Given the reaction:SO2 + C → SO3 + COf the above equation, the stoichiometric coefficients are as follows:
SO2 is 1C is 1SO3 is 1CO is 1To determine the moles of C needed to react with 1.42 moles of SO2, we need to use the stoichiometry of the balanced chemical equation as shown above.We have 1.42 moles of SO2. Using the coefficients of the balanced chemical equation, the amount of moles of C required will be equal to 1.42 moles since the coefficients are 1. Therefore, 1.42 moles of C are needed to react with 1.42 moles of SO2.In order to react with 1.42 moles of SO2, 1.42 moles of C are required.
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the diffusion coefficient of fe in bcc iron is approximately 3 x 10-11 cm2/s at 900 oc and 1.5 x 10-14 cm2/s at 630oc. the activation energy in cal/mol is approximately
The activation energy of Fe in BCC iron is approximately 139.06 cal/mol at 900 OC and 199.17 cal/mol at 630 OC.
Given:The diffusion coefficient of Fe in BCC iron is approximately 3 x 10-11 cm2/s at 900 OC and 1.5 x 10-14 cm2/s at 630OCFormula:The Arrhenius equation: k = Ae^(-Q/RT)
Activation Energy, Q = -R ln(k/T)where R is the gas constant, k is the rate constant, T is the absolute temperature, and A is the pre-exponential factor.Calculation:R = 1.987 cal/(mol K)
The activation energy is given byQ=−Rln(kT)At 900 OC: k= 3 x 10-11 cm2/s and T = 1173 KR= 1.987 cal/mol.Kln(kT) = ln(3 x 10^-11 cm²/s × 1173 K) = -69.91 Q = -1.987 cal/(mol K) × (-69.91) Q = 139.06 cal/molAt 630 OC: k = 1.5 × 10-14 cm2/s and T = 903 KR = 1.987 cal/(mol K)ln(kT) = ln(1.5 × 10^-14 cm²/s × 903 K) = -100.32 Q = -1.987 cal/(mol K) × (-100.32) Q = 199.17 cal/mol
Therefore, the activation energy of Fe in BCC iron is approximately 139.06 cal/mol at 900 OC and 199.17 cal/mol at 630 OC.
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