In nature, one common strategy to make thermodynamically unfavorable reactions proceed is to couple them chemically to reactions that are thermodynamically favorable. As long as the overall reaction is thermodynamically favorable, even the unfavorable reaction will proceed.
Part A
Consider these hypothetical chemical reactions:
A⇌B,ΔG= 14.8 kJ/mol
B⇌C,ΔG= -29.7 kJ/mol
C⇌D,ΔG= 8.10 kJ/mol
What is the free energy, ΔG, for the overall reaction, A⇌D?
Part B
Firefly luciferase is the enzyme that allows fireflies to illuminate their abdomens. Because this light generation is an ATP-requiring reaction, firefly luciferase can be used to test for the presence of ATP. In this way, luciferase can test for the presence of life. The coupled reactions are
luciferin+O2ATP⇌⇌oxyluciferin+lightAMP+PPi
If the overall ΔG of the coupled reaction is -7.50 kJ/mol , what is the equilibrium constant, K, of the first reactions at 11 ∘C ? The ΔG for the hydrolysis of ATP to AMP is −31.6 kJ/mol.

The nature of attack on sites in a molecule depends on the nature of such sites. The following are the nature of the sites mentioned in the question:

1) The indicated carbon in compound A is electrophilic.

2) The indicated bond in compound B is nucleophilic.

3) The indicated carbon in compound C is electrophilic.

4) The indicated carbon in compound D is neither electrophilic nor nucleophilic.

5) The indicated oxygen in compound E is nucleophilic.

The terms "electrophilic" and "nucleophilic" are very common in chemistry.

An electrophilic center is usually positively charged, has a positive dipole or is electron deficient hence it attacks negative centers. The term itself means "electron loving". That actually means that it has an affinity for negative charges.

The -I inductive effect of the bromine atom in the carbon in compound A makes that carbon atom to be electrophilic. Also, the carbonyl bond and the O C H 3 attached to the carbon in compound C also makes it electrophilic.

The term "nucleophilic" literately means "nucleus loving". That means a specie that has a high affinity for positive charges. This specie must be electron rich.

The carbon atom in compound B has a double bond which is electron rich and can attack any positive center hence it is nucleophilic. Also, the oxygen atom in E bears two lone pairs of electrons which can attack any positive center in a molecule hence the oxygen atom is also nucleophilic.

In compound D, the carbon atom is bonded to a methyl, two hydrogens and a carbon. There is a nitrogen atom two bonds away. There is no +I or -I inductive effect on this carbon atom because the nitrogen atom is far away. Therefore, the indicated carbon in compound D is neither electrophilic nor nucleophilic.

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Answer:

The various uses of water :

1. Water is used for daily purpose like cooking , bathing , cleaning and drinking.

2. Water is used as a universal solvent.

3. water maintains the temperature of our body.

4. Water helps in digestion in our body.

5 .water is used in factories and industries.

6. Water is used to grow plants , vegetables and crops.

Answer:

The various use of water are;

I) Cooking.

ii) Drinking

III) Bathing

iv) Generating hydro- electricity

v) Construction work etc

Answer:

answer in picture

Explanation:

Answer:

Explanation:

Answer:

6.02×10^23 I hope it helps you

Explanation:

I hope it helps you

Explanation:

here's the answer to your question

Answer:

35

Explanation:

is the answer for your question

Answer:

False

Explanation:

The first reaction is;

NO(g) + 1/2O2(g) ---->NO2(g)

K= [NO2]/[NO] [ O2]^1/2

The second reaction is;

2NO(g) + O2(g) ---->2NO2(g)

K'= [NO2]^2/[NO]^2 [O2]

It now follows that;

K'= K^2

Hence the statement in the question is false

Explanation:

the reaction is indeed an oxidation reduction reaction

Answer:

790 years

Explanation:

Given that;

0.693/t1/2 = 2.303/t log [A]o/[A]

So;

t1/2 =half life of carbon-14

t= age of the sample

[A]o= activity of the living sampoke

[A] = activity at time t

0.693/5.73 ×10^3 = 2.303/t log 85/77

1.21 × 10^-4 = 2.303/t log 1.1

1.21 × 10^-4 = 0.0953/t

t= 0.0953/1.21 × 10^-4

t= 790 years (to 2sf)

Answer:

B. Complex B.

Explanation:

Complex B will have binding site with high affinity for reduced plastocyanin due to greater redox potential. The high number of redox potential will will transport electron chain in cyanobacteria.

Redox potential is the measure of the electron gain or loss to the electrode. For reduced plastocyanin complex B will have the highest affinity.

Electron affinity is the energy released when the atom gets attached to the atom or other molecule. The high number of redox potential increases the electron transport in the cell.

The greater the redox potential more will be its tendency to show electron affinity. To bond with reduced species, the oxidized species must have greater redox potential.

Therefore, option B. complex b will have the highest affinity.

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Answer:

[tex]0.175\; \rm mol \cdot L^{-1}[/tex].

Explanation:

Magnesium chloride and silver nitrate reacts at a [tex]2:1[/tex] ratio:

[tex]\rm MgCl_2\, (aq) + 2\, AgNO_3\, (aq) \to Mg(NO_3)_2 \, (aq) + 2\, AgCl\, (s)[/tex].

In reality, the nitrate ion from silver nitrate did not take part in this reaction at all. Consider the ionic equation for this very reaction:

[tex]\begin{aligned}& \rm Mg^{2+} + 2\, Cl^{-} + 2\, Ag^{+} + 2\, {NO_3}^{-} \\&\to \rm Mg^{2+} + 2\, {NO_3}^{-} + 2\, AgCl\, (s)\end{aligned}[/tex].

The precipitate silver chloride [tex]\rm AgCl[/tex] is insoluble in water and barely ionizes. Hence, [tex]\rm AgCl\![/tex] isn't rewritten as ions.

Net ionic equation:

[tex]\begin{aligned}& \rm Ag^{+} + Cl^{-} \to AgCl\, (s)\end{aligned}[/tex].

Calculate the initial quantity of nitrate ions in the mixture.

[tex]\begin{aligned}n(\text{initial}) &= c(\text{initial}) \cdot V(\text{initial}) \\ &= 0.25\; \rm mol \cdot L^{-1} \times 0.150\; \rm L \\ &= 0.0375\; \rm mol \end{aligned}[/tex].

Since nitrate ions [tex]\rm {NO_3}^{-}[/tex] do not take part in any reaction in this mixture, the quantity of this ion would stay the same.

[tex]n(\text{final}) = n(\text{initial}) = 0.0375\; \rm mol[/tex].

However, the volume of the new solution is twice that of the original nitrate solution. Hence, the concentration of nitrate ions in the new solution would be [tex](1/2)[/tex] of the concentration in the original solution.

[tex]\begin{aligned} c(\text{final}) &= \frac{n(\text{final})}{V(\text{final})} \\ &= \frac{0.0375\; \rm mol}{0.300\; \rm L} = 0.175\; \rm mol \cdot L^{-1}\end{aligned}[/tex].

Answer:

56.5J

Explanation:

To find the heat energy required use the formula for the specific heat capacity which is

c=quantity of heat/mass×change in temperature

in this question c is 0.226j/g,the mass is 50g and the change in temperature is 30-25=5

therefore

0.226=Q/50×5

Q=0.226×250

=56.5J

I hope this helps

Answer:

[tex]T_2= 36.7 \textdegree C[/tex]

Explanation:

Mass of Water [tex]m_w=6.90kg[/tex]

Temperature [tex]T=34.7 degrees[/tex]

Heat Flow [tex]H=57.1kJ[/tex]

Specific heat capacity of water [tex]\mu= 4.18J.g^(-1).K^(-1)[/tex]

Generally the equation for Final Temperature is mathematically given by

[tex]M*\mu *T_1 + Q = M*\mu *T_2[/tex]

[tex]T_2=\frac{M*\mu *T_1 + Q }{M*\mu}[/tex]

Therefore

[tex]T_2=\frac{6.90*4.18*34.7 + 57.1}{6.90*4.18}[/tex]

[tex]T_2= 36.7 \textdegree C[/tex]

Answer:

19.2 g

Explanation:

Step 1: Write the balanced equation

P₂O₅(s) + 3 H₂O(l) ⇒ 2 H₃PO₄

Step 2: Calculate the moles corresponding to 5.29 g of H₂O

The molar mass of H₂O is 18.02 g/mol.

5.29 g × 1 mol/18.02 g = 0.294 mol

Step 3: Calculate the theoretical yield of phosphoric acid, in moles

The molar ratio of H₂O to H₃PO₄ is 3:2. The theoretical yield of H₃PO₄ is 2/3 × 0.294 mol = 0.196 mol

Step 4: Calculate the mass corresponding to 0.196 moles of H₃PO₄

The molar mass of H₃PO₄ is 97.99 g/mol.

0.196 mol × 97.99 g/mol = 19.2 g

Answer:

22.55 mmHg (0.03 atm)

Explanation:

According to Raoult's law, the vapor pressure (Psolution) of a solution is given by:

Psolution = Xsolvent x Psolvent

Where Xsolvent is the mole fraction of the solvent in the solution and Psolvent is the vapor pressure of the pure solvent.

From the data, we have: Psolvent = 25.76 mmHg

We have to calculate Xsolvent, which is equal to the moles of solvent divided into the total number of moles.

The solution is composed of the solute (glucose) dissolved in the solvent (water). So, the total number of moles is calculated from the moles of solute and solvent.

To calculate the moles of solute (glucose), we divide the mass of glucose into its molar mass:

moles of glucose = mass/molar mass = 550 g/(180.2 g/mol) = 3.05 mol

The same for the moles of solvent (water). The mass of water is obtained from the product of the volume and density:

mass of water = volume x density = 1020.0 mL x 1.00 g/mL = 1020.0 g

molar mass H₂O = (1 g/mol x 2) + 16 g/mol = 18 g/mol

moles of water = mass water/molar masss = 1020.0 g/(18 g/mol) = 56.67 mol

Now, we can calculate Xsolvent:

Xsolvent = moles of water/total moles

total moles = moles glucose + moles water = 3.05 mol + 56.67 mol = 59.72 mol

⇒ Xsolvent = 56.67 mol/(59.72 mol) = 0.9489

Finally, we calculate the vapor pressure of the solution:

Psolution = 0.9489 x 23.76 mmHg = 22.55 mmHg

22.55 mmHg x 1 atm/760 mmHg = 0.03 atm

Answer:

1. 17.5 g of CO₂

2. The limiting reactant is carbon (graphite), and its formula is C(graphite)

3. 3.7 g of O₂

Explanation:

First, we have to write the chemical equation for the reaction. For this, we have to know the chemical formula of each reactant and product:

Thus, we write the chemical equation:

C(graphite) + O₂(g) → CO₂(g)

The equation is already balanced because it has the same number of C and O atoms on both sides. Thus, we can see that 1 mol of C(graphite) reacts with 1 mol of O₂ and produce 1 mol of CO₂ (mole-to-mole reaction).

Now we convert the grams of reactants to moles by using the molecular weight (Mw) of each compound:

Mw(C) = 12 g/mol

moles of C(graphite) = 4.77g/(12 g/mol) = 0.3975 mol

Mw(O₂) = 16 g/mol x 2 = 32 g/mol

moles of O₂ = 16.4 g/(32 g/mol) = 0.5125 mol

Now, we can compare the stoichiometric ratio (given by the moles of reactants in the equation) with the actual ratio (given by the mass of reactants we have):

stoichiometric ratio ⇒ 1 mol C(graphite)/mol O₂

actual ratio ⇒ 0.3975 mol C(graphite)/0.5125 mol O₂

We can see that we need 0.3975 moles of O₂ to react with C(graphite) and we have more moles (0.5125 mol) so the excess reactant is O₂. Thus, the limiting reactant is C(graphite).

The amount of product (CO₂) that is formed is calculated from the amount of limiting reactant. We can see in the chemical equation that 1 mol of CO₂ is produced from 1 mol of C(graphite) ⇒ stoichiometric ratio = 1 mol CO₂/mol C(graphite).

Thus, we multiply the moles of C(graphite) we have by the stoichiometric ratio to calculate the moles of CO₂ produced:

moles of CO₂ = 0.3975 mol C(graphite) x 1 mol CO₂/mol C(graphite) = 0.3975 mol CO₂

Now, we convert the moles of CO₂ to mass by using the Mw:

Mw(CO₂) = 12 g/mol + (16 g/mol x 2) = 44 g/mol

mass of CO₂ = 0.3975 mol CO₂ x 44 g/mol CO₂ = 17.5 g

Therefore, the maximum amount of carbon dioxide (CO₂) formed is 17.5 g.

Since this is a mole-to-mole reaction, the moles of excess reactant that remains after the reaction is complete is calculated as the difference between the moles of excess reactant and limiting reactant:

remaining moles of O₂ = 0.5125 mol - 0.3975 mol = 0.115 mol O₂

Finally, we convert the moles of O₂ to mass with the Mw (32 g/mol) :

mass of O₂ = 0.115 mol O₂ x 32 g/mol = 3.68 g

Therefore, the mass of the excess reagent that remains after the reaction is complete is 3.7 g.

Answer:

The molar mass of benzoic acid is 122.1 g/mol

The molar mass of hydrochloric acid = 36.5 g/mol

Explanation:

Benzoyl chloride is an organic compound with the molecular formula C₆H₅COCl. It is an acyl chloride since is it an organic derivative of a carboxylic acid. Acyl chlorides have the general molecular formula, R-COCl, where R is a side chain.

The R group of benzoyl chloride is the benzyl group C₆H₅. It reacts with water (hydrolysis) to produce hydrochloric acid and benzoic acid. The equation of the reaction is given below:

C₆H₅COCl + H₂O → C₆H₅CO₂H + HCl

The molar mass of benzoic acid as well as of hydrochloric acid is calculated from the sum of the masses of the atoms of the elements present in the compound thus:

Molar mass of carbon = 12.0107 g

Molar mass of hydrogen = 1.00784 g

Molar mass of oxygen = 15.999 g

Molar mass of chlorine = 35.453 g

Molar mass of benzoic acid, C₆H₅CO₂H containing 7 moles of atoms of carbon, 6 moles of atoms of hydrogen and 2 moles of atoms of oxygen = 7 × 12.0107 + 6 × 1.00784 + 2 × 15.999 = 122.1 g

Therefore, the molar mass of benzoic acid is 122.1 g/mol

Molar mass of hydrochloric acid, HCl, containing 1 mole of atoms of hydrogen and 1 mole of atoms of chlorine = 1 × 1.00784 + 1 × 35.453 = 36.5 g

Therefore, the molar mass of hydrochloric acid = 36.5 g/mol

Dynamic equilibrium is showed at the point at which solid liquid and gas intersect.

At the point at which solid liquid and gas intersect represents a system that shows dynamic equilibrium. There is equal amount of reactants and products at the point of dynamic equilibrium because the transition of substances occur between the reactants and products at equal rates, means that there is no net change. Reactants and products are formed at the rate that no change occur in their concentration.

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Answer:

Zero-Order

Explanation:

The exothermic decaying of nitrous oxide at 575° C will lead to [tex]N_{2} and O_{2}[/tex] as follows:

[tex]2N_{2}O[/tex] → [tex]2N_{2}(g) + O_{2} (g)[/tex]

Hot platinum wire in the above reaction would function as a catalyst in the zero-order. However, if the reaction is considered in the gaseous phase, it will be more inclined towards second-order.

In the given scenario([tex]2N_{2}O[/tex] → [tex]2N_{2}(g) + O_{2} (g)[/tex]), the reactant molecules of Nitrous oxide are restricted to the ones which have linked themselves to the catalyst's surface. Once this limited surface is filled, the extra molecules of gas would remain vacant until the previously attached molecules with the surface are decayed entirely.

Answer:

The answer is D which is Selenium

Answer:

D

Explanation:

We have to bear in mind that the acid is a weak acid. A weak acid does not dissociate completely in solution. We will have more concentration of undissociated acid than A^- and H3O^+ and OH^- in the system at equilibrium.

Being a weak acid, there is maximum concentration of water molecules followed by that of undissiociated acid.

Hence, for this solution, the concentration of ions in solution follows the order;

[H2O] > [HA] > [A-] ~ [H3O ] > [OH-]

Answer:

Mass gallium (Ga°(s)) produced ≅ 0.800 grams (1 sig. fig.)

Explanation:

Ga(OH)₃ => Ga⁺³ + 3OH⁻

Ga⁺³ + 3e⁻ => Ga°(s)

? grams Ga°(s) = 0.680 Amps x 1 mole e⁻/1 Faraday x 1 Faraday/96,500 Amp·sec x 1 mole Ga°/3 moles e⁻ x 69.723 grams Ga°/mole Ga° x 60 sec/1 min x 80 min = [(0.680)(69.723)(60)(80)/(96,500)(3)] grams Ga° = 0.786099731 grams Ga° (calc. ans.) ≅ 0.800 grams Ga°  (1 sig. fig.)

Answer:

the answer is C

Explanation:

a molecule can be made up of two atoms of the same kind, as when two oxygen atoms bind together to make an oxygen molecule

I'd really appreciate a brainleast

Answer:

gamma rays , alpha particles , beta particles , neutrons

Answer:

I think its A maybe am not sure

Answer:

COOHCOOH + 2OH⁻ ⇄  C₂O₄²⁻ + 2H₂O

Explanation:

The reaction of oxalic acid with a strong base like sodium hydroxide is the following:

COOHCOOH + OH⁻ ⇄ COOHCOO⁻ + H₂O    (1)

In this first reaction, the oxalic acid loses one proton. In a second reaction with NaOH, the ion COOHCOO⁻ loses its second proton to form ion oxalate as follows:

COOHCOO⁻ + OH⁻ ⇄ C₂O₄²⁻ + H₂O      (2)  

The general reaction between oxalic acid and NaOH is (eq 1 + eq 2):

COOHCOOH + 2OH⁻ ⇄  C₂O₄²⁻ + 2H₂O              

I hope it helps you!  

Answer

A

Explanation:

due to high specific heat capacity it loses heat and has low temperature

Answer:

6.684g

Explanation:

Here, we can use the mole ratio of the gases to calculate.

We know that the mole ratio of the gases equate to their number of moles.

Firstly, we calculate the number of moles of the oxygen gas. The number of moles of the oxygen gas is equal to the mass of the oxygen gas divided by the molar mass of the oxygen gas. The molar mass of the oxygen gas is 32g/mol

Thus, the number of moles produced is 5.98/32 = 0.186875

Where do we move from here?

We know that if we place the partial pressure of oxygen over the total pressure, this would be equal to the number of moles of oxygen divided by the total number of moles. Now let’s do this.

449/851 = 0.186875/n

n =(0.186875 * 851)/449

n = 0.3542

Now we do the same for argon to get the number of moles of argon.

Firstly, we use dalton’s partial pressure law to get the partial pressure of argon. In the simplest form, the partial pressure of argon is the total pressure minus the partial pressure of oxygen.

P = 851 - 449 = 402 mmHg

We now use the mole ratio relation.

402/851 = n/0.3542

n = (402 * 0.3542) / 851

n = 0.1673

Since we now know the number of moles of argon, we can use this multiplied by the atomic mass of argon to get the mass.

The atomic mass of argon is 39.948 amu

The mass is thus 39.948 * 0.1673 = 6.684g

Answer:

D. [CO₂]

Explanation:

Let's consider the following equation at equilibrium.

CaCO₃(s) ⇄ CaO(s) + CO₂(g)

The equilibrium constant, Kc, is the ratio of the equilibrium concentrations of products over the equilibrium concentrations of reactants each raised to the power of their stoichiometric coefficients. It only includes gases and aqueous species.

Kc = [CO₂]