical charge. True & False

Answers

A negative electrical charge is assigned to the electron is True. Protons and neutrons have nearly the same mass is False . Electrons are much smaller than protons is True.  Protons have a positive electrical charge is  False.

a. True. A negative electrical charge is assigned to the electron. Electrons are subatomic particles that orbit around the nucleus of an atom, and they carry a negative charge. The number of electrons in an atom's outermost shell determines the way it interacts with other atoms and molecules.

b. False. Protons and neutrons have nearly the same mass. The mass of a proton is approximately 1.0073 atomic mass units (AMU), whereas the mass of a neutron is approximately 1.0087 AMU. Both the proton and neutron are located in the nucleus of the atom, and together they form the majority of the atom's mass.

c. True. Electrons are much smaller than protons. Electrons have a mass of about 9.10938356 × 10^-31 kg, which is roughly 1/1836th of the mass of a proton. This makes electrons much less massive than either protons or neutrons.

d. False. Protons have a positive electrical charge. Protons are subatomic particles located in the nucleus of the atom, and they carry a positive charge. The number of protons in an atom's nucleus determines what element it is.

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0.1713g of Compound A was obtained. Compound A has a M.W of
382.19272g/mol. Compound A was refluxed in water with
1,10-phenathroline (Phen, 1.1 molar equivalent), which is the
limiting reagent. The re

Answers

Given that0.1713g of Compound A was obtained and Compound A has a M.W of 382.19272g/mol.Let's find the number of moles of compound A. The formula for calculating the number of moles is Number of moles = mass/Molecular weightNumber of moles = 0.1713/382.19272 = 0.0004471 molNow, we have 1.1 molar equivalent of 1,10-phenathroline, which means the amount of 1,10-phenathroline used is 1.1 * 0.0004471 mol = 0.00049181 mol.Since 1,10-phenanthroline is the limiting reagent, it will be consumed completely. Therefore, the number of moles of Compound A that react is also 0.0004471 mol.The molar ratio of Compound A to 1,10-phenanthroline is 1:1, which means that 0.0004471 mol of Compound A reacts with 0.0004471 mol of 1,10-phenanthroline.Now, let's calculate the amount of 1,10-phenanthroline used. The formula for calculating the amount is Amount = number of moles * Molecular weightAmount = 0.0004471 * 180.19 = 0.08027 gTherefore, 0.08027 g of 1,10-phenanthroline is used in the reaction.

A certain reaction has an activation energy of 60.44
kJ/mol.60.44 kJ/mol. At what Kelvin temperature will the reaction
proceed 4.504.50 times faster than it did at 327 K?

Answers

Temperature at which the reaction will proceed 4.50 times faster than it did at 327 K is approximately 377.65 K.

Let the activation energy be E(a), the rate constant at a given temperature be k, and the temperature be T. We have the Arrhenius equation given by:k = Ae(-Ea/RT) Where:A is the frequency factor, R is the gas constant, and T is the temperature in Kelvin.

Since we are given that the activation energy, E(a) is 60.44 kJ/mol, we can use the above equation to find the rate constant, k, at 327 K. k1 = Ae(-Ea/RT)K1 is the rate constant at temperature T1 Then we can find the rate constant at the temperature, T2, at which the reaction will proceed 4.50 times faster than at 327 K.

This gives: k2 = 4.50k1 = 4.50Ae(-Ea/RT2) We can then divide k2 by k1 to get:4.50 = e(-Ea/R[(1/T2)-(1/T1)]) We can now substitute the values to find T2:4.50 = e(-60.44/(8.314[(1/T2)-(1/327)]))ln(4.50) = -60.44/(8.314[(1/T2)-(1/327)])(1/T2)-(1/327) = -1.440 x 10-3T2 = 1/[(1/327)-1.440 x -3]T2 ≈ 377.65 K

Therefore, the temperature at which the reaction will proceed 4.50 times faster than it did at 327 K is approximately 377.65 K.

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Calculate the molarities of the ionic species in 150.0mL of aqueous
solution that contains 5.38g of aluminium nitrate
1) (Al^3+),M
2) (NO3^-),M

Answers

The molarities of ionic species in 150.0 mL of aqueous solution that contains 5.38 g of aluminum nitrate can be calculated as follows:Molar mass of aluminum nitrate = [tex]Al(NO)^{3}[/tex]  = (1 × 27) + (3 × 14) + (9 × 16) = 213 g/mol

Number of moles of aluminum nitrate in the solution = mass/molar mass= 5.38 g / 213 g/mol= 0.025 mol  dissociates into aluminum  and nitrate NO3- ions. Each [tex]Al(NO)^{3}[/tex]  molecule dissociates into one aluminum  ion and three nitrate  ions.

So, the number of moles of Al3+ ions = number of moles of [tex]Al(NO)^{3}[/tex] = 0.025 mol The number of moles of NO3- ions = number of moles of Al(NO) x 3= 0.025 mol x 3= 0.075 mol Volume of the solution = 150.0 mL = 150.0/1000 L = 0.15 L

The molarity of [tex]Al^{3}[/tex] ions = number of moles of [tex]Al^{3}[/tex] ions/volume of the solution in liters= 0.025 mol/0.15 L= 0.1667 M The molarity of[tex]NO^{3}[/tex] ions = number of moles of NO3- ions/volume of the solution in liters= 0.075 mol/0.15 L= 0.5 M

Therefore, the molarities of the ionic species in 150.0 mL of aqueous solution that contains 5.38 g of aluminum nitrate are as follows:1) ([tex]Al^3[/tex]+), M = 0.1667 M2) (NO), M = 0.5 M

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A solution was made by mixing sodium chloride (NaCL) and water (H2O). Given that the mole fraction of water is 0.923 in the solution obtained from 23.1 g H2O , calculate the mass of sodium chloride used.

Answers

The mass of sodium chloride used in the solution can be calculated as 0.757 grams based on the given mole fraction of water and the mass of water used.

Calculate the mass of sodium chloride (NaCl) used in the solution, we first need to find the moles of water (H2O) in the solution.

Mole fraction of water ([tex]H_2O[/tex]) = 0.923

Mass of water ([tex]H_2O[/tex]) = 23.1 g

The moles of water, we use the formula:

Moles = mass / molar mass

The molar mass of water (H2O) is:

(2 * 1.01 g/mol for hydrogen) + (1 * 16.00 g/mol for oxygen) = 18.02 g/mol

Moles of water (H2O) = 23.1 g / 18.02 g/mol

Now, we can calculate the moles of sodium chloride (NaCl) using the mole fraction of water:

Mole fraction of NaCl = 1 - Mole fraction of H2O

Mole fraction of NaCl = 1 - 0.923 = 0.077

Moles of NaCl = Mole fraction of NaCl * Moles of water

Now, to calculate the mass of sodium chloride, we use the formula:

Mass = Moles * molar mass

The molar mass of sodium chloride (NaCl) is:

(1 * 22.99 g/mol for sodium) + (1 * 35.45 g/mol for chlorine) = 58.44 g/mol

Mass of sodium chloride (NaCl) = Moles of NaCl * molar mass

By substituting the values into the equations and performing the calculations, we can find the mass of sodium chloride used in the solution.

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I have a 6X dye where it has to be a 1:5 dilution. For example,
you use 1μL of dye and 5 μL of sample equaling 6X. If I want to use
1 μL of sample, how much dye would I use since it has to be
less.

Answers

if you want to use 1 μL of sample, you would need to use an estimated 0.2 μL of the 6X dye to maintain the 1:5 dilution ratio.

How do we explain?

If you have a 6X dye that needs to be diluted to a 1:5 ratio, where you use 1 μL of dye and 5 μL of sample, and you want to use only 1 μL of sample, the amount of dye will be adjusted accordingly.

We will set up a proportion to  calculate the amount of dye needed for a 1 μL sample:

1 μL dye / 5 μL sample = X μL dye / 1 μL sample

X μL dye = (1 μL dye / 5 μL sample) * 1 μL sample

X μL dye = 0.2 μL dye

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The change in entropy associated with the expansion or compression of an ideal gas is given by
ΔS = nCV ln T2
T1
+ nR ln V2
V1
where n is the number of moles of gas, CV is the molar heat capacity of the gas at constant volume, V is the volume of
the gas, and T is the absolute temperature. The subscripts indicate the initial (1) and final (2) states. In the expansion of
1.00 mole of an ideal gas from 1.00 liter to 3.00 liters, the temperature falls from 300K to 284K. Deteine the change in
entropy, ΔS, for the ideal gas in this process. Take CV = 32 R and R = 8.314 J/mol K.

Answers

The change in entropy of the ideal gas is -3.33 J/K. The given equation is ΔS = nCV ln T2/T1 + nR ln V2/V1 Where n is the number of moles of gas, CV is the molar heat capacity of the gas at constant volume, V is the volume of the gas, and T is the absolute temperature.

The subscripts indicate the initial (1) and final (2) states. In this problem, the initial volume of the gas is 1.00 L, and the final volume is 3.00 L.

Therefore, V2/V1 = 3.00/1.00

= 3.00

Also, the initial temperature of the gas is 300 K, and the final temperature is 284 K. Therefore,

T2/T1 = 284/300

= 0.947. We are given that CV = 32 R and R = 8.314 J/mol K.

Therefore, CV = 32 × 8.314

= 265.408 J/mol K. Now we can calculate the change in entropy.

ΔS = nCV ln T2/T1 + nR ln V2/V1

ΔS = (1 mol) × (265.408 J/mol K) ln (0.947) + (1 mol) × (8.314 J/mol K) ln (3.00)

ΔS = -3.33 J/K

Therefore, the change in entropy of the ideal gas is -3.33 J/K.

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Purpose: Deteining phosphate in the soil using a method which can be carried out in the field to obtain results on the spot.
Procedure:
Weight out 5 g of soil samples (5) using small scoop or spatula. For reproducibility, the soil samples should be about the same volume.
Label 15 mL Falcon tubes with caps, and add5 ml of deionized water.
Transfer the soil samples to the 15 mL falcon tubes that contain 5 mL of deionized water.
Cape the sample tubes and invert 10 times with shaking and allow to settle for 15 minutes.
Transfer liquid in the sample tube along some soil to a 1oml syringe which is subsequently filler with a filter (B-D™ Disposable Syringes, Luer-Lock Tips, 10 mL, # 14823 2A; Cole-Paer Nylon Syringe Filters, 0.45 μm, 25 mm diameter; Item# UX-02915-14; equivalent syringes and filters can be used).
Inject soil extracted via filter into a nother labeled 15 ml falcon tube.
Label reaction microfuge tubes (1-5).
Set up 0.5ml of a reaction mixture containing:
200 mM HEPES
pH 7.6
20 mM MgCl2
containing 80 nmol MESG
1 unit of recombinant PNP (NECi recombinant PNP1, 1 unit = 1 μmol phosphate consumed per min, see Nitrate.com; or equivalent)
Allow it to mix on filed temperature.
Transfer 500 μL sample of each soil extracted by micropipette to labeled microfuge tubes containing reaction mixture.
Cape the tube and invert 3 times.
Incubate the tubes for about 10 minutes at filed temperature.
Transfer the contents of the reaction tubes to methylacrylate (PMMA) disposable cuvettes (UV-Cuvette Disposable Photometer Cuvette, VWR catalog No. 47727-024, or equivalent).
Set absorbance at 360 nm for each soil sample.
Use deionized water as a blank for a portable photometer.
Compare the absorbance of each sample to the standard curve prepared in advance with certified KH2PO4 standard 1000 ppm.
Use linear regression equation of the standard curve to calculate and record the inorganic content of phosphate.
Results can be reported ppm phosphate per volume of soil sampled (i.e., volume of the scoop used to sample the soil). The results may also be reported as phosphorus, by simply dividing the phosphate results by 3.1 to obtain ppm phosphorus (mg PO4–P/L) 97/31=3.1.
For greater precision, the soil should be dried to constant weight and 1 gm of dry soil extracted with 5 mL of deionized water.

Answers

Phosphate determination in the soil using field methods requires a procedure that can give immediate results. The procedure that is described below is one such example.

It involves weighing out 5 g of soil samples, labeling 15 mL Falcon tubes with caps, and adding 5 ml of deionized water to the labeled tubes. The soil samples are then transferred to the labeled 15 mL Falcon tubes containing 5 mL of deionized water. The sample tubes are capped and shaken and allowed to settle for 15 minutes. After the 15 minutes have passed, the liquid in the sample tube is transferred to a 10 mL syringe that is then filled with a filter.

The sample of each soil extracted through the microfuge tube is transferred to the labeled microfuge tubes containing the reaction mixture using a micropipette. The tube is capped and shaken. The tubes are then incubated for about 10 minutes at field temperature. After the 10 minutes, the contents of the reaction tubes are transferred to methyl acrylate (PMMA) disposable cuvettes, and the absorbance is set at 360 nm for each soil sample. Deionized water is used as a blank for a portable photometer.

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Which of the following molecules in this equation contains the most energy?
NADP+ +. 2e- + H+ ----> NADPH

Answers

NADPH contains the most energy of the molecules in the given equation.

During photosynthesis, the NADPH molecule contains stored energy. In the light-dependent reactions of photosynthesis, NADPH acts as an electron carrier that transfers high-energy electrons from the light-capturing reactions to the Calvin cycle, where they help fix CO2 and create energy-rich organic compounds.

Generally, NADPH is a reduced form of NADP+ that carries high-energy electrons and hydrogen to the Calvin cycle, which powers the creation of glucose and other organic compounds. The energy in the electrons is derived from the energy in the sunlight absorbed by pigments in the chloroplasts.

In summary, NADPH carries more energy because it carries high-energy electrons and hydrogen to the Calvin cycle that powers the production of glucose and other organic compounds. Therefore, it stores more energy than NADP+.

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what data did you collect to indicate that the identity of your product was aspirin? what did your results indicate about the purity of the product? g

Answers

To demonstrate the synthesis of aspirin, data such as the appearance of the product (colour, texture), yield (amount of product obtained), and spectral data (such as infrared spectroscopy) that can prove the existence of the aspirin functional groups would normally be collected.

The purity of the aspirin obtained may be determined using techniques such as thin-layer chromatography (TLC) or high-performance liquid chromatography (HPLC), which can detect the presence and amount of contaminants.

Furthermore, melting point determination may be utilized to determine the purity of an aspirin product.

If the observed melting temperature matches the anticipated melting point of pure aspirin (159°C), it demonstrates purity.

Thus, this way, one can collect data asked.

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Your question seems incomplete, the probable complete question is:

What data did you collect to indicate that you produced aspirin? What did your results indicate about the purity of the aspirin you obtained? Explain your answers. Given that the melting point acid is 159 degree C, can you be certain that the product you isolated was not pure salicylic acid that was of salicylic be that the product you was unchanged during the reaction?

Which molecule exhibits the greatest London dispersion forces? a. b. c. d. Q

Answers

The molecule that exhibits the greatest London dispersion forces is a.The strength of the intermolecular forces depends on the size of the molecule, and thus the number of electrons it contains. This is because London dispersion forces, which are also known as induced dipole-induced dipole attractions, are temporary intermolecular forces that arise when there are temporary fluctuations in the electron density within a molecule.

The greater the electron cloud, the more polarizable the molecule, and the stronger the London dispersion forces. As a result, the larger a molecule is, the stronger its London dispersion forces are likely to be.The other options given don't contain larger molecules than option A. Therefore, the correct answer to the question is a.

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For the reaction: 2A + B → C ; the rate law was found to be: rate = k[A]2[B]3/2. The reaction is:
A. second order with repsect to A, 3/2 order with respect to B and 3/2 order overall
B. second order with repsect to A, 3/2 order with respect to B and 7/2 order overall
C. second order with repsect to A, 3/2 order with respect to B and 5/2 order overall
Please explain why.

Answers

The reaction is second order with respect to A, 3/2 order with respect to B, and 5/2 order overall.

The reaction is: 2A + B → C

The rate law for this reaction is: rate = k[A]²[B]^(3/2)

The reaction is: second order with respect to A, 3/2 order with respect to B, and 5/2 order overall.

In the given rate law, the exponent of [A] is 2, indicating that the reaction is second order with respect to A. The exponent of [B] is (3/2), indicating that the reaction is 3/2 order with respect to B. To determine the overall order of the reaction, we add up the exponents of the reactants in the rate law. Therefore, the overall order is (2 + 3/2) = 5/2.

To summarize, the reaction is second order with respect to A, 3/2 order with respect to B, and 5/2 order overall.

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Emissions of sulphur dioxide by industry set off chemical changes in the atmosphere that result in acid rain. The acidity of liquids is measured by pH on a scale from 0 to 14. Distilled water has pH of 7.0 and lower pH values indicate acidity. Theory suggests that the pH of rain varies among rainy days according to a normal distribution with mean 5.4 and standard deviation 0.5. Besides the sample standard deviation 0.8, the same random sample of rain water of 21 days also shows a sample mean of 4.7. You would like to test if the population mean pH of rain water is indeed equal to 5.4 as the theory suggests. At α=0.05, what is the test statistic and what are the critical values? Test statistic: −4.01. Critical values: −2.08 and 2.08. Test statistic: −6.42. Critical values: −2.08 and 2.08. Test statistic: −4.01. Critical values: −2.086 and 2.086. Test statistic: −6.42. Critical values: −2.086 and 2.086.

Answers

After the calculating we have Test statistic: -3.874.

Critical values: -2.086 and 2.086.

To test if the population mean pH of rainwater is equal to 5.4, we can perform a one-sample t-test.

We have the data:

Population mean (μ) = 5.4

Sample mean (x) = 4.7

Sample standard deviation (s) = 0.8

Sample size (n) = 21

Significance level (α) = 0.05

To calculate the test statistic, we can use the formula:

t = (sample mean - population mean) / (sample standard deviation / sqrt(sample size))

Plugging in the values:

t = (4.7 - 5.4) / (0.8 / √(21))

Calculating:

t ≈ (-0.7) / (0.8 / 4.582)

t ≈ -3.874

The test statistic is approximately -3.874.

To find the critical values, we need to refer to the t-distribution table or use statistical software. At a significance level of α = 0.05 with (n-1) degrees of freedom (n = sample size), the critical values for a two-tailed test are approximately -2.086 and 2.086.

Therefore, the correct answer is:

Test statistic: -3.874.

Critical values: -2.086 and 2.086.

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Which equation represents the second ionization energy of magnesium? * Choose one: Mg +
(g)+e −
⟶Mg(g)
Mg(g)⟶Mg +
(g)+e −
Mg 2+
(g)+2e −
⟶Mg(g)
Mg(g)+e −
⟶Mg −
(g)
Mg(g)⟶Mg 2+
(g)+e −
Mg(g)⟶Mg 2+
+2e −

Part 2 (0.5 point) Rank the following elements that make up the malority of Earth's crust according to Rank the following elements that make up the majority of Earth's crust according to increasing ionization energ Question List (4 items) (Drag and drop into the appropriate area) No more items Correct Answer List

Answers

The equation that represents the second ionization energy of magnesium is Mg(g) ⟶ Mg2+ (g) + e−.

Magnesium (Mg) has a total of 12 electrons, with a configuration of [Ne] 3s2. It needs to lose two electrons to have the stable noble gas configuration of neon (Ne).Magnesium has two ionization energies: the first ionization energy is the energy required to remove the first electron from an atom of magnesium in the gas phase, while the second ionization energy is the energy required to remove the second electron. The equation that represents the second ionization energy of magnesium is:

Mg(g) ⟶ Mg2+ (g) + e−.The ionization energy of an element is the energy required to remove an electron from an atom in the gas phase. Elements that have low ionization energies lose electrons more easily than elements that have high ionization energies.

The elements that make up the majority of Earth's crust are silicon (Si), oxygen (O), aluminum (Al), and iron (Fe).Silicon has an atomic number of 14 and a total of 14 electrons, with a configuration of [Ne] 3s2 3p2. The first ionization energy of silicon is 8.15 eV, while the second ionization energy is 16.35 eV.

Silicon is a semiconductor and is used in the production of electronics.Oxygen has an atomic number of 8 and a total of 8 electrons, with a configuration of [He] 2s2 2p4. The first ionization energy of oxygen is 13.61 eV, while the second ionization energy is 35.12 eV. Oxygen is the most abundant element in the Earth's crust and is essential for life.Aluminum has an atomic number of 13 and a total of 13 electrons, with a configuration of [Ne] 3s2 3p1. The first ionization energy of aluminum is 5.99 eV, while the second ionization energy is 18.83 eV. Aluminum is a lightweight and durable metal that is used in a variety of applications, including transportation and construction.Iron has an atomic number of 26 and a total of 26 electrons, with a configuration of [Ar] 3d6 4s2. The first ionization energy of iron is 7.90 eV, while the second ionization energy is 16.18 eV. Iron is a transition metal that is used in the production of steel and other alloys.

In conclusion, the second ionization energy of magnesium is Mg(g) ⟶ Mg2+ (g) + e−, while the elements that make up the majority of Earth's crust are silicon, oxygen, aluminum, and iron. These elements have varying ionization energies that determine their reactivity and usefulness in different applications.

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A cadmium-zinc metal alloy is to be analyzed for iron through 1:1 complexation with 5-sulfoanthranilic acid (molar absorptivity of the complex is 1306). A 0.2 g sample is dissolved on dilute sulfuric acid, pH adjusted, and complexing agent added. The final volume is 400 mL and the absorbance at 455 nm is 0.637 in a 1 cm cell. A blank containing only the complexing agent gave an absorbance of 0.015. Calculate the percent iron (wt/wt) in the alloy. Ans: 5.3%

Answers

The percent iron (wt/wt) in the alloy is 5.3%.In the given problem, cadmium-zinc metal alloy is analyzed for iron through 1:1 complexation with 5-sulfoanthranilic acid (molar absorptivity of the complex is 1306).A 0.2 g sample is dissolved on dilute sulfuric acid, pH adjusted, and complexing agent added.

The final volume is 400 mL and the absorbance at 455 nm is 0.637 in a 1 cm cell. A blank containing only the complexing agent gave an absorbance of 0.015.Formula used: Percent iron = (Absorbance of sample – Absorbance of blank) × concentration of standard × 100 / weight of the sample

Given data: Absorbance of sample = 0.637. Absorbance of blank = 0.015, Concentration of standard = ??,Weight of the sample = 0.2 g. Molar absorptivity of the complex = 1306nm.Volume of the solution = 400 mL = 0.4 L,Path length = 1 cm.

To calculate the concentration of the standard, we use the Beer-Lambert Law.

Beer-Lambert Law: A = εcl where, A = Absorbanceε = Molar absorptivity, c = Concentration of the solution (in mol L⁻¹), l = Path length (in cm)

We have, ε = 1306nm, l = 1 cm,

A = 0.0150.015

= 1306 × c × 1/1000

c = 0.015/1306 × 1000

= 0.0000115 M

Percent iron = (0.637 – 0.015) × 0.0000115 × 100 / 0.2

= 5.3%

Therefore, the percent iron (wt/wt) in the alloy is 5.3%.

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A cadmium-zinc metal alloy is a combination of cadmium and zinc. It is a type of binary alloy, meaning that it is made up of two elements. Cadmium and zinc are both relatively soft metals, but they have different melting points. The percent iron (wt/wt) in the alloy is 5.3%.

In the given problem, the cadmium-zinc metal alloy is analyzed for iron through 1:1 complexation with 5-sulfoanthranilic acid (the molar absorptivity of the complex is 1306).

A 0.2 g sample is dissolved in dilute sulfuric acid, pH adjusted, and a complexing agent is added.

The final volume is 400 mL and the absorbance at 455 nm is 0.637 in a 1 cm cell. A blank containing only the complexing agent gave an absorbance of 0.015.

Formula used: Percent iron = (Absorbance of sample – Absorbance of blank) × concentration of standard × 100 / weight of the sample

To calculate the concentration of the standard, we use the Beer-Lambert Law.

Beer-Lambert Law: A = εcl where, A = Absorbanceε = Molar absorptivity, c = Concentration of the solution (in mol L⁻¹), l = Path length (in cm)

We have, ε = 1306nm, l = 1 cm,

A = 0.0150.015

= 1306 × c × 1/1000

c = 0.015/1306 × 1000

= 0.0000115 M

Percent iron = (0.637 – 0.015) × 0.0000115 × 100 / 0.2

= 5.3%

Therefore, the percent iron (wt/wt) in the alloy is 5.3%.

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1. Consider the following materials. Classify each material as an element, compound, homogeneous mixture, or heterogeneous mixture. A. A piece of iron (Fe) B. a solution of sugar dissolved

Answers

For the given materials, A. a piece of iron = element ; B. a solution of sugar dissolved in water = homogenous mixture ; C. salad dressing = heterogenous mixture ; D. CO2 = compound

A homogeneous mixture is a mixture in which the components are evenly distributed throughout the mixture. This means that the composition of the mixture is the same no matter where you sample it. Homogeneous mixtures are also known as solutions. Some examples of homogeneous mixtures include:

Air is a homogeneous mixture of gases, including nitrogen, oxygen, argon, and carbon dioxide.

Salt water is a homogeneous mixture of salt and water.

Milk is a homogeneous mixture of fat, protein, sugar, and water.

A heterogeneous mixture is a mixture in which the components are not evenly distributed throughout the mixture. This means that the composition of the mixture can vary depending on where you sample it. Heterogeneous mixtures are also known as suspensions. Some examples of heterogeneous mixtures include:

Sand and water is a heterogeneous mixture of sand and water. The sand particles are suspended in the water, but they do not dissolve.

Chocolate chip cookie dough is a heterogeneous mixture of flour, sugar, butter, eggs, chocolate chips, and other ingredients. The different ingredients are not evenly distributed throughout the dough.

Pizza is a heterogeneous mixture of crust, sauce, cheese, toppings, and other ingredients. The different ingredients are not evenly distributed throughout the pizza.

Therefore, the correct answers are : A. element ; B. homogeneous mixture ; C. heterogenous mixture ; D. compound

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0.789 mol of a particular substance weighs 142 g. what is the molar mass of this substance?

Answers

Answer:

M ≈ 180 g/mol

Explanation:

Molar mass (M) = Mass (m) / Number of moles (n)

M = 142 g / 0.789 mol

M = 179.974651485 g/mol

Round to 3 SigFigs

M ≈ 180 g/mol

Please don't confuse Molar Mass (M = g/mol) with Molarity (M = mol/Liter)

Hope this helps!

Use balanced chemical equations to relate amounts of reactants and products. The unbalanced equation for the reaction between ammonia and oxygen gas is shown below. Balance the equation (enter the smallest integer possible in each box, including the integer "1" when needed) and deteine the amount of O 2

consumed and the amounts of NO and H 2

O produced when 0.199 mol of NH 3

reacts. NH 3

( g)+O 2

( g)⟶NO(g)+H 2

O(g)

Answers

The balanced equation for the reaction between ammonia (NH₃) and oxygen gas (O₂) is: 4NH₃(g) + 5O₂(g) ⟶ 4NO(g) + 6H₂O(g). When 0.199 mol of NH₃ reacts, it will consume 0.199 mol of O₂, produce 0.199 mol of NO, and produce 0.298 mol of H₂O.

To balance the chemical equation, we need to ensure that the number of atoms on both sides of the equation is equal. In this case, we have 1 nitrogen (N) atom on the left side and 1 nitrogen atom on the right side, so the coefficient for NH₃ remains as 4. Similarly, we have 3 hydrogen (H) atoms on the left side and 6 hydrogen atoms on the right side, so the coefficient for H₂O becomes 6.

To balance the oxygen (O) atoms, we compare the number of O atoms on both sides. On the left side, we have 3 O atoms from NH₃ and 10 O atoms from O₂, giving us a total of 13 O atoms. On the right side, we have 4 O atoms from NO and 6 O atoms from H₂O, giving us a total of 10 O atoms. To balance the O atoms, we need to multiply the coefficient for O₂ by 5, resulting in 5O₂.

Now that the equation is balanced, we can determine the amounts of substances involved. Since the coefficient ratio is 4:5 between NH₃ and O₂, if we have 0.199 mol of NH₃, we will also have 0.199 mol of O₂ consumed. Similarly, the coefficients of the balanced equation tell us that 0.199 mol of NH₃ will produce 0.199 mol of NO and 0.298 mol of H₂O.

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Which of these is the function of a poly (A) signal sequence?
-It adds the poly (A) tail to the 3' end of the mRNA.
-It codes for a sequence in eukaryotic transcripts that signals enzymatic cleavage~10 35 nucleotides away.
-It allows the 3' end of the mRNA to attach to the ribosome.
-It is a sequence that codes for the hydrolysis of the RNA polymerase.
-It adds a 7-methylguanosine cap to the 3' end of the mRNA.

Answers

Poly (A) signal sequence is an RNA element that regulates the post-transcriptional processing of most eukaryotic genes. The Poly (A) signal sequence is responsible for adding the poly (A) tail to the 3' end of the mRNA.

It is a sequence that codes for enzymatic cleavage of the newly transcribed pre-mRNA. This signal marks the end of the coding region and the beginning of the 3′-untranslated region (3′-UTR) of the pre-mRNA.

The 3' end of the mRNA then attaches to the ribosome so that the mRNA can be translated into a protein. The 5' cap, which consists of a 7-methylguanosine structure, is added to the 5' end of the mRNA. The Poly (A) signal sequence is one of the key post-transcriptional mechanisms that regulate the timing and efficiency of mRNA translation. The length of the poly (A) tail is often a critical determinant of mRNA stability and translation efficiency.

Typically, the longer the poly (A) tail, the more stable and efficiently translated the mRNA. This is because the poly (A) tail binds to specific proteins that protect the mRNA from degradation and help the mRNA bind to ribosomes. The Poly (A) signal sequence is, therefore, a critical element in controlling gene expression.

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For example, a solution which places all of the values in a list and sorts the list can not achieve full marks.Hint: try starting with maximum aggregation (refer to the lecture materials) and work from there.Hint: the aggregation will require two summary variables.If the user inputs a number less than 2 for the number of people, the program should output a friendly message informing the user that at least 2 people are required.RequirementsYou must choose appropriate data types for user input.Your solution must not crash if the user inputs zero or one for a number of years.Your solution must be implemented using a for loop on a range.Your solution must not place user input values in a data structure (e.g. set, list, tuple, or dict) or use any predefined aggregation functions (e.g. max, sort).You must use the ask_for_height function to obtain the height of each person.def ask_for_height():height = int(input('Enter the height of a person (cm): '))return heightExample RunsRun 1Number of people: 4Enter the height of a person (cm): 174Enter the height of a person (cm): 153Enter the height of a person (cm): 86Enter the height of a person (cm): 189Second-tallest height: 174 cm while anticipating your career, share your job and how you may benefit (or not) from this freelance economy business model that is growing. This is a "more than Uber topic in 2019". Many Gen Xers and Baby Boomers see the gig economy as a place for under-employed hipsters to work-- it's more than that and it is now a mainstream part of our work life in America. nicole bought a piece of property for $12,000 she sold it for $15,000 what is the percent of increase In what ways are government agencies akin tomonopolies? In what ways are government agencies unlikeprivate-sector monopolies? Create a child class of PhoneCall class as per the following description: - The class name is lncomingPhoneCall - The lncomingPhoneCall constructor receives a String argument represents the phone number, and passes it to its parent's constructor and sets the price of the call to 0.02 - A getInfo method that overrides the super class getInfo method. The method should display the phone call information as the following: The phone number and the price of the call (which is the same as the rate) The income statement for Carew Ltd shows the following for the year ended 31 Decermber 2020 . Depreciation 89000 Erutertaining and 7.420 promotional gifts (note 1) Research and developmerst 126,500 (note 2) Warehousing and 227,900 distribution Motor expenses 57,900 Miscellaneous (note 3) 12.000 Note 1: Entertaining includes 6,250 for a client Christmas party with 50 attendees Note 2: all R\&D expenditure is eligible for RDEC Note 3: includes a 5,500 QCD Note 4: included in profit before tax is an amount remitted from an overseas branch of 25,000 which has had 5,000 of local tax deducted. The finance director considers that DTR could be claimed. Carew Ltd had a tax written down value of its general pool of 164.500 at 1 January 2020 and made purchases of plant and machinery of E68,500 during the year. Included within that is an amount for 12,500 for a piece of machinery that has a lifespan of two years. Required: 1. Prepare the capital allowances for the year ended 31 December 2020 (4 marks) 2. Prepare a corporation tax computation for Carew Ltd for the year ended 31 December 2020 (6 marks) 3. Explain how a thinly capitalised company must seek to reduce its Net Income and Owner's Equity for Four BusinessesFour different proprietorships, Aries, Gemini, Leo, and Pisces, show the same balance sheet data at the beginning and end of a year. These data, exclusive of the amount of owner's equity, are summarized as follows:Total AssetsTotal LiabilitiesBeginning of the year$84,400$33,800End of the year$135,000$56,700On the basis of the above data and the following additional information for the year, determine the net income (or loss) of each company for the year.(Hint: First determine the amount of increase or decrease in owner's equity during the year.)AriesThe owner had made no additional investments in the business and had made no withdrawals from the business.GeminiThe owner had made no additional investments in the business but had withdrawn $7,500.LeoThe owner had made an additional investment of $18,000 but had made no withdrawals.PiscesThe owner had made an additional investment of $27,800 and had withdrawn $6,400. Suppose we are preparing a lovely Canard `a lOrange (roast duck with orange sauce). We first take our duck out of a 36F refrigerator and place it in a 350F oven to roast. After 10 minutes the internal temperature is 53F. If we want to roast the duck until just under well-done (about 170F internally), when will it be ready