Answer:
Explanation:
From the given information ;the objective is to determine how the instructor made the 0.25L elution buffer
0.25 L elution buffer = 250 mL elution butter
The breaking buffer that we use this week contains
10mM Tris = 0.01 M
150mM NaCl = 0.15 M
300mM imidazole. = 0.3 M
The stock concentration of Tris in 1M
Therefore ; by using the formula: [tex]M_1V_1 = M_2 V_2[/tex]; we can determine the volume in the preparation; so;
[tex]1*V_1 = 0.0 1 \ M * 250 \ mL[/tex]
[tex]V_1 = \dfrac{0.0 1 \ M * 250 \ mL}{1 }[/tex]
[tex]V_1 = 2.5 \ mL[/tex]
In NaCl, The amount of stock concentration is 5 M
so; using the same formula; we have:
[tex]5*V_1 = 0.15 \ M * 250 \ mL[/tex]
[tex]V_1 = \dfrac{0. 15 \ M * 250 \ mL}{5 }[/tex]
[tex]V_1 = 7.5 \ mL[/tex]
From Imidazole ; the amount of stock concentration is
[tex]1*V_1 = 0.3 \ M * 250 \ mL[/tex]
[tex]V_1 = \dfrac{0. 3 \ M * 250 \ mL}{1 }[/tex]
[tex]V_1 = 75 \ mL[/tex]
Thus; we can have a table as shown as :
Stock concentration volume to be added Final concentration
1 M of Tris 2.5 mL 10 mM
5 M of NaCl 7.5 mL 150 mM
1 M of Imidazole 75 mL 300 mM
In conclusion. the addition of all the volume make up the 250 mL elution buffer that is equivalent to 0.25 L.
A chemistry student weighs out 0.306 g of citric acid (H3C6H5O7) , a triprotic acid, into a 250. mL volumetric flask and dilutes to the mark with distilled water. He plans to titrate the acid with 0.1000 M NaOH solution. Calculate the volume of NaOH solution the student will need to add to reach the equivalence point. Be sure your answer has the correct number of significant digits
Answer:
THE VOLUME OF NaOH NEEDED TO BE ADDED TO CITRIC ACID TO REACH THE EQUIVALENT POINT IS 4.725 L
Explanation:
The titration is between citric acid (H3C6H507) and NaOH
mass of citric acid = 0.306 g
Volume of citric acid = 250 mL = 250 /1000 = 0.25 L
Concentration of NaOH = 0.1000 M
Volume = unknown
First calculate the molar mass of citric acid
( 1 * 3 + 12* 6 + 1*5 + 16*7) = (4 + 72 + 5 + 112) = 193 g/mol
Since,
Concentration in moles/dm3 = concentration in g/dm3 / RMM
So the molarity of citric acid is:
Molarity = 0.306g / 0.25dm3 / Rmm
Molarity = 1.224g/dm3 / 193 g/mol
Molarity = 0.0063 M
Equation for the reaction is:
C3H5O(COOH)3 + 3NaOH → Na3C3H5O(COO)3 + 3H2O
Using the formula:
CaVa / CbVb = na/ nb
Ca = 0.0063 M
Cb = 0.1000 M
Va = 0.25 L
Vb = unknown
na = 1
nb = 3
Vb = Ca Va nb/ Cb na
Vb = 0.0063 * 0.25 * 3 / 0.1000 * 1
Vb = 0.4725 / 0.1000
Vb = 4.725 L
The volume of NaOH needed to reach the equivalent point is therefore 4.725 L
what is the balanced equation for calcium sulfate?
Answer:
CaSO4
Explanation:
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates.
A semipermeable sac containing 4% NaCl, 9% glucose, and 10% albumin is suspended in a solution with the following composition: 10% NaCl, 10% glucose, and 40% albumin. Assume that the sac is permeable to all substances except albumin. State whether each of the following will (a) move into the sac, (b) move out of the sac, or (c) not move.
glucose: a. moves into sac
water: b. moves out of sac
albumin: c; does not move
NaCl: a; moves into sac
Answer:
Glucose: (a) moves into sac
Water: (b) moves out of sac
Albumin: (c) does not move
NaCl: (a) moves into sac
Explanation:
A semi-permeable membrane is a membrane that allow certain molecules or ions to pass through by diffusion.
Diffusion is the movement of molecules from a region of higher concentration to a region of lower concentration until equilibrium is attained. A special form of diffusion known as osmosis transports water molecules across a semi-permeable membrane.
Osmosis is the movement of water molecules from a region lower solute concentration (high water molecules concentration) to a region of higher solute concentration (low water molecules concentration) until equilibrium is attained.
From the above definitions and the given data;
Glucose concentration is higher in solution outside the sac, thus, glucose molecules will move into the sac.
Water molecules are higher in the sac as a result of the lower concentration of solutes, therefore, water molecules will move out of the sac into the solution outside.
Since the sac is impermeable to albumin, it does not move.
NaCl concentration is lower in the sac, therefore, it will move ro the solution outside into the sac.
Glucose will move into the sac, water will move out of the sac, albumin will neither move in nor out, and NaCl will move into the sac.
The molecules of each of the substances will move by diffusion from the region of higher concentration to the region of lower concentration of each substance as long as there is a permeable membrane. Water, on the other hand, will move by osmosis from the region of high to low water potential through a permeable membrane. Regions with higher concentrations of substances usually have low water potentials and vice versa.Thus, both glucose and NaCl molecules will diffuse from the solution into the sac, and water molecules will move from the sac into the surrounding solution. Since the sac is not permeable to albumin, then the movement in or out is inhibited.
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Suppose that while you're in the lab performing a simple distillation you encountered one of the following errors: The components within the mixture, isopropanol and dichloromethane, distilled well below their boiling point. Poor separation between isopropanol and dichloromethane was observed. The initial volume of the distillation mixture has decreased significantly, almost dry, but no distillate was collected.
Answer:
Isopropanol and dichloromethane, distilled well below their boiling point.
Explanation:
The best way to separate isopropanol and dichloromethane is the method of fractional distillation. In this method, different compounds separate from each other due to difference in boiling. The boiling point of dichloromethane is 39.6 degree Celsius which is lower than the boiling point of isopropanol which is 82.5 degree Celsius. So dichloromethane will be evaporated when the temperature reaches to 40 degree Celsius and separated from isopropanol before reaching its boiling point.
The half-life of radium-226 is 1590 years. (a) A sample of radium-226 has a mass of 50 mg. Find a formula for the mass of the sample that remains after t years. (b) Find the mass after 500 years correct to the nearest milligram. (c) When will the mass be reduced to 40 mg
Answer:
Explanation:
a )
m = m₀ [tex]e^{-\lambda t[/tex]
m is mass after time t . original mass is m₀ , λ is disintegration constant
λ = .693 / half life
= .693 / 1590
= .0004358
m = m₀ [tex]e^{- 0.0004358 t}[/tex]
b )
m = 50 x [tex]e^{-.0004358\times 500}[/tex]
= 40.21 mg .
c )
40 = 50 [tex]e^{-.0004358t[/tex]
.8 = [tex]e^{-.0004358t[/tex]
[tex]e^{.0004358t[/tex] = 1.25
.0004358 t = .22314
t = 512 years .
A boy with pneumonia has lungs with a volume of 1.7 L that fill with 0.070 mol of air when he inhales. When he exhales, his lung volume decreases to 1.3 L. Enter the number of moles of gas that remain in his lungs after he exhales. Assume constant temperature and pressure.
Answer:
0.053moles
Explanation:
Hello,
To calculate the number of moles of gas remaining in his after he exhale, we'll have to use Avogadro's law which states that the volume of a given mass of gas is directly proportional to its number of moles provided that temperature and pressure are kept constant. Mathematically,
V = kN, k = V / N
V1 / N1 = V2 / N2= V3 / N3 = Vx / Nx
V1 = 1.7L
N1 = 0.070mol
V2 = 1.3L
N2 = ?
From the above equation,
V1 / N1 = V2 / N2
Make N2 the subject of formula
N2 = (N1 × V2) / V1
N2 = (0.07 × 1.3) / 1.7
N2 = 0.053mol
The number of moles of gas in his lungs when he exhale is 0.053 moles
BASIC CALCULATIONS IN SPECTROSCOPY
1. Calculate the %T of light at 425nm if the light entering the cell is 200 lumens and the amount of light exiting the cell is 50 lumens.
2. Calculate the absorbance of the above problem.
Answer: 25%
Explanation:
1. Transmittance, T= P/P0
Where P = light exiting the cell
P0 = light entering the cell
Therefore %T = P/P0 ×100
= 50/200×100
=25%
2. Absorbance, A= -log(T)
But T= 0.25
Therefore A= -log(0.25)
= 0.6020
A certain metal forms a soluble nitrate salt M(NO3)3. Suppose the left half cell of a galvanic cell apparatus is filled with a 3.0mM solution of M(NO3)3 and the right half cell with a 3.0M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 20.0 C.
Required:
a. Which electrode will be positive?
b. What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode.
Answer:
1.The electrode on the right is positive
2. 0.058V
Explanation:
The above cell is a concentration cell.
A concentration cell is an electrolytic cell that is made of two half-cells with the same electrodes, but differs in concentrations of the solutions. A concentration cell functions by diluting the more concentrated solution and concentrating the more dilute solution, creating a voltage as the cell reaches an equilibrium thereby transferring the electrons from the cell with the lower concentration to the cell with the higher concentration.
In the above cell, electrons flow from the left electrode (less concentrated) to the right electrode (more concentrated). Therefore, the right electrode is the positive electrode (cathode).
Part 2: Please, see the attachment below for the calculations.
An unknown compound, B, has the molecular formula C7H12. On catalytic hydrogenation 1 mol of B absorbs 2 mol of hydrogen and yields 2-methylhexane. B has significant IR absorption band at about 3300 and 2200 cm-1. Which compound best represents B?
Answer:
5-methylhex-1-yne//5-methylhex-2-yne//2-methylhex-3-yne
Explanation:
We have to start with the information on the IR spectrum. The signal at 3300 is due to a C-H bend sp carbon and the signal in 2200 is due to the stretch carbon-carbon. Therefore we will have an alkyne. Now if we have 2-methylhexane as the product of hydrogenation we have several options to put the triple bond. Between carbons 1 and 2 (5-methylhex-1-yne), between carbons 2 and 3 (5-methylhex-2-yne) and between carbons 3 and 4 (2-methylhex-3-yne). On carbon 5 we have a tertiary carbon therefore we dont have any other options.
See figure 1
I hope it helps!
In what unit do we usually measure the force of the earth gravity? Acceleration due to gravity is 9.8/s^2
Answer:
in short weight
Explanation:
weight is mass x gravitational pull on an object
A student sets up the following equation to convert a measurement. (The ? stands for a number the student is going to calculate.) Fill in the missing part of this equation. Note: your answer should be in the form of one or more fractions multiplied together. (23. Pa cm^3)____?kPa . m^3
Answer:
The correct answer will be "-6.7 × 10¹⁰ kg.m/s".
Explanation:
The required conversions are:
⇒ [tex]1 \ kg=1000 \ g[/tex]
⇒ [tex]1 \ m=100 \ cm[/tex]
Now,
The complete conversion will be:
= [tex][-6.7\times 10^5 \ \frac{kg \ m}{s} ]\times [\frac{10^3 \ g}{kg}\times \frac{10^2 \ cm}{1 \ m}][/tex]
On cancelling the terms, we get
= [tex]-6.7\times 10^{10} \frac{kg \ m}{s}[/tex]
So that the missing terms will be [tex][\frac{10^3 \ g}{kg}\times \frac{10^2 \ cm}{1 \ m}][/tex] and [tex][-6.7\times 10^{10}\frac{kg \ m}{s}][/tex]
Pyruvate is the end product of glycolysis. Its further metabolism depends on the organism and on the presence or absence of oxygen. Draw the structure of the product from each reaction as it would exist at pH 7. Include the appropriate hydrogen atoms. Reaction A: aerobic conditions in humans or yeast
The given question is incomplete. The image present in the question for Reaction A is attached below along with the answer.
Explanation:
Pyruvate molecule reacts with Coenzyme A in the presence of oxygen and it results in the formation of acetyl Coenzyme A and carbon dioxide.
The enzyme pyruvae dehydrogenase helps in catalyzing this reaction. As in this biochemical reaction [tex]NAD^{+}[/tex] gets converted into NADH.
This reaction is shown in the image attached below.
At 25 oC, the rate constant for the first-order decomposition of a pesticide solution is 6.40 x 10-3 min-1. If the starting concentration of pesticide is 0.0314 M, what concentration will remain after 62.0 minutes at 25 oC? 3.12 x 10-2 M 47.4 M 2.11 x 10-2 M 4.67 x 10-2 M 8.72 M
Answer:
[tex]2.11\ * 10^{-2}[/tex] is the correct answer to the given question.
Explanation:
Given k=6.40 x 10-3 min-1.
According to the first order reaction .
The concentration of time can be written as
[tex][\ A\ ]\ = \ [\ A_{0}\ ] * e \ ^\ {-kt}[/tex]
Here [tex][\ A\ ]_{0}[/tex] = Initial concentration.
So [tex][\ A\ ]_{0}= 0.0314 M[/tex]
Putting this value into the above equation.
[tex]0.0314 \ *\ e^{6.40 x 10^{-3} \ * \ 62.0 }[/tex]
=0.211 M
This can be written as
[tex]=\ 2.11 *\ 10^{-2}[/tex]
One of the many remarkable enzymes in the human body is carbonic anhydrase, which catalyzes the interconversion of carbon dioxide and water with bicarbonate ion and protons. If it were not for this enzyme, the body could not rid itself rapidly enough of the CO2 accumulated by cell metabolism. The enzyme catalyzes the dehydration (release to air) of up to 107 CO2 molecules per second. Which components of this description correspond to the terms enzyme, substrate, and turnover number?
Answer:
Enzyme is carbonic anhydrase
Substrate is [tex]CO_2[/tex]
Turnover number is [tex]10^{7}[/tex]
Explanation:
An enzyme is used by a living organism as a catalyst to perform a specific biochemical reaction.
A substrate is a molecule upon which an enzyme acts.
Turnover number refers to the number of substrate molecules transformed by a single enzyme molecule per minute. Here, the enzyme is the rate-limiting factor.
Here,
Enzyme is carbonic anhydrase
Substrate is [tex]CO_2[/tex]
Turnover number is [tex]10^{7}[/tex]
why does Portland have moderate climate
Answer:
Due to its location, Portland has a moderate climate. Also, which portland are you talking about? Portland Oregon or Portland Maine. Portland Oregon has a much more rainy climate, so I would say Maine has a better climate.
Explanation:
A 20.0-mL sample of lake water was acidified with nitric acid and treated with excess KSCN to form a red complex (KSCN itself is colorless). The solution was then diluted to 50.0-mL and put in a 1.00 cm pathlength cell, where it yielded an absorbance of 0.345. For comparison, a 5.0-mL reference sample of 4.80 x 10-4 M Fe3 was treated with HNO3 and KSCN and diluted to 50.0 mL. The reference solution was also placed in a 1.00-cm cell and gave an absorbance of 0.512. What is the concentration of Fe3 in Jordan Lake
Answer:
8.09x10⁻⁵M of Fe³⁺
Explanation:
Using Lambert-Beer law, the absorbance of a sample is proportional to its concentration.
In the problem, the Fe³⁺ is reacting with KSCN to produce Fe(SCN)₃ -The red complex-
The concentration of Fe³⁺ in the reference sample is:
4.80x10⁻⁴M Fe³⁺ × (5.0mL / 50.0mL) = 4.80x10⁻⁵M Fe³⁺
Because reference sample was diluted from 5.0mL to 50.0mL.
That means a solution of 4.80x10⁻⁵M Fe³⁺ gives an absorbance of 0.512
Now, as the sample of the lake gives an absorbance of 0.345, its concentration is:
0.345 × (4.80x10⁻⁵M Fe³⁺ / 0.512) = 3.23x10⁻⁵M.
As the solution was diluted from 20.0mL to 50.0mL, the concentration of Fe³⁺ in Jordan lake is:
3.23x10⁻⁵M Fe³⁺ × (50.0mL / 20.0mL) = 8.09x10⁻⁵M of Fe³⁺
The concentration of Fe³⁺ in Jordan Lake is = 8.09* 10⁻⁵ M
According to Lambert-Beer law ;The rate of absorbance of a sample is directly proportional to concentration of the sample
The reaction that produces a red complex
Fe³⁺ + KScN ----> Fe ( SCN )₃ ( red complex )
First step: Determine the Concentration of Fe³⁺ in reference sample
= 4.80x10⁻⁴ * ( 5.0 / 50.0 ) = 4.80 * 10⁻⁵M
reference sample was diluted from 5.0 mL to 50.0 mL
∴ Concentration of 4.80 * 10⁻⁵M has an absorbance = 0.512
Given that Lake sample absorbance = 0.345
Next step : Determine the concentration of the lake sample
Concentration of lake sample :
= absorbance of lake sample * ( conc of reference sample / absorbance )
= 0.345 * ( 4.80* 10⁻⁵ / 0.512 ) = 3.23* 10⁻⁵M.
Final step : Determine the concentration of Fe³⁺ in Jordan lake
= 3.23 * 10⁻⁵ * ( 50.0mL / 20.0mL) = 8.09* 10⁻⁵ M
Note : Solution was diluted from 20.0 mL to 50.0 mL
Hence we can conclude that The concentration of Fe³⁺ in Jordan Lake is = 8.09* 10⁻⁵ M .
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Isomer such as acetic acid and methyl formate have
Answer:
C
Explanation:
This is the definition of an isomer.
Which option describes a similarity and a difference between isotopes of an element? A. same atomic number; different number of protons B. same number of protons; different atomic number C. same atomic number; different mass number D. same mass number; different atomic number E. same number of neutrons; same number of protons
Answer:
c
Explanation:
A 8.00g of a certain Compound X, known to be made of carbon, hydrogen and perhaps oxygen, and to have a molecular molar mass of 44./gmol, is burned completely in excess oxygen, and the mass of the products carefully measured: product mass carbon dioxide 24.01g water 13.10g Use this information to find the molecular formula of X.
Answer:
C3H6.
Explanation:
Data obtained from the question:
Mass of the compound = 8g
Mass of CO2 = 24.01g
Mass of H2O = 13.10g
Next, we shall determine the mass of C, H and O present in the compound. This is illustrated below:
Molar Mass of CO2 = 12 + (2x16) = 44g/mol
Molar Mass of H2O = (2x1) + 16 = 18g/mol
Mass of C in compound = Mass of C/Molar Mass of CO2 x 24.01
=> 12/44 x 24.01 = 6.5g
Mass of H in the compound = Mass of H/Molar Mass of H2O x 13.1
=> 2x1/18 x 13.1 = 1.5g
Mass of O in the compound = Mass of compound – (mass of C + Mass of H)
=> 8 – (6.5 + 1.5) = 0
Next, we shall determine the empirical formula of the compound. This is illustrated below:
C = 6.5g
H = 1.
Divide by their molar mass
C = 6.5/12 = 0.54
H = 1.4/1 = 1.
Divide by the smallest
C = 0.54/0.54 = 1
H = 1/0.54 = 2
Therefore, the empirical formula is CH2
Finally, we shall determine the molecular formula as follow:
The molecular formula of a compound is a multiple of the empirical formula.
Molecular formula = [CH2]n
[CH2]n = 44
[12 + (2x1)]n = 44
14n = 44
Divide both side by 14
n = 44/14
n = 3
Molecular formula = [CH2]n = [CH2]3 = C3H6
Therefore, the molecular formula of the compound is C3H6
where are chemicals found in the home?
a. only in the bathroom
b. only in locked cabinets
c. in every room
d. only in the kitchen
Answer:
c
Explanation:
chemicals can be found in every part of our lives
A gas company in Massachusetts charges $2.80 for 15.0 ft3 of natural gas (CH4) measured at 20.0°C and 1.00 atm. Calculate the cost of heating 2.00 × 102 mL of water (enough to make a cup of coffee or tea) from 20.0°C to 100.0°C. Assume that only 50.0% of the heat generated by the combustion is used to heat the water; the rest of the heat is lost to the surroundings. Assume that the products of the combustion of methane are CO2(g) and H2O(l).
Answer:
$0.0238
Explanation:
The energy you need to increase the temperature of water from 20°C to 100°C is obtained from:
Q = C×m×ΔT
Where Q is the energy, C is specific heat of water (4.184J/g°C), m is mass of water (2.00x10²g - Density of water 1g/mL), ΔT is change in temperature (100.0°C - 20.0°C)
Replacing:
Q = 4.184J/g°C × 2.00x10²g × 80.0°C
Q = 66944J = 66.944kJ
As you are assuming the energy of combustion will be just 50.0% to heat the water the energy you need is 66.944kJ × 2 = 133.888kJ
The combustion of methane is:
CH4(g) + 2O2(g) ⟶ CO2(g) + 2H2O(l) ΔH = −890.8kJ
That means 1 mole of methane produce 890.8kJ. As you need 133.888kJ, moles of methane are:
133.888kJ × (1 mol CH₄ / 890.8kJ) = 0.150 moles of CH₄.
Using PV = nRT, moles of 15.0ft³ (424.8L) at 20.0°C (293.15K) and 1.00atm:
1.00atmₓ424.8L = moles CH₄ₓ0.082atmL/molKₓ293.15K
17.67 = moles CH₄
As 17.67 moles of CH₄ cost $2.80, the cost of 0.150 moles of CH₄ is:
0.150 moles CH₄ ₓ ($2.80 / 17.67 moles) =
$0.0238Which of the following best describe an atomic number? An element identity is defined by its atomic number this means it represents the number of
a)Atomic number is the number of protons in the nucleus of an atom.
b)atomic number represents the number of protons
An element's identity is defined by its atomic number; this means it represents the number of protons in its nucleus.
The question is incomplete, the complete question is;
Which of the following best describes an atomic number? An element's identity is defined by its atomic number; this means it represents the number of
A) protons plus neutrons in its nucleus.
B) electrons in the element.
C) protons in its nucleus.
D) neutrons in its nucleus.
The subatomic particles in the atom are;
ElectronsProtonsNeutronsNeutrons and protons are contained in the nucleus hence they are collectively called nucleons.
Electrons are found in the orbits. The number of protons must be equal to the number of electrons for the atom to be electrically neutral.
The number of protons in an atom or atomic number serve as a means of identifying an atom.
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Which of the following viewed the atom as having a nucleus made up of protons and neutrons,with electrons orbiting the nucleus in fixed, stable orbits, much like the planets orbit the sun?
The correct answer is C. Bohr's model
Explanation:
Bohr's model of the atom developed in 1913 proposed each atom contained a nucleus with protons and neutrons. Also, there were electrons that orbited the nucleus. About this, Niels Bohr proposed the orbits of electrons were similar to those of planets around the sun; however, these did not occur due to gravity but to attraction forces. This model integrated new accurate ideas about the atom. However, this model was still inaccurate because particles in an atom are electrically charged and electrons do not orbit in fixed stable orbits and cannot be compared to the movement of planets around a star.
Answer:
Bohr's model
Explanation:
Which of the following formulas represents an ionic compound?
1.HI 2.HCI 3.LiCI 4.SO2
Answer:
Numbers 4,3
Explanation:
Ionic bond is between nonmental and metals
Commercially available hot packs are simple in design: a pouch with water on one side, isolated by a barrier from a specific salt on the other side. When the barrier is broken, the salt and water mix and the solution becomes hot. Select the statement that is true about the reaction occurring in hot packs.A. The hot pack absorbs heat from the environment.
B. The reaction between the salt and water is exothermic.
C. The reaction between the salt and water is endothermic.
D. The reaction between the salt and water is neither endothermic nor exothermic.
Answer:
b :)
Explanation:
an exothermic reaction is when heat/light is produced. heart is produced from this reaction so it is exothermic
The correct answer is option c. The reaction between salt and water is endothermic.
How are salt and water endothermic?Chemical reaction
Salt is a hygroscopic material that attracts water and heat from its surroundings. This is why leather shoes are "dry" and wrinkled when covered with salt. This type of reaction is known as an endothermic reaction, which is a chemical reaction that absorbs heat.
Endothermic reaction: A chemical reaction that absorbs heat is called an endothermic reaction. The temperature will drop. For example, (i) heating nitrogen and oxygen together to a temperature of about 3000 ° C produces nitrogen oxide gas. N2 + O2 + heat → 2NO (g)
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A temperature of 50°F is equal to °C.
Answer:
CONVERT IT:
50°F is equal to 10°C
Answer:
10 degrees Celsius
Explanation:
(50°F − 32) × 5/9 = 10°C
A sample of carbon dioxide gas at a pressure of 879 mm Hg and a temperature of 65°C, occupies a volume of 14.2 liters. Of the gas is cooled at constant pressure to a temperature of 23°C, the volume of the gas sample will be
Answer:
The correct answer is 12.43 Liters.
Explanation:
Based on the given question, the volume V₁ occupied by the sample of carbon dioxide gas is 14.2 liters at temperature (T₁) 65 degree C or 65+273 K = 338 K.
The gas is cooled at a temperature (T₂) 23 degree C or 273+23 K = 296 K
The volume of the gas (V₂) after cooling can be determined by using the formula,
V₁/T₁ = V₂/T₂
14.2/338 = V₂/296
0.0420 = V₂/296
V₂ = 0.0420 * 296
V₂ = 12.43 Liters.
A 100.0 mL sample of 0.300 M NaOH is mixed with a 100.0 mL sample of 0.300 M HNO 3 in a coffee cup calorimeter. If both solutions were initially at 35.00°C and the temperature of the resulting solution was recorded as 37.00°C, determine the ΔH° rxn (in units of kJ/mol NaOH) for the neutralization reaction between aqueous NaOH and HCl. Assume 1) that no heat is lost to the calorimeter or the surroundings, and 2) that the density and the heat capacity of the resulting solution are the same as water.
Answer:
THE STANDARD HEAT OF NEUTRALIZATION OF THE BASE SODIUM HYDROXIDE BY THE ACID HYDROGEN TRIOXONITRATE V ACID IS -56 kJ / mol.
Explanation:
Volume of 0.3 M NaOh = 100 mL
Volume of 0.3 M HNO3 = 100 mL
Initail temp of NaOH and HNO3 = 35 °C = 35 + 273 K = 308 K
Final temp. of mixture = 37 °C = 37 + 273 K = 310 K
We can make the following assumptions form the question given:
1. specific heat of the reaction mixture is the same as the specific heat of water = 4.2 J/g K
2. the toal mass of the reaction mixture is 200 mL = 200 g since no heat is lost to the calorimeter or surrounding.
3. initail temperature of the reaction mixture is equal to the average temperature of the two reactant solutions
= ( 308 + 308 /2) = 308 K
4. Rise in temeperature for the reaction = 310 -308 K = 2 K
Then the total heat evolved during the reaction = mass * specifc heat capacity * temperature change
Heat = 200 g * 4.2 J/g K * 2 K
Heat = 1680 J
EQUATION FOR THE REACTION
HNO3 + NaOH -------> NaNO3 + H20
From the equation, 1 mole of HNO3 reacts with 1 mole of NaOH to prouce mole of water.
100 mL of 0.5 M HNO3 contains 100 * 0.3 /1000 = 0.03 mole of acid
This result is same for the base NaOH = 0.03 mole of base
So therefore,
0.03 mole of acid will react with 0.03 mole of base to produce 0.03 mole of water to evolved 1680 J of heat energy.
The production of 1 mole of water will evolve 1680 / 0.03 J of heat
= 56 000 J or 56 kJ of heat energy per mole of water.
So therefore, 1the standard heat of neutralization of sodium hydroxide by trioxoxnitrate V acid is -56 kJ/mol.
A tank at is filled with of dinitrogen monoxide gas and of boron trifluoride gas. You can assume both gases behave as ideal gases under these conditions. Calculate the mole fraction and partial pressure of each gas, and the total pressure in the tank. Round each of your answers to significant digits.
Answer:
(1). Mole fraction = 0.152 for sulfur tetrafluoride gas.
Mole fraction = 0.848 For dinitrogen monoxide gas.
(2). Partial Pressure for dinitrogen monoxide gas = 187 kPa
Partial Pressure for sulfur tetrafluoride gas = 33.4 kpa.
(3). Total Partial Pressure = 220.4 kpa.
Explanation:
So, we are given the following data or parameters or information in the question above;
• Volume of the tank = 5.00L per tank;
• Temperature of the tank = 7.03°C;
• The mass of the content in the tank =
17.7g of dinitrogen monoxide gas and
7.77g of sulfur tetrafluoride gas.
So, we will be making use of the formulae below to calculate the MOLE FRACTION:
Moles, n= mass/molar mass and mole fraction = n(1)/ n(1) + n(2) per each constituents.
Moles, n1 = 17.7g of dinitrogen monoxide gas/ 44 grams per mole. =0.4023 moles.
Moles, n2 = 7.77g of sulfur tetrafluoride gas/ 108.1 grams per mole. = 0.07188 moles.
Total numbers of moles = n1 + n2 = 0.47415 moles
Mole fraction =0.4023 / 0.47415 = 0.848 of dinitrogen monoxide gas.
Mole fraction = 0.07188/0.47415 = 0.152 of sulfur tetrafluoride gas.
PART TWO: CALCULATE THE PARTIAL PRESSURE AND TOTAL PRESSURE BY USING THE FORMULA BELOW;
pressure × volume = number of moles × gas constant, R × temperature.
Pressure = n × R × T/ V.
For dinitrogen monoxide gas. ;
Partial Pressure = 0.4023 × 8.314 × 280.03 / 5 × 10^-3 = 187 kPa.
For sulfur tetrafluoride gas
Partial Pressure = 0.07188 × 8.314 ( × 280.03 / 5 × 10^-3. = 33.4 kpa.
(3). Total pressure = (187 + 33.4)kpa = 220.4 kpa
If a pork roast must absorb 1500 kJkJ to fully cook, and if only 14% of the heat produced by the barbeque is actually absorbed by the roast, what mass of CO2CO2 is emitted into the atmosphere during the grilling of the pork roast?
You need to know the amount of heat generated by the combustion reaction.
Assuming propane as fuel, you can use thiis data:
C3H8(g)+5O2(g)---3CO2(g)+4H2O(g) ΔH= -2217 KJ
So when 3 moles of CO2 is emmitted 2217 kJ of heat is produced.
The molar wegiht of CO2 is 12 g/mol + 2 * 16 g/mol = 44 g/mol.
Then 3 mol * 44 g / mol = 132 g of CO2 are produced with 2217 kJ of heat.
Now you have to calculate how much energy you need to produce if only 12% is abosrbed by the pork
Energy absorbed by the pork = 12% * total energy =>
total energy = energy absorbed by the pork / 0.12 = 1700 kJ / 0.12 = 14,166.67 kJ.
Now, state the proportion:
132 g CO2 / 2217 kJ = x / 14,166.7 kJ =>
x = 14,166.67 * 132 / 2217 = 843.48 g CO2.
Answer: 843 g of CO2
